1,4-benzenediboronic acid

Modify Date: 2025-08-20 05:29:01

1,4-benzenediboronic acid Structure
1,4-benzenediboronic acid structure
Common Name 1,4-benzenediboronic acid
CAS Number 4612-26-4 Molecular Weight 165.75
Density 1.3±0.1 g/cm3 Boiling Point 420.1±55.0 °C at 760 mmHg
Molecular Formula C6H8B2O4 Melting Point >350 °C(lit.)
MSDS Chinese USA Flash Point 207.9±31.5 °C
Symbol GHS07
GHS07
Signal Word Warning

 Use of 1,4-benzenediboronic acid


1,4-Phenylenediboronic acid is a biochemical reagent that can be used as a biological material or organic compound for life science related research.

 Names

Name 1,4-Phenylenebisboronic acid
Synonym More Synonyms

 1,4-benzenediboronic acid Biological Activity

Description 1,4-Phenylenediboronic acid is a biochemical reagent that can be used as a biological material or organic compound for life science related research.
Related Catalog
In Vitro 1,4-Phenylenediboronic acid 用于钯催化的顺序烯基化和共轭加成反应、scholl 环化、Suzuki-Miyaura 交叉偶联反应。它还用于制备中氮茚衍生物如 OLED、有机薄膜晶体管、F 荧光和可溶液加工的配位聚合物。

 Chemical & Physical Properties

Density 1.3±0.1 g/cm3
Boiling Point 420.1±55.0 °C at 760 mmHg
Melting Point >350 °C(lit.)
Molecular Formula C6H8B2O4
Molecular Weight 165.75
Flash Point 207.9±31.5 °C
Exact Mass 166.060867
PSA 80.92000
LogP 0.96
Vapour Pressure 0.0±1.0 mmHg at 25°C
Index of Refraction 1.555
InChIKey BODYVHJTUHHINQ-UHFFFAOYSA-N
SMILES OB(O)c1ccc(B(O)O)cc1
Storage condition 0-6°C

 Safety Information

Symbol GHS07
GHS07
Signal Word Warning
Hazard Statements H302
Personal Protective Equipment dust mask type N95 (US);Eyeshields;Gloves
Hazard Codes Xn:Harmful;
Risk Phrases R22
Safety Phrases S36
RIDADR NONH for all modes of transport
WGK Germany 3
HS Code 29310095

 Synthetic Route

~89%

1,4-benzenediboronic acid Structure

1,4-benzenedibo...

CAS#:4612-26-4

Literature: Kuritani, Masumi; Tashiro, Shohei; Shionoya, Mitsuhiko Chemistry - An Asian Journal, 2013 , vol. 8, # 7 p. 1368 - 1371

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1,4-benzenediboronic acid Structure

1,4-benzenedibo...

CAS#:4612-26-4

Literature: Nielsen, D. R.; McEwen, W. E. Journal of the American Chemical Society, 1957 , vol. 79, p. 3081 - 3084

~84%

1,4-benzenediboronic acid Structure

1,4-benzenedibo...

CAS#:4612-26-4

Detail
Literature: Mandolesi, Sandra D.; Vaillard, Santiago E.; Podesta, Julio C.; Rossi, Roberto A. Organometallics, 2002 , vol. 21, # 22 p. 4886 - 4888

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1,4-benzenediboronic acid Structure

1,4-benzenedibo...

CAS#:4612-26-4

Literature: Chen, Tse-An; Lee, Te-Ju; Lin, Ming-Yuan; Sohel, Shariar M. A.; Diau, Eric Wei-Guang; Lush, Shie-Fu; Liu, Rai-Shung Chemistry - A European Journal, 2010 , vol. 16, # 6 p. 1826 - 1833

~%

1,4-benzenediboronic acid Structure

1,4-benzenedibo...

CAS#:4612-26-4

Literature: Nielsen, D. R.; McEwen, W. E. Journal of the American Chemical Society, 1957 , vol. 79, p. 3081 - 3084 Full Text View citing articles Show Details Gmelin Handbook: B: B-Verb.9, 5.2.8.3, page 226 - 229

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1,4-benzenediboronic acid Structure

1,4-benzenedibo...

CAS#:4612-26-4

Literature: Lemonnier, Jean-Francois; Guenee, Laure; Beuchat, Cesar; Wesolowski, Tomasz A.; Mukherjee, Prasun; Waldeck, David H.; Gogick, Kristy A.; Petoud, Stephane; Piguet, Claude Journal of the American Chemical Society, 2011 , vol. 133, # 40 p. 16219 - 16234

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1,4-benzenediboronic acid Structure

1,4-benzenedibo...

CAS#:4612-26-4

Literature: Coutts,I.G.C. et al. Journal of the Chemical Society [Section] C: Organic, 1970 , p. 488 - 493

 Customs

HS Code 2916399090
Summary 2916399090 other aromatic monocarboxylic acids, their anhydrides, halides, peroxides, peroxyacids and their derivatives VAT:17.0% Tax rebate rate:9.0% Supervision conditions:none MFN tariff:6.5% General tariff:30.0%

 Articles10

More Articles
Constructing Regioregular Star Poly(3-hexylthiophene) via Externally Initiated Kumada Catalyst-Transfer Polycondensation Yuan, M.; et al.

ACS Macro Lett. 3rd ed., 1 , 392-395, (2012)

Multifunctional electron-transporting indolizine derivatives for highly efficient blue fluorescence, orange phosphorescence host and two-color based white OLEDs Wan, J.; et al.

J. Mater. Chem. 10th ed., 22 , 4502-4510, (2012)

Energy transfer from fluorene-based conjugated polyelectrolytes to on-chain and self-assembled porphyrin units Marques, A. T.; et al.

J. Polym. Sci. 7th ed., 50 , 1408-1417, (2012)

 Synonyms

1,4-benzeendiboronic acid
p-phenyldiboronic acid
1,4-Phenylenediboronic acid
1,4-benzenediboronic acid
MFCD00236018
4-(dihydroxyboryl)phenylboronic acid
4-bis(dihydroxyboryl)benzene
1,4-Phenylenebisboronic
benzene-1,4-diyldiboronic acid
1,4-Benzendiboronic acid
1,4-Phenyldiboronic acid
benzene-1,4-diboronic acid
p-phenylenebis(dihydroxyborane)
Boronic acid, B,B'-1,4-phenylenebis-
P-PHENYLENEDIBORONIC ACID
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