Methyl quinoline-6-carboxylate

Modify Date: 2024-01-02 20:47:05

Methyl quinoline-6-carboxylate Structure
Methyl quinoline-6-carboxylate structure
Common Name Methyl quinoline-6-carboxylate
CAS Number 38896-30-9 Molecular Weight 187.195
Density 1.2±0.1 g/cm3 Boiling Point 315.1±15.0 °C at 760 mmHg
Molecular Formula C11H9NO2 Melting Point 88 °C
MSDS N/A Flash Point 144.4±20.4 °C

 Names

Name Methyl Quinoline-6-Carboxylate
Synonym More Synonyms

 Chemical & Physical Properties

Density 1.2±0.1 g/cm3
Boiling Point 315.1±15.0 °C at 760 mmHg
Melting Point 88 °C
Molecular Formula C11H9NO2
Molecular Weight 187.195
Flash Point 144.4±20.4 °C
Exact Mass 187.063324
PSA 39.19000
LogP 2.11
Vapour Pressure 0.0±0.7 mmHg at 25°C
Index of Refraction 1.615

 MSDS

Name: Methyl quinoline-6-carboxylate 97% Material Safety Data Sheet
Synonym:
CAS: 38896-30-9
Section 1 - Chemical Product MSDS Name:Methyl quinoline-6-carboxylate 97% Material Safety Data Sheet
Synonym:

Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
CAS# Chemical Name content EINECS#
38896-30-9 Methyl quinoline-6-carboxylate 97% unlisted
Hazard Symbols: None Listed.
Risk Phrases: None Listed.

Section 3 - HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW
Not available.
Potential Health Effects
Eye:
May cause eye irritation.
Skin:
May cause skin irritation. May be harmful if absorbed through the skin.
Ingestion:
May cause irritation of the digestive tract. May be harmful if swallowed.
Inhalation:
May cause respiratory tract irritation. May be harmful if inhaled.
Chronic:
Not available.

Section 4 - FIRST AID MEASURES
Eyes: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid.
Skin:
Get medical aid. Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes.
Ingestion:
Get medical aid. Wash mouth out with water.
Inhalation:
Remove from exposure and move to fresh air immediately.
Notes to Physician:
Treat symptomatically and supportively.

Section 5 - FIRE FIGHTING MEASURES
General Information:
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear.
Extinguishing Media:
Use water spray, dry chemical, carbon dioxide, or chemical foam.

Section 6 - ACCIDENTAL RELEASE MEASURES
General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks:
Vacuum or sweep up material and place into a suitable disposal container.

Section 7 - HANDLING and STORAGE
Handling:
Avoid breathing dust, vapor, mist, or gas. Avoid contact with skin and eyes.
Storage:
Store in a cool, dry place. Store in a tightly closed container.

Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION
Engineering Controls:
Use adequate ventilation to keep airborne concentrations low.
Exposure Limits CAS# 38896-30-9: Personal Protective Equipment Eyes: Not available.
Skin:
Wear appropriate protective gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin exposure.
Respirators:
Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced.

Section 9 - PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Solid
Color: light brown
Odor: Not available.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point: 85 - 86 deg C
Autoignition Temperature: Not available.
Flash Point: Not available.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water:
Specific Gravity/Density:
Molecular Formula: C11H9NO2
Molecular Weight: 187

Section 10 - STABILITY AND REACTIVITY
Chemical Stability:
Not available.
Conditions to Avoid:
Incompatible materials.
Incompatibilities with Other Materials:
Strong oxidizing agents.
Hazardous Decomposition Products:
Nitrogen oxides, carbon monoxide, carbon dioxide, ammonia.
Hazardous Polymerization: Has not been reported

Section 11 - TOXICOLOGICAL INFORMATION
RTECS#:
CAS# 38896-30-9 unlisted.
LD50/LC50:
Not available.
Carcinogenicity:
Methyl quinoline-6-carboxylate - Not listed by ACGIH, IARC, or NTP.

Section 12 - ECOLOGICAL INFORMATION


Section 13 - DISPOSAL CONSIDERATIONS
Dispose of in a manner consistent with federal, state, and local regulations.

Section 14 - TRANSPORT INFORMATION

IATA
No information available.
IMO
No information available.
RID/ADR
No information available.

