Methyl isocyanoacetate

Modify Date: 2024-01-02 21:35:47

Methyl isocyanoacetate Structure
Methyl isocyanoacetate structure
Common Name Methyl isocyanoacetate
CAS Number 39687-95-1 Molecular Weight 99.088
Density 1.09 g/mL at 25 °C(lit.) Boiling Point 75-76 °C10 mm Hg(lit.)
Molecular Formula C4H5NO2 Melting Point N/A
MSDS Chinese USA Flash Point 193 °F
Symbol GHS05 GHS07
GHS05, GHS07
Signal Word Danger

 Names

Name methyl isocyanoacetate
Synonym More Synonyms

 Chemical & Physical Properties

Density 1.09 g/mL at 25 °C(lit.)
Boiling Point 75-76 °C10 mm Hg(lit.)
Molecular Formula C4H5NO2
Molecular Weight 99.088
Flash Point 193 °F
Exact Mass 99.032028
PSA 26.30000
Index of Refraction n20/D 1.417(lit.)
Storage condition −20°C

 Safety Information

Symbol GHS05 GHS07
GHS05, GHS07
Signal Word Danger
Hazard Statements H302 + H312 + H332-H314
Precautionary Statements P280-P305 + P351 + P338-P310
Personal Protective Equipment Faceshields;full-face respirator (US);Gloves;Goggles;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter
Hazard Codes C: Corrosive;
Risk Phrases R20/21/22;R34
Safety Phrases S26-S36/37/39-S45
RIDADR UN 2922 8/PG 2
WGK Germany 3
Hazard Class 8.0, 6.1
HS Code 2926909090

 Synthetic Route

~70%

Methyl isocyanoacetate Structure

Methyl isocyano...

CAS#:39687-95-1

Literature: Park, William K. C.; Auer, Manfred; Jaksche, Herbert; Wong, Chi-Huey Journal of the American Chemical Society, 1996 , vol. 118, # 42 p. 10150 - 10155

~75%

Methyl isocyanoacetate Structure

Methyl isocyano...

CAS#:39687-95-1

Literature: Obrecht, Roland; Herrmann, Rudolf; Ugi, Ivar Synthesis, 1985 , # 4 p. 400 - 402

 Customs

HS Code 2926909090
Summary HS:2926909090 other nitrile-function compounds VAT:17.0% Tax rebate rate:9.0% Supervision conditions:none MFN tariff:6.5% General tariff:30.0%

 Articles3

More Articles
Chemoenzymatic construction of a four-component Ugi combinatorial library.

Biotechnol. Bioeng. 69(4) , 457-60, (2000)

The chemoenzymatic preparation of a nine-member Ugi condensation library is described. The carboxylic acid and amine precursors are based on 3-hydroxybutyrate and 4-amino-1-butanol, respectively, and ...

Highly active copper-network catalyst for the direct aldol reaction.

Chem. Asian J. 6(9) , 2545-9, (2011)

The development of a highly active solid-phase catechol-copper network catalyst for direct aldol reaction is described. The catalyst was prepared from an alkyl-chain-linked bis(catechol) and a copper(...

Tetrahedron Lett. 47 , 8641, (2006)

 Synonyms

Acetic acid, 2-isocyano-, methyl ester
methyl 2-isocyanoacetate
EINECS 254-593-8
MFCD00000006
Acetic acid, isocyano-, methyl ester
Methyl isocyanoacetate
Isocyanoacetic Acid Methyl Ester
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