Trifluoroacetic anhydride

Modify Date: 2024-01-02 16:15:51

Trifluoroacetic anhydride Structure
Trifluoroacetic anhydride structure
Common Name Trifluoroacetic anhydride
CAS Number 407-25-0 Molecular Weight 210.031
Density 1.6±0.1 g/cm3 Boiling Point 39.5±0.0 °C at 760 mmHg
Molecular Formula C4F6O3 Melting Point -63.5 °C
MSDS Chinese USA Flash Point -26.1±20.8 °C
Symbol GHS05 GHS07
GHS05, GHS07
Signal Word Danger

 Names

Name Trifluoroacetic anhydride
Synonym More Synonyms

 Chemical & Physical Properties

Density 1.6±0.1 g/cm3
Boiling Point 39.5±0.0 °C at 760 mmHg
Melting Point -63.5 °C
Molecular Formula C4F6O3
Molecular Weight 210.031
Flash Point -26.1±20.8 °C
Exact Mass 209.975159
PSA 43.37000
LogP 2.56
Vapour Pressure 438.6±0.0 mmHg at 25°C
Index of Refraction 1.291
Stability Stable, but moisture sensitive. Reacts with water to liberate hydrogen (flammable!). Incompatible with water, strong oxidizing agents.
Water Solubility Hydrolysis

 Toxicological Information

CHEMICAL IDENTIFICATION

RTECS NUMBER :
AJ9800000
CHEMICAL NAME :
Acetic acid, trifluoro-, anhydride
CAS REGISTRY NUMBER :
407-25-0
BEILSTEIN REFERENCE NO. :
0746197
LAST UPDATED :
199701
DATA ITEMS CITED :
4
MOLECULAR FORMULA :
C4-F6-O3
MOLECULAR WEIGHT :
210.04
WISWESSER LINE NOTATION :
FXFFVOVXFFF

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :
Standard Draize test
ROUTE OF EXPOSURE :
Administration onto the skin
SPECIES OBSERVED :
Rodent - rabbit
REFERENCE :
85JCAE "Prehled Prumyslove Toxikologie; Organicke Latky," Marhold, J., Prague, Czechoslovakia, Avicenum, 1986 Volume(issue)/page/year: -,575,1986
TYPE OF TEST :
Standard Draize test
ROUTE OF EXPOSURE :
Administration into the eye
SPECIES OBSERVED :
Rodent - rabbit
REFERENCE :
85JCAE "Prehled Prumyslove Toxikologie; Organicke Latky," Marhold, J., Prague, Czechoslovakia, Avicenum, 1986 Volume(issue)/page/year: -,575,1986 *** NIOSH STANDARDS DEVELOPMENT AND SURVEILLANCE DATA *** NIOSH OCCUPATIONAL EXPOSURE SURVEY DATA : NOES - National Occupational Exposure Survey (1983) NOES Hazard Code - X4633 No. of Facilities: 147 (estimated) No. of Industries: 2 No. of Occupations: 3 No. of Employees: 5451 (estimated) No. of Female Employees: 1249 (estimated)

 Safety Information

Symbol GHS05 GHS07
GHS05, GHS07
Signal Word Danger
Hazard Statements H314-H332
Supplemental HS Reacts violently with water.
Precautionary Statements P280-P305 + P351 + P338-P310
Personal Protective Equipment Faceshields;full-face respirator (US);Gloves;Goggles;multi-purpose combination respirator cartridge (US)
Hazard Codes C:Corrosive
Risk Phrases R14;R20;R35;R52/53
Safety Phrases S26-S36/37/39-S43-S45-S61-S9-S8-S28A-S27
RIDADR UN 3265 8/PG 1
WGK Germany 2
RTECS AJ9800000
Packaging Group I
Hazard Class 8
HS Code 29159080

 Synthetic Route

 Customs

HS Code 2915900090
Summary 2915900090 other saturated acyclic monocarboxylic acids and their anhydrides, halides, peroxides and peroxyacids; their halogenated, sulphonated, nitrated or nitrosated derivatives VAT:17.0% Tax rebate rate:9.0% Supervision conditions:AB(certificate of inspection for goods inward,certificate of inspection for goods outward) MFN tariff:5.5% General tariff:30.0%

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 Synonyms

trifluoro acetic anhydride
trifluoroacetic
TRIFLUORACETIC ANHYDRIDE
Trifluoroacetyl anhydride
Perfluoracetic anhydride
trifluoroacetylanhydride
perfluoroaceticanhydride
MFCD00000416
Trifluoromethanesulfonic acid
2,2,2-trifluoroacetic anhydride
Trifluoroacetic Anhydride (TFAA)
hexafluoroacetic anhydride
Trifluoroacetic acid anhydride
EINECS 206-982-9
bis-trifluoroacetic anhydride
TFAA
Trifluoroacetic anhy
Perfluoroacetic anhydride
Trifluoroacetic anhydride
RIFLUOROACETIC ANHYDRIDE
TRIFLUOROACETO ANHYDRIDE
TIFLUOROACETIC ANHYDRIDE
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