Section 15 - REGULATORY INFORMATION

European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: Not available.
Risk Phrases:
Safety Phrases:
S 24/25 Avoid contact with skin and eyes.
WGK (Water Danger/Protection)
CAS# 38896-30-9: No information available.
Canada
None of the chemicals in this product are listed on the DSL/NDSL list.
CAS# 38896-30-9 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 38896-30-9 is not listed on the TSCA inventory.
It is for research and development use only.


SECTION 16 - ADDITIONAL INFORMATION
N/A

 Safety Information

Hazard Codes Xi: Irritant;
Risk Phrases R36/37/38
Safety Phrases S26-S36/37/39
HS Code 2933499090

 Synthetic Route

~99%

Methyl quinoline-6-carboxylate Structure

Methyl quinolin...

CAS#:38896-30-9

Literature: Abe, Hideki; Sato, Akimi; Tokishita, Shin-Ichi; Ohta, Toshihiro; Ito, Hisanaka Heterocycles, 2011 , vol. 83, # 7 p. 1649 - 1658

~76%

Methyl quinoline-6-carboxylate Structure

Methyl quinolin...

CAS#:38896-30-9

Literature: Watson, Donald A.; Fan, Xuexiang; Buchwald, Stephen L. Journal of Organic Chemistry, 2008 , vol. 73, # 18 p. 7096 - 7101

~%

Methyl quinoline-6-carboxylate Structure

Methyl quinolin...

CAS#:38896-30-9

Literature: Hoechst Aktiengesellschaft Patent: US6093729 A1, 2000 ; US 6093729 A

~42%

Methyl quinoline-6-carboxylate Structure

Methyl quinolin...

CAS#:38896-30-9

Literature: Cho, Chan Sik; Lee, Na Young; Choi, Heung-Jin; Kim, Tae-Jeong; Shim, Sang Chul Journal of Heterocyclic Chemistry, 2003 , vol. 40, # 5 p. 929 - 932

~%

Methyl quinoline-6-carboxylate Structure

Methyl quinolin...

CAS#:38896-30-9

Literature: Agejas-Chicharro, Javier; Belen Bueno Melendo, Ana; Camp, Nicholas Paul; Gilmore, Jeremy; Jimenez-Aguado, Alma Maria; Lamas-Peteira, Carlos; Marcos-Llorente, Alicia; Mazanetz, Michael Philip; Montero Salgado, Carlos; Timms, Graham Henry; Williams, Andrew Caerwyn Patent: US2004/122001 A1, 2004 ; US 20040122001 A1

~%

Methyl quinoline-6-carboxylate Structure

Methyl quinolin...

CAS#:38896-30-9

Literature: Elderfield; Siegel Journal of the American Chemical Society, 1951 , vol. 73, p. 5622,5627

~91%

Methyl quinoline-6-carboxylate Structure

Methyl quinolin...

CAS#:38896-30-9

Literature: Jagadeesh, Rajenahally V.; Junge, Henrik; Pohl, Marga-Martina; Radnik, Joerg; Brueckner, Angelika; Beller, Matthias Journal of the American Chemical Society, 2013 , vol. 135, # 29 p. 10776 - 10782

~%

Methyl quinoline-6-carboxylate Structure

Methyl quinolin...

CAS#:38896-30-9

Literature: RHIZEN PHARMACEUTICALS SA; INCOZEN THERAPEUTICS PVT. LTD.; VAKKALANKA, Swaroop Kumar Venkata Satya; NAGARATHNAM, Dhanapalan; VISWANADHA, Srikant; MUTHUPPALANIAPPAN, Meyyappan; BABU, Govindarajulu; BHAVAR, Prashant K Patent: WO2013/144737 A2, 2013 ;

 Customs

HS Code 2933499090
Summary 2933499090. other compounds containing in the structure a quinoline or isoquinoline ring-system (whether or not hydrogenated), not further fused. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:20.0%

 Synonyms

6-Quinolinecarboxylic Acid Methyl Ester
Methyl 6-quinolinecarboxylate
6-Quinolinecarboxylic acid, methyl ester
Methyl quinoline-6-carboxylate
MFCD00956766
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