dioxido-oxo-tert-butyl-phosphorane

Modify Date: 2024-01-11 17:40:46

dioxido-oxo-tert-butyl-phosphorane Structure
dioxido-oxo-tert-butyl-phosphorane structure
Common Name dioxido-oxo-tert-butyl-phosphorane
CAS Number 4923-84-6 Molecular Weight 138.10200
Density 1.083 (estimate) Boiling Point 255.4ºC at 760 mmHg
Molecular Formula C4H11O3P Melting Point 187-189ºC(lit.)
MSDS Chinese USA Flash Point 108.3ºC
Symbol GHS05
GHS05
Signal Word Danger

 Names

Name tert-Butylphosphonic acid
Synonym More Synonyms

 Chemical & Physical Properties

Density 1.083 (estimate)
Boiling Point 255.4ºC at 760 mmHg
Melting Point 187-189ºC(lit.)
Molecular Formula C4H11O3P
Molecular Weight 138.10200
Flash Point 108.3ºC
Exact Mass 138.04500
PSA 67.34000
LogP 0.96260
Appearance of Characters Crystalline Powder | White

 Safety Information

Symbol GHS05
GHS05
Signal Word Danger
Hazard Statements H314
Precautionary Statements P280-P305 + P351 + P338-P310
Personal Protective Equipment Eyeshields;Faceshields;full-face particle respirator type N100 (US);Gloves;respirator cartridge type N100 (US);type P1 (EN143) respirator filter;type P3 (EN 143) respirator cartridges
Hazard Codes C
Risk Phrases 34
Safety Phrases 26-27-28-36/37/39-45
RIDADR UN 3261 8/PG 2
WGK Germany 3
Packaging Group III

 Synthetic Route

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dioxido-oxo-tert-butyl-phosphorane Structure

dioxido-oxo-ter...

CAS#:4923-84-6

Literature: Wozniak, Michel; Nowogrocki, Guy Journal of the Chemical Society, Dalton Transactions: Inorganic Chemistry (1972-1999), 1981 , p. 2423 - 2428

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dioxido-oxo-tert-butyl-phosphorane Structure

dioxido-oxo-ter...

CAS#:4923-84-6

Literature: Feshchenko,N.G.; Mel'nichuk,E.A. J. Gen. Chem. USSR (Engl. Transl.), 1978 , vol. 48, p. 365 - 368,329 - 332

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dioxido-oxo-tert-butyl-phosphorane Structure

dioxido-oxo-ter...

CAS#:4923-84-6

Literature: Murav'ev,I.V.; Fedorovich,I.S. J. Gen. Chem. USSR (Engl. Transl.), 1976 , vol. 46, p. 1262 - 1264,1241 - 1243

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dioxido-oxo-tert-butyl-phosphorane Structure

dioxido-oxo-ter...

CAS#:4923-84-6

Literature: Quast, Helmut; Heuschmann, Manfred; Abdel-Rahman, Mohamed O. Liebigs Annalen der Chemie, 1981 , # 5 p. 943 - 966

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dioxido-oxo-tert-butyl-phosphorane Structure

dioxido-oxo-ter...

CAS#:4923-84-6

Literature: Quast, Helmut; Heuschmann, Manfred; Abdel-Rahman, Mohamed O. Liebigs Annalen der Chemie, 1981 , # 5 p. 943 - 966

~%

dioxido-oxo-tert-butyl-phosphorane Structure

dioxido-oxo-ter...

CAS#:4923-84-6

Literature: Murav'ev,I.V.; Fedorovich,I.S. J. Gen. Chem. USSR (Engl. Transl.), 1975 , vol. 45, p. 1746 - 1748,1711 - 1713

 Articles5

More Articles
Borophosphonate cages: easily accessible and constitutionally dynamic heterocubane scaffolds.

Chemistry 18(32) , 9939-45, (2012)

A versatile and experimentally facile procedure for the synthesis of borophosphonate cages of the general formula [tBuPO(3)BR'](4) is described. The method involves heating of tert-butylphosphonic aci...

Hexanuclear copper(II) cages built on a central {μ3-O···H···μ3-O} moiety, 1,3-bis(dimethylamino)-2-propanolato and capping R-phosphonates: crystal structures, magnetic behavior, and DFT studies.

Inorg. Chem. 51(12) , 6842-50, (2012)

The syntheses, structural characterization, and magnetic behavior of two new hexanuclear copper(II) complexes derived from R-phosphonic acids and 1,3-bis(dimethylamino)-2-propanol (Hbdmap) with formul...

Multicomponent assembly of anionic and neutral decanuclear copper(II) phosphonate cages.

Inorg. Chem. 51(10) , 5605-16, (2012)

A multicomponent synthetic strategy involving copper(II) ions, tert-butylphosphonic acid (t-BuPO(3)H(2)) and 3-substituted pyrazole ligands has been adopted for the synthesis of soluble molecular copp...

 Synonyms

MFCD00012296
tert-butylphosphonic acid