9H-Fluorene-4-carboxylicacid, 9-oxo-, methyl ester

Modify Date: 2024-01-09 22:57:43

9H-Fluorene-4-carboxylicacid, 9-oxo-, methyl ester Structure
9H-Fluorene-4-carboxylicacid, 9-oxo-, methyl ester structure
Common Name 9H-Fluorene-4-carboxylicacid, 9-oxo-, methyl ester
CAS Number 4269-19-6 Molecular Weight 238.23800
Density 1.303g/cm3 Boiling Point 420.3ºC at 760mmHg
Molecular Formula C15H10O3 Melting Point 135-136ºC
MSDS N/A Flash Point 189.7ºC

 Names

Name methyl 9-oxofluorene-4-carboxylate
Synonym More Synonyms

 Chemical & Physical Properties

Density 1.303g/cm3
Boiling Point 420.3ºC at 760mmHg
Melting Point 135-136ºC
Molecular Formula C15H10O3
Molecular Weight 238.23800
Flash Point 189.7ºC
Exact Mass 238.06300
PSA 43.37000
LogP 2.68460
Index of Refraction 1.638

 MSDS

Name: Methyl 9-oxo-9h-fluorene-4-carboxylate 97% Material Safety Data Sheet
Synonym: Methyl 9-fluorenone-4-carboxylat
CAS: 4269-19-6
Section 1 - Chemical Product MSDS Name:Methyl 9-oxo-9h-fluorene-4-carboxylate 97% Material Safety Data Sheet
Synonym:Methyl 9-fluorenone-4-carboxylat

Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
CAS# Chemical Name content EINECS#
4269-19-6 Methyl 9-oxo-9H-fluorene-4-carboxylate 97% unlisted
Hazard Symbols: None Listed.
Risk Phrases: None Listed.

Section 3 - HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW
Not available.
Potential Health Effects
Eye:
May cause eye irritation.
Skin:
May cause skin irritation. May be harmful if absorbed through the skin.
Ingestion:
May cause irritation of the digestive tract. May be harmful if swallowed.
Inhalation:
May cause respiratory tract irritation. May be harmful if inhaled.
Chronic:
Not available.

Section 4 - FIRST AID MEASURES
Eyes: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid.
Skin:
Get medical aid. Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes.
Ingestion:
Get medical aid. Wash mouth out with water.
Inhalation:
Remove from exposure and move to fresh air immediately.
Notes to Physician:
Treat symptomatically and supportively.

Section 5 - FIRE FIGHTING MEASURES
General Information:
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear.
Extinguishing Media:
Use water spray, dry chemical, carbon dioxide, or chemical foam.

Section 6 - ACCIDENTAL RELEASE MEASURES
General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks:
Vacuum or sweep up material and place into a suitable disposal container.

Section 7 - HANDLING and STORAGE
Handling:
Avoid breathing dust, vapor, mist, or gas. Avoid contact with skin and eyes.
Storage:
Store in a cool, dry place. Store in a tightly closed container.

Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION
Engineering Controls:
Use adequate ventilation to keep airborne concentrations low.
Exposure Limits CAS# 4269-19-6: Personal Protective Equipment Eyes: Not available.
Skin:
Wear appropriate protective gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin exposure.
Respirators:
Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced.

Section 9 - PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Solid
Color: yellow
Odor: Not available.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point: 135 - 136 deg C
Autoignition Temperature: Not available.
Flash Point: Not available.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water:
Specific Gravity/Density:
Molecular Formula: C15H10O3
Molecular Weight: 238

Section 10 - STABILITY AND REACTIVITY
Chemical Stability:
Not available.
Conditions to Avoid:
Incompatible materials.
Incompatibilities with Other Materials:
Strong oxidizing agents.
Hazardous Decomposition Products:
Carbon monoxide, carbon dioxide.
Hazardous Polymerization: Not available.

Section 11 - TOXICOLOGICAL INFORMATION
RTECS#:
CAS# 4269-19-6 unlisted.
LD50/LC50:
Not available.
Carcinogenicity:
Methyl 9-oxo-9H-fluorene-4-carboxylate - Not listed by ACGIH, IARC, or NTP.

Section 12 - ECOLOGICAL INFORMATION


Section 13 - DISPOSAL CONSIDERATIONS
Dispose of in a manner consistent with federal, state, and local regulations.

Section 14 - TRANSPORT INFORMATION

IATA
No information available.
IMO
No information available.
RID/ADR
No information available.

Section 15 - REGULATORY INFORMATION

European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: Not available.
Risk Phrases:
Safety Phrases:
S 24/25 Avoid contact with skin and eyes.
WGK (Water Danger/Protection)
CAS# 4269-19-6: No information available.
Canada
None of the chemicals in this product are listed on the DSL/NDSL list.
CAS# 4269-19-6 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 4269-19-6 is not listed on the TSCA inventory.
It is for research and development use only.


SECTION 16 - ADDITIONAL INFORMATION
N/A

 Safety Information

Hazard Codes Xi
Safety Phrases S24/25
HS Code 2918300090

 Synthetic Route

~%

9H-Fluorene-4-carboxylicacid, 9-oxo-, methyl ester Structure

9H-Fluorene-4-c...

CAS#:4269-19-6

Literature: Underwood; Kochmann Journal of the American Chemical Society, 1924 , vol. 46, p. 2073

~%

9H-Fluorene-4-carboxylicacid, 9-oxo-, methyl ester Structure

9H-Fluorene-4-c...

CAS#:4269-19-6

Literature: Underwood; Kochmann Journal of the American Chemical Society, 1924 , vol. 46, p. 2073

~%

9H-Fluorene-4-carboxylicacid, 9-oxo-, methyl ester Structure

9H-Fluorene-4-c...

CAS#:4269-19-6

Literature: Graebe; Aubin Justus Liebigs Annalen der Chemie, 1888 , vol. 247, p. 272

~%

9H-Fluorene-4-carboxylicacid, 9-oxo-, methyl ester Structure

9H-Fluorene-4-c...

CAS#:4269-19-6

Literature: Graebe; Aubin Justus Liebigs Annalen der Chemie, 1888 , vol. 247, p. 272

~%

9H-Fluorene-4-carboxylicacid, 9-oxo-, methyl ester Structure

9H-Fluorene-4-c...

CAS#:4269-19-6

Literature: Graebe; Aubin Justus Liebigs Annalen der Chemie, 1888 , vol. 247, p. 272

~%

9H-Fluorene-4-carboxylicacid, 9-oxo-, methyl ester Structure

9H-Fluorene-4-c...

CAS#:4269-19-6

Literature: Graebe; Aubin Justus Liebigs Annalen der Chemie, 1888 , vol. 247, p. 272

 Customs

HS Code 2918300090
Summary 2918300090 other carboxylic acids with aldehyde or ketone function but without other oxygen function, their anhydrides, halides, peroxides, peroxyacids and their derivatives。Supervision conditions:None。VAT:17.0%。Tax rebate rate:9.0%。MFN tariff:6.5%。General tariff:30.0%

 Synonyms

fluoren-9-one-4-carboxylic acid methyl ester
Fluorenon-4-carbonsaeure-methylester
9-oxo-9H-fluorene-4-carboxylic acid methyl ester
9-Oxofluoren-4-carbonsaeure-methylester
9-oxo-fluorene-4-carboxylic acid methyl ester
methyl 9-oxo-9h-fluorene-4-carboxylate
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