2-CHLORO-6-FLUOROBENZALDOXIME structure
|
Common Name | 2-CHLORO-6-FLUOROBENZALDOXIME | ||
---|---|---|---|---|
CAS Number | 443-33-4 | Molecular Weight | 173.57200 | |
Density | 1.32 g/cm3 | Boiling Point | 238ºC at 760 mmHg | |
Molecular Formula | C7H5ClFNO | Melting Point | 129-133 °C(lit.) | |
MSDS | Chinese USA | Flash Point | 97.8ºC | |
Symbol |
GHS07 |
Signal Word | Warning |
Name | 2-chloro-6-fluorobenzaldoxime |
---|---|
Synonym | More Synonyms |
Density | 1.32 g/cm3 |
---|---|
Boiling Point | 238ºC at 760 mmHg |
Melting Point | 129-133 °C(lit.) |
Molecular Formula | C7H5ClFNO |
Molecular Weight | 173.57200 |
Flash Point | 97.8ºC |
Exact Mass | 173.00400 |
PSA | 32.59000 |
LogP | 2.28720 |
Vapour Pressure | 0.0237mmHg at 25°C |
Index of Refraction | 1.533 |
Synonym: Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
Risk Phrases: 36/37/38 Section 3 - HAZARDS IDENTIFICATION EMERGENCY OVERVIEW
Irritating to eyes, respiratory system and skin. Potential Health Effects Eye: Causes eye irritation. Skin: Causes skin irritation. May be harmful if absorbed through the skin. Ingestion: May cause irritation of the digestive tract. May be harmful if swallowed. Inhalation: Causes respiratory tract irritation. May be harmful if inhaled. Chronic: Not available. Section 4 - FIRST AID MEASURES Eyes: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid. Skin: Get medical aid. Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Ingestion: Get medical aid. Wash mouth out with water. Inhalation: Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid. Notes to Physician: Treat symptomatically and supportively. Section 5 - FIRE FIGHTING MEASURES General Information: As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Extinguishing Media: Use water spray, dry chemical, carbon dioxide, or chemical foam. Section 6 - ACCIDENTAL RELEASE MEASURES General Information: Use proper personal protective equipment as indicated in Section 8. Spills/Leaks: Vacuum or sweep up material and place into a suitable disposal container. Section 7 - HANDLING and STORAGE Handling: Avoid breathing dust, vapor, mist, or gas. Avoid contact with skin and eyes. Storage: Store in a cool, dry place. Store in a tightly closed container. Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION Engineering Controls: Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate ventilation to keep airborne concentrations low. Exposure Limits CAS# 443-33-4: Personal Protective Equipment Eyes: Not available. Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to prevent skin exposure. Respirators: Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced. Section 9 - PHYSICAL AND CHEMICAL PROPERTIES Physical State: Solid Color: light yellow Odor: Not available. pH: Not available. Vapor Pressure: Not available. Viscosity: Not available. Boiling Point: Not available. Freezing/Melting Point: 133 - 134 deg C Autoignition Temperature: Not available. Flash Point: Not available. Explosion Limits, lower: Not available. Explosion Limits, upper: Not available. Decomposition Temperature: Solubility in water: Specific Gravity/Density: Molecular Formula: C7H5ClFNO Molecular Weight: 174 Section 10 - STABILITY AND REACTIVITY Chemical Stability: Not available. Conditions to Avoid: Incompatible materials. Incompatibilities with Other Materials: Strong oxidizing agents. Hazardous Decomposition Products: Hydrogen chloride, chlorine, nitrogen oxides, carbon monoxide, carbon dioxide. Hazardous Polymerization: Has not been reported Section 11 - TOXICOLOGICAL INFORMATION RTECS#: CAS# 443-33-4 unlisted. LD50/LC50: Not available. Carcinogenicity: 2-Chloro-6-fluorobenzaldehyde oxime - Not listed by ACGIH, IARC, or NTP. Section 12 - ECOLOGICAL INFORMATION Section 13 - DISPOSAL CONSIDERATIONS Dispose of in a manner consistent with federal, state, and local regulations. Section 14 - TRANSPORT INFORMATION IATA No information available. IMO No information available. RID/ADR No information available. Section 15 - REGULATORY INFORMATION European/International Regulations European Labeling in Accordance with EC Directives Hazard Symbols: XI Risk Phrases: R 36/37/38 Irritating to eyes, respiratory system and skin. Safety Phrases: S 26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S 37/39 Wear suitable gloves and eye/face protection. WGK (Water Danger/Protection) CAS# 443-33-4: No information available. Canada None of the chemicals in this product are listed on the DSL/NDSL list. CAS# 443-33-4 is not listed on Canada's Ingredient Disclosure List. US FEDERAL TSCA CAS# 443-33-4 is not listed on the TSCA inventory. It is for research and development use only. SECTION 16 - ADDITIONAL INFORMATION N/A |
Symbol |
GHS07 |
---|---|
Signal Word | Warning |
Hazard Statements | H302-H319 |
Precautionary Statements | P305 + P351 + P338 |
Personal Protective Equipment | dust mask type N95 (US);Eyeshields;Gloves |
Hazard Codes | Xi:Irritant; |
Risk Phrases | R36/37/38 |
Safety Phrases | S26-S26,37/39 |
RIDADR | NONH for all modes of transport |
WGK Germany | 2 |
HS Code | 2928000090 |
~95% 2-CHLORO-6-FLUO... CAS#:443-33-4 |
Literature: Hajipour, Abdol Reza; Mallakpour, Shadpour E.; Imanzadeh, Gholamhasan Journal of Chemical Research - Part S, 1999 , # 3 p. 228 - 229 |
~% 2-CHLORO-6-FLUO... CAS#:443-33-4 |
Literature: Lock Chemische Berichte, 1936 , vol. 69, p. 2253,2255 |
Precursor 2 | |
---|---|
DownStream 7 | |
HS Code | 2928000090 |
---|---|
Summary | 2928000090 other organic derivatives of hydrazine or of hydroxylamine VAT:17.0% Tax rebate rate:9.0% Supervision conditions:none MFN tariff:6.5% General tariff:20.0% |
MFCD00837704 |
(NE)-N-[(2-chloro-6-fluorophenyl)methylidene]hydroxylamine |
EINECS 207-135-6 |
2-Chloro-6-fluorobenzaldehyde oxime |
2-Chloro-6-fluorobenzaldoxime |