3-Methoxy-2-cyclopenten-1-one
3-Methoxy-2-cyclopenten-1-one structure
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Common Name | 3-Methoxy-2-cyclopenten-1-one | ||
|---|---|---|---|---|
| CAS Number | 4683-50-5 | Molecular Weight | 112.127 | |
| Density | 1.1±0.1 g/cm3 | Boiling Point | 214.9±29.0 °C at 760 mmHg | |
| Molecular Formula | C6H8O2 | Melting Point | 49-53ºC(lit.) | |
| MSDS | Chinese USA | Flash Point | 96.5±17.8 °C | |
| Name | 3-methoxycyclopent-2-en-1-one |
|---|---|
| Synonym | More Synonyms |
| Density | 1.1±0.1 g/cm3 |
|---|---|
| Boiling Point | 214.9±29.0 °C at 760 mmHg |
| Melting Point | 49-53ºC(lit.) |
| Molecular Formula | C6H8O2 |
| Molecular Weight | 112.127 |
| Flash Point | 96.5±17.8 °C |
| Exact Mass | 112.052429 |
| PSA | 26.30000 |
| LogP | -0.04 |
| Vapour Pressure | 0.2±0.4 mmHg at 25°C |
| Index of Refraction | 1.467 |
| Personal Protective Equipment | Eyeshields;Gloves;type N95 (US);type P1 (EN143) respirator filter |
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| RIDADR | NONH for all modes of transport |
| HS Code | 2914509090 |
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~95%
3-Methoxy-2-cyc... CAS#:4683-50-5 |
| Literature: Chandrasekhar; Srinivasa Rao; Ramakrishna Reddy Synlett, 2005 , # 9 art. no. D04705ST, p. 1471 - 1473 |
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~94%
3-Methoxy-2-cyc... CAS#:4683-50-5 |
| Literature: Schule, Arnaud; Liang, Huan; Vors, Jean-Pierre; Ciufolini, Marco A. Journal of Organic Chemistry, 2009 , vol. 74, # 4 p. 1587 - 1597 |
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~55%
3-Methoxy-2-cyc... CAS#:4683-50-5 |
| Literature: Tumer, Seniz U.; Herndon, James W.; McMullen, Leonard A. Journal of the American Chemical Society, 1992 , vol. 114, # 22 p. 8394 - 8404 |
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~78%
3-Methoxy-2-cyc... CAS#:4683-50-5 |
| Literature: Mphahlele, Malose J.; Modro, Tomasz A. Journal of Organic Chemistry, 1995 , vol. 60, # 25 p. 8236 - 8240 |
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~%
3-Methoxy-2-cyc... CAS#:4683-50-5 |
| Literature: House,H.O.; Rasmusson,G.H. Journal of Organic Chemistry, 1963 , vol. 28, p. 27 - 30 |
|
~6%
3-Methoxy-2-cyc... CAS#:4683-50-5 |
| Literature: Herndon, James W.; Tumer, Seniz U. Tetrahedron Letters, 1989 , vol. 30, # 3 p. 295 - 296 |
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~%
3-Methoxy-2-cyc... CAS#:4683-50-5 |
| Literature: Mironov,V.A. et al. Bulletin of the Academy of Sciences of the USSR, Division of Chemical Science (English Translation), 1973 , vol. 22, p. 570 - 573 Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, 1973 , vol. 22, # 3 p. 596 - 599 |
|
~%
3-Methoxy-2-cyc... CAS#:4683-50-5 |
| Literature: Mironov,V.A. et al. Bulletin of the Academy of Sciences of the USSR, Division of Chemical Science (English Translation), 1973 , vol. 22, p. 570 - 573 Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, 1973 , vol. 22, # 3 p. 596 - 599 |
| Precursor 8 | |
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| DownStream 10 | |
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CAS#:62966-17-0| HS Code | 2914509090 |
|---|---|
| Summary | HS:2914509090 other ketones with other oxygen function VAT:17.0% Tax rebate rate:9.0% Supervision conditions:none MFN tariff:5.5% General tariff:30.0% |
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Synthesis and structure-activity relationship of cyclopentenone oximes as novel inhibitors of the production of tumor necrosis factor-α.
Bioorg. Med. Chem. Lett. 24(13) , 2807-10, (2014) 3-Alkyl-2-aryl-2-cyclopenten-1-one oxime derivatives (1) were studied as a novel class of inhibitors of tumor necrosis factor α (TNF-α) with regard to synthesis and in vitro SAR inhibition of TNF-α. T... |
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Stereoselective α-quaternization of 3-methoxycycloalk-2-enones via 1,4-diastereoinduction of alkoxy dienolates.
J. Org. Chem. 77(2) , 1202-7, (2012) The alkylation of dienolates generated from 3-methoxycycloalk-2-enones having a 3'-hydroxyl alkenyl chain provides the corresponding quaternized cycloalkenones in a highly diastereoselective manner. T... |
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Expanding the scope of asymmetric electrophilic atom-transfer reactions: titanium- and ruthenium-catalyzed hydroxylation of beta-ketoesters.
Proc. Natl. Acad. Sci. U. S. A. 101(16) , 5810-4, (2004) The enantioselective formation of a quaternary stereogenic center coinciding with a hydroxylation process is a very rare reaction from a homogeneous catalysis point of view. Indeed, to our knowledge, ... |
| 3-Methoxycyclopent-2-enone |
| 3-Methoxy-2-cyclopenten-1-one |
| 1-methoxy-2-cyclopenten-1-one |
| 3-methoxy-cyclopent-2-en-1-one |
| 3-methoxycyclopent-2-ene-1-one |
| MFCD00192267 |
| 2-Cyclopenten-1-one, 3-methoxy- |
| 3-Methoxycyclopent-2-en-1-one |
| 3-methoxy-2-cyclopentene-1-one |