((4s,5s)-(+)-o-[1-benzyl-1-(5-methyl-2-phenyl-4,5-dihydro-oxazol-4-yl)-2-phenylethyl]-diphenyl-phosphinite)(1,5-cod)iridium (i) tetrakis(3,5-bis(trifluoromethyl)phenylborate structure
|
Common Name | ((4s,5s)-(+)-o-[1-benzyl-1-(5-methyl-2-phenyl-4,5-dihydro-oxazol-4-yl)-2-phenylethyl]-diphenyl-phosphinite)(1,5-cod)iridium (i) tetrakis(3,5-bis(trifluoromethyl)phenylborate | ||
---|---|---|---|---|
CAS Number | 405235-55-4 | Molecular Weight | 1719.25000 | |
Density | N/A | Boiling Point | N/A | |
Molecular Formula | C77H58BF24IrNO2P | Melting Point | 112-113ºC | |
MSDS | USA | Flash Point | N/A |
Name | ((4s,5s)-(+)-o-[1-benzyl-1-(5-methyl-2-phenyl-4,5-dihydro-oxazol-4-yl)-2-phenylethyl]-diphenyl-phosphinite)(1,5-cod)iridium (i) tetrakis(3,5-bis(trifluoromethyl)phenylborate |
---|---|
Synonym | More Synonyms |
Melting Point | 112-113ºC |
---|---|
Molecular Formula | C77H58BF24IrNO2P |
Molecular Weight | 1719.25000 |
Exact Mass | 1719.35000 |
PSA | 44.41000 |
LogP | 20.53680 |
Personal Protective Equipment | Eyeshields;Gloves;type N95 (US);type P1 (EN143) respirator filter |
---|---|
Safety Phrases | 22-24/25 |
RIDADR | NONH for all modes of transport |
HS Code | 28439000 |
A New Class of Modular Phosphinite-Oxazoline Ligands: Ir-Catalyzed Enantioselective Hydrogenation of Alkenes We thank Dr. Martin Studer and Dr. Beno_t Pugin (Solvias AG, Basel) for fruitful discussions, and Prof. Kevin Burgess (Texas A&M University) for preprints of related unpublished work. Financial support by the Swiss National Science Foundation is gratefully acknowledged.
Angew. Chem. Int. Ed. Engl. 40 , 4445-4447, (2001)
|
|
Threonine-derived phosphinite-oxazoline ligands for the Ir-catalyzed enantioselective hydrogenation. Menges, F. and Pfaltz, A.
Adv. Synth. Catal. 344 , 40-44, (2002)
|
((4S,5S)-(-)-O-[1-Benzyl-1-(5-methyl-2-phenyl-4,5-dihydro-oxazol-4-yl)-2-phenylethyl]-diphenylphosphinite)(1,5-COD)iridium(I)tetrakis-(3,5-bis(trifluoromethyl)phenyl |
((4S,5S)-(+)-O-[1-Benzyl-1-(5-methyl-2-phenyl-4,5-dihydro-oxazol-4-yl)-2-phenylethyl]-diphenyl-phosphinite)(1,5-COD)iridium(I) tetrakis(3,5-bis(trifluoromethy |
((4S,5S)-(+)-O-[1-Benzyl-1-(5-methyl-2-phenyl-4,5-dihydrooxazol-4-yl)-2-phenylethyl]-diphenylphosphinite)(1,5-COD)iridium(I)tetrakis(3,5-bis(trifluoromethyl)phenylborate,min. |
((4S,5S)-(-)-O-[1-Benzyl-1-(5-methyl-2-phenyl-4,5-dihydrooxazol-4-yl)-2-phenylethyl]-diphenylphosphinite)(1,5-COD)iridium(I) tetrakis(3,5-bis(trifluoromethyl)phenylborate,min. (S,S)-[COD]Ir[Ph2PT |