1-cyano-N-phenylmethanethioamide

Modify Date: 2024-01-06 10:35:50

1-cyano-N-phenylmethanethioamide Structure
1-cyano-N-phenylmethanethioamide structure
Common Name 1-cyano-N-phenylmethanethioamide
CAS Number 4955-82-2 Molecular Weight 162.21200
Density 1.31g/cm3 Boiling Point 258ºC at 760 mmHg
Molecular Formula C8H6N2S Melting Point 77-80ºC(lit.)
MSDS N/A Flash Point 109.8ºC

 Names

Name 1-cyano-N-phenylmethanethioamide
Synonym More Synonyms

 Chemical & Physical Properties

Density 1.31g/cm3
Boiling Point 258ºC at 760 mmHg
Melting Point 77-80ºC(lit.)
Molecular Formula C8H6N2S
Molecular Weight 162.21200
Flash Point 109.8ºC
Exact Mass 162.02500
PSA 67.91000
LogP 2.02248
Index of Refraction 1.697

 MSDS

Name: 1-Cyanothioformanilide 