benzyl tiglate structure
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Common Name | benzyl tiglate | ||
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CAS Number | 37526-88-8 | Molecular Weight | 190.23800 | |
Density | 1.031 g/mL at 25 °C(lit.) | Boiling Point | 139 °C9 mm Hg(lit.) | |
Molecular Formula | C12H14O2 | Melting Point | N/A | |
MSDS | USA | Flash Point | >230 °F |
Name | benzyl tiglate |
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Synonym | More Synonyms |
Density | 1.031 g/mL at 25 °C(lit.) |
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Boiling Point | 139 °C9 mm Hg(lit.) |
Molecular Formula | C12H14O2 |
Molecular Weight | 190.23800 |
Flash Point | >230 °F |
Exact Mass | 190.09900 |
PSA | 26.30000 |
LogP | 2.69600 |
Index of Refraction | n20/D 1.522(lit.) |
Benzyl Tiglate
Revision number: 1
SAFETY DATA SHEET Section1. BASE INFORMATION Product name:Benzyl Tiglate Revision number:1 Section2. HAZARDS IDENTIFICATION Classification of the GHS PHYSICAL HAZARDSNot classified HEALTH HAZARDSNot classified Not classified ENVIRONMENTAL HAZARDS GHS label elements None Pictograms or hazard symbols Signal wordNo signal word None Hazard statement Precautionary statementsNone Section3. COMPOSITION/INFORMATION ON INGREDIENTS Substance/mixture:Substance Component(s):Benzyl Tiglate Percent:>97.0%(GC) CAS Number:37526-88-8 Synonyms:Tiglic Acid Benzyl Ester Chemical Formula:C12H14O2 Section4. FIRST AID MEASURES Inhalation:Remove victim to fresh air and keep at rest in a position comfortable for breathing. Get medical advice/attention if you feel unwell. Skin contact:Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. If skin irritation or rash occurs: Get medical advice/attention. Eye contact:Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention. Ingestion:Get medical advice/attention if you feel unwell. Rinse mouth. A rescuer should wear personal protective equipment, such as rubber gloves and air- Protection of first-aiders: tight goggles. Section5. FIRE-FIGHTING MEASURES Suitable extinguishingDry chemical, foam, water spray, carbon dioxide. media: Extinguishing media not to Solid streams of water be used: Benzyl Tiglate Section5. FIRE-FIGHTING MEASURES Specific methods:Fire-extinguishing work is done from the windward and the suitable fire-extinguishing method according to the surrounding situation is used. Uninvolved persons should evacuate to a safe place. In case of fire in the surroundings: Remove movable containers if safe to do so. Special protectiveWhen extinguishing fire, be sure to wear personal protective equipment. equipment for firefighters: Section6. ACCIDENTAL RELEASE MEASURES Use personal protective equipment. Keep people away from and upwind of spill/leak. Personal precautions, protective equipment and Ensure adequate ventilation. Entry to non-involved personnel should be controlled emergency procedures: around the leakage area by roping off, etc. Environmental precautions: Prevent product from entering drains. Methods and materials for Absorb spilled material in a suitable absorbent (e.g. rag, dry sand, earth, saw-dust). containment and cleaning In case of large amount of spillage, contain a spill by bunding. Adhered or collected up: material should be promptly disposed of, in accordance with appropriate laws and regulations. Section7. HANDLING AND STORAGE Handling Technical measures:Handling is performed in a well ventilated place. Wear suitable protective equipment. Prevent generation of vapor or mist. Wash hands and face thoroughly after handling. Use a ventilation, local exhaust if vapor or aerosol will be generated. Advice on safe handling:Avoid contact with skin, eyes and clothing. Storage Keep container tightly closed. Store in a cool and dark place. Storage conditions: Store away from incompatible materials such as oxidizing agents. Law is followed. Packaging material: Section8. EXPOSURE CONTROLS / PERSONAL PROTECTION Engineering controls:Install a closed system or local exhaust as possible so that workers should not be exposed directly. Also install safety shower and eye bath. Personal protective equipment Respiratory protection: Vapor respirator. Follow local and national regulations. Hand protection:Protective gloves. Eye protection:Safety glasses. A face-shield, if the situation requires. Skin and body protection: Protective clothing. Protective boots, if the situation requires. Section9. PHYSICAL AND CHEMICAL PROPERTIES Physical state (20°C):Liquid Form:clear Color:Colorless - Very pale yellow Odor:No data available pH: No data available Melting point/freezing point:No data available Boiling Point/Range:134 °C/1.2kPa Flash Point:No data available Explosive limits Lower:No data available Upper:No data available Density:1.04 Solubility:No data available Section10. STABILITY AND REACTIVITY Stability:Stable under proper conditions. No special reactivity has been reported. Reactivity: Incompartible materials: oxidizing agents Benzyl Tiglate Section10. STABILITY AND REACTIVITY Hazardous Decomposition Carbon monoxide, Carbon dioxide Products: Section11. TOXICOLOGICAL INFORMATION Acute Toxicity:No data available Skin corrosion/irritation: No data available Serious eyeNo data available damage/irritation: Germ cell mutagenicity: No data available Carcinogenicity: IARC =No data available NTP =No data available Reproductive toxicity:No data available Section12. ECOLOGICAL INFORMATION Ecotoxicity: No data available Fish: Crustacea:No data available No data available Algae: Persistence / degradability: No data available No data available Bioaccumulative potential(BCF): Mobillity in soil log Pow:No data available No data available Soil adsorption (Koc): Henry's LawNo data available constant(PaM3/mol): Section13. DISPOSAL CONSIDERATIONS Recycle to process, if possible. Consult your local regional authorities. You may be able to burn in a chemical incinerator equipped with an afterburner and scrubber system. Observe all federal, state and local regulations when disposing of the substance. Section14. TRANSPORT INFORMATION Hazards Class:Does not correspond to the classification standard of the United Nations Not Listed UN-No: Section15. REGULATORY INFORMATION Safe management ordinance of dangerous chemical product (State Council announces on January 26, 2002): Safe use and production, the storage of a dangerous chemical, transport, loading and unloading were prescribed. Benzyl Tiglate SECTION 16 - ADDITIONAL INFORMATION N/A |
~10% benzyl tiglate CAS#:37526-88-8 |
Literature: Ishihara, Kazuaki; Nakayama, Masaya; Ohara, Suguru; Yamamoto, Hisashi Tetrahedron, 2002 , vol. 58, # 41 p. 8179 - 8188 |
~43% benzyl tiglate CAS#:37526-88-8 |
Literature: Lynch, Christopher L.; Hale, Jeffrey J.; Budhu, Richard J.; Gentry, Amy L.; Finke, Paul E.; Caldwell, Charles G.; Mills, Sander G.; MacCoss, Malcolm; Shen, Dong-Ming; Chapman, Kevin T.; Malkowitz, Lorraine; Springer, Martin S.; Gould, Sandra L.; DeMartino, Julie A.; Siciliano, Salvatore J.; Cascierl, Margaret A.; Carella, Anthony; Carver, Gwen; Holmes, Karen; Schleif, William A.; Danzeisen, Renee; Hazuda, Daria; Kessler, Joseph; Lineberger, Janet; Miller, Michael; Emini, Emilio Organic Letters, 2003 , vol. 5, # 14 p. 2473 - 2475 |
~% benzyl tiglate CAS#:37526-88-8 |
Literature: Advanced Synthesis and Catalysis, , vol. 350, # 13 p. 2033 - 2038 |
~% benzyl tiglate CAS#:37526-88-8 |
Literature: Zhurnal Obshchei Khimii, , vol. 28, p. 503,503, 505; engl. Ausg. S. 494, 496 |
HS Code | 2916190090 |
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Summary | 2916190090 unsaturated acyclic monocarboxylic acids, their anhydrides, halides, peroxides, peroxyacids and their derivatives。supervision conditions:AB(certificate of inspection for goods inward,certificate of inspection for goods outward)。VAT:17.0%。tax rebate rate:9.0%。MFN tariff:6.5%。general tariff:30.0% |
Tiglinsaeure-benzylester |
FEMA 3330 |
benzyl trans-2,3-dimethylacrylate |
MFCD00017279 |
Tiglic Acid Benzyl Ester |
EINECS 253-544-8 |
2-methyl-crotonic acid benzyl ester |
Benzyl-2-methylcrotonat |
benzyl 2-methylcrotonate |
benzyl E-2-methyl-2-butenoate |
BENZYL 2-METHYL-2-BUTENOATE |
Benzyl Tiglate |
2-Methyl-crotonsaeure-benzylester |
BENZYL TRANS-2-METHYL-2-BUTENOATE |