Bicyclo[2.2.1]hept-5-ene-2,3-dicarbonyldichloride, (1R,2R,3R,4S)-rel-

Modify Date: 2024-01-10 12:47:40

Bicyclo[2.2.1]hept-5-ene-2,3-dicarbonyldichloride, (1R,2R,3R,4S)-rel- Structure
Bicyclo[2.2.1]hept-5-ene-2,3-dicarbonyldichloride, (1R,2R,3R,4S)-rel- structure
Common Name Bicyclo[2.2.1]hept-5-ene-2,3-dicarbonyldichloride, (1R,2R,3R,4S)-rel-
CAS Number 4582-21-2 Molecular Weight 219.06500
Density 1.453g/cm3 Boiling Point 243.3ºC at 760mmHg
Molecular Formula C9H8Cl2O2 Melting Point N/A
MSDS Chinese USA Flash Point 133.5ºC
Symbol GHS05 GHS07
GHS05, GHS07
Signal Word Danger

 Names

Name trans-5-norbornene-2,3-dicarbonyl chloride
Synonym More Synonyms

 Chemical & Physical Properties

Density 1.453g/cm3
Boiling Point 243.3ºC at 760mmHg
Molecular Formula C9H8Cl2O2
Molecular Weight 219.06500
Flash Point 133.5ºC
Exact Mass 217.99000
PSA 34.14000
LogP 1.95550
Index of Refraction n20/D 1.517(lit.)

 Toxicological Information

CHEMICAL IDENTIFICATION

RTECS NUMBER :
RB8225000
CHEMICAL NAME :
5-Norbornene-2,3-dicarbonyl chloride, trans-
CAS REGISTRY NUMBER :
4582-21-2
BEILSTEIN REFERENCE NO. :
3134243
LAST UPDATED :
199612
DATA ITEMS CITED :
2
MOLECULAR FORMULA :
C9-H8-Cl2-O2
MOLECULAR WEIGHT :
219.07
WISWESSER LINE NOTATION :
L55 A CUTJ FVG GVG -T

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
1830 uL/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
TXAPA9 Toxicology and Applied Pharmacology. (Academic Press, Inc., 1 E. First St., Duluth, MN 55802) V.1- 1959- Volume(issue)/page/year: 28,313,1974
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Administration onto the skin
SPECIES OBSERVED :
Rodent - rabbit
DOSE/DURATION :
1 mL/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
TXAPA9 Toxicology and Applied Pharmacology. (Academic Press, Inc., 1 E. First St., Duluth, MN 55802) V.1- 1959- Volume(issue)/page/year: 28,313,1974

 Safety Information

Symbol GHS05 GHS07
GHS05, GHS07
Signal Word Danger
Hazard Statements H312 + H332-H314
Precautionary Statements P280-P305 + P351 + P338-P310
Personal Protective Equipment Faceshields;full-face respirator (US);Gloves;Goggles;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter
Hazard Codes C
Risk Phrases R34
Safety Phrases S24/25
RIDADR UN 3265 8/PG 2
WGK Germany 3
RTECS RB8225000
Packaging Group III
HS Code 2917209090

 Synthetic Route

~99%

Bicyclo[2.2.1]hept-5-ene-2,3-dicarbonyldichloride, (1R,2R,3R,4S)-rel- Structure

Bicyclo[2.2.1]h...

CAS#:4582-21-2

Literature: Shen, Wang; Garvey, David S.; Cohen, Jerry; Stein, Herman; Rosenberg, Saul H. Bioorganic and Medicinal Chemistry Letters, 1998 , vol. 8, # 8 p. 891 - 896

~%

Bicyclo[2.2.1]hept-5-ene-2,3-dicarbonyldichloride, (1R,2R,3R,4S)-rel- Structure

Bicyclo[2.2.1]h...

CAS#:4582-21-2

Literature: Pulamagatta; Pankaj; Beiner; Binder Macromolecules, 2011 , vol. 44, # 4 p. 958 - 965

~%

Bicyclo[2.2.1]hept-5-ene-2,3-dicarbonyldichloride, (1R,2R,3R,4S)-rel- Structure

Bicyclo[2.2.1]h...

CAS#:4582-21-2

Literature: Moore, Joel D.; Byrne, Robert J.; Vedantham, Punitha; Flynn, Daniel L.; Hanson, Paul R. Organic Letters, 2003 , vol. 5, # 23 p. 4241 - 4244

~%

Bicyclo[2.2.1]hept-5-ene-2,3-dicarbonyldichloride, (1R,2R,3R,4S)-rel- Structure

Bicyclo[2.2.1]h...

CAS#:4582-21-2

Literature: Imp. Chem. Ind. Patent: GB578867 , 1945 ;

 Customs

HS Code 2917209090
Summary 2917209090 other cyclanic, cyclenic or cyclotherpenic polycarboxylic acids, their anhydrides, halides, peroxides, peroxyacids and their derivatives。supervision conditions:AB(certificate of inspection for goods inward,certificate of inspection for goods outward)。VAT:17.0%。tax rebate rate:9.0%。MFN tariff:6.5%。general tariff:30.0%

 Articles1

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Investigation of fine-structure of polyamide thin-film composite membrane under swelling effect by positron annihilation lifetime spectroscopy and molecular dynamics simulation. Huang YH, et al.

J. Memb. Sci. 417-418 , 201–209, (2012)

 Synonyms

3,6-endomethylene-1,2,3,6-tetrahydrophtaloyl chloride
endo,exo-bicyclo[2,2,1]-hept-5-ene-2,3-dicarboxylic acid chloride
3,6-ENDOMETHYLENE-1,2,3,6-TETRAHYDROPHTHALOYL CHLORIDE
trans-bicyclo[2.2.1]hept-5-ene-2,3-dicarbonyl dichloride
trans-bicyclo(2.2.1)hept-5-enyl-2,3-dicarbonylchloride
trans-3,6-endo-Methylene-1,2,3,6-tetrahydrophthaloyl chloride
EINECS 224-967-5
MFCD00167567
endo,exo-bicyclo[2.2.1]hept-5-ene-2,3-dicarboxylic acid dichloride
endo,exo-bicyclo[2.2.1]hept-2-ene-5,6-dicarboxylic acid dichloride
trans-5-norbornene-3-dicarbonylchloride
(2-endo,3-exo)-bicyclo[2.2.1]hept-5-ene-2,3-dicarbonyl dichloride
5-NORBORNENE-2,3-DICARBONYL CHLORIDE
endo,exo-norbornene-2,3-dicarboxylic acid dichloride
BICYCLO[2.2.1]-5-HEPTENE-2,3-DICARBONYL CHLORIDE
(+/-)-trans-norborn-5-ene-2,3-dicarbonyl dichloride
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