2-CHLORO-6-FLUOROBENZALDOXIME

Modify Date: 2024-01-03 16:27:45

2-CHLORO-6-FLUOROBENZALDOXIME Structure
2-CHLORO-6-FLUOROBENZALDOXIME structure
Common Name 2-CHLORO-6-FLUOROBENZALDOXIME
CAS Number 443-33-4 Molecular Weight 173.57200
Density 1.32 g/cm3 Boiling Point 238ºC at 760 mmHg
Molecular Formula C7H5ClFNO Melting Point 129-133 °C(lit.)
MSDS Chinese USA Flash Point 97.8ºC
Symbol GHS07
GHS07
Signal Word Warning

 Names

Name 2-chloro-6-fluorobenzaldoxime
Synonym More Synonyms

 Chemical & Physical Properties

Density 1.32 g/cm3
Boiling Point 238ºC at 760 mmHg
Melting Point 129-133 °C(lit.)
Molecular Formula C7H5ClFNO
Molecular Weight 173.57200
Flash Point 97.8ºC
Exact Mass 173.00400
PSA 32.59000
LogP 2.28720
Vapour Pressure 0.0237mmHg at 25°C
Index of Refraction 1.533

 MSDS

Name: 2-Chloro-6-fluorobenzaldehyde oxime tech Material Safety Data Sheet
Synonym:
CAS: 443-33-4
Section 1 - Chemical Product MSDS Name:2-Chloro-6-fluorobenzaldehyde oxime tech Material Safety Data Sheet
Synonym:

Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
CAS# Chemical Name content EINECS#
443-33-4 2-Chloro-6-fluorobenzaldehyde oxime 207-135-6
Hazard Symbols: XI
Risk Phrases: 36/37/38

Section 3 - HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW
Irritating to eyes, respiratory system and skin.
Potential Health Effects
Eye:
Causes eye irritation.
Skin:
Causes skin irritation. May be harmful if absorbed through the skin.
Ingestion:
May cause irritation of the digestive tract. May be harmful if swallowed.
Inhalation:
Causes respiratory tract irritation. May be harmful if inhaled.
Chronic:
Not available.

Section 4 - FIRST AID MEASURES
Eyes: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid.
Skin:
Get medical aid. Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes.
Ingestion:
Get medical aid. Wash mouth out with water.
Inhalation:
Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid.
Notes to Physician:
Treat symptomatically and supportively.

Section 5 - FIRE FIGHTING MEASURES
General Information:
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear.
Extinguishing Media:
Use water spray, dry chemical, carbon dioxide, or chemical foam.

Section 6 - ACCIDENTAL RELEASE MEASURES
General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks:
Vacuum or sweep up material and place into a suitable disposal container.

Section 7 - HANDLING and STORAGE
Handling:
Avoid breathing dust, vapor, mist, or gas. Avoid contact with skin and eyes.
Storage:
Store in a cool, dry place. Store in a tightly closed container.

Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION
Engineering Controls:
Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate ventilation to keep airborne concentrations low.
Exposure Limits CAS# 443-33-4: Personal Protective Equipment Eyes: Not available.
Skin:
Wear appropriate protective gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin exposure.
Respirators:
Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced.

Section 9 - PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Solid
Color: light yellow
Odor: Not available.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point: 133 - 134 deg C
Autoignition Temperature: Not available.
Flash Point: Not available.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water:
Specific Gravity/Density:
Molecular Formula: C7H5ClFNO
Molecular Weight: 174

Section 10 - STABILITY AND REACTIVITY
Chemical Stability:
Not available.
Conditions to Avoid:
Incompatible materials.
Incompatibilities with Other Materials:
Strong oxidizing agents.
Hazardous Decomposition Products:
Hydrogen chloride, chlorine, nitrogen oxides, carbon monoxide, carbon dioxide.
Hazardous Polymerization: Has not been reported

Section 11 - TOXICOLOGICAL INFORMATION
RTECS#:
CAS# 443-33-4 unlisted.
LD50/LC50:
Not available.
Carcinogenicity:
2-Chloro-6-fluorobenzaldehyde oxime - Not listed by ACGIH, IARC, or NTP.

Section 12 - ECOLOGICAL INFORMATION


Section 13 - DISPOSAL CONSIDERATIONS
Dispose of in a manner consistent with federal, state, and local regulations.

Section 14 - TRANSPORT INFORMATION

IATA
No information available.
IMO
No information available.
RID/ADR
No information available.

Section 15 - REGULATORY INFORMATION

European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XI
Risk Phrases:
R 36/37/38 Irritating to eyes, respiratory system
and skin.
Safety Phrases:
S 26 In case of contact with eyes, rinse immediately
with plenty of water and seek medical advice.
S 37/39 Wear suitable gloves and eye/face
protection.
WGK (Water Danger/Protection)
CAS# 443-33-4: No information available.
Canada
None of the chemicals in this product are listed on the DSL/NDSL list.
CAS# 443-33-4 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 443-33-4 is not listed on the TSCA inventory.
It is for research and development use only.


SECTION 16 - ADDITIONAL INFORMATION
N/A

 Safety Information

Symbol GHS07
GHS07
Signal Word Warning
Hazard Statements H302-H319
Precautionary Statements P305 + P351 + P338
Personal Protective Equipment dust mask type N95 (US);Eyeshields;Gloves
Hazard Codes Xi:Irritant;
Risk Phrases R36/37/38
Safety Phrases S26-S26,37/39
RIDADR NONH for all modes of transport
WGK Germany 2
HS Code 2928000090

 Synthetic Route

~95%

2-CHLORO-6-FLUOROBENZALDOXIME Structure

2-CHLORO-6-FLUO...

CAS#:443-33-4

Literature: Hajipour, Abdol Reza; Mallakpour, Shadpour E.; Imanzadeh, Gholamhasan Journal of Chemical Research - Part S, 1999 , # 3 p. 228 - 229

~%

2-CHLORO-6-FLUOROBENZALDOXIME Structure

2-CHLORO-6-FLUO...

CAS#:443-33-4

Literature: Lock Chemische Berichte, 1936 , vol. 69, p. 2253,2255

 Customs

HS Code 2928000090
Summary 2928000090 other organic derivatives of hydrazine or of hydroxylamine VAT:17.0% Tax rebate rate:9.0% Supervision conditions:none MFN tariff:6.5% General tariff:20.0%

 Synonyms

MFCD00837704
(NE)-N-[(2-chloro-6-fluorophenyl)methylidene]hydroxylamine
EINECS 207-135-6
2-Chloro-6-fluorobenzaldehyde oxime
2-Chloro-6-fluorobenzaldoxime
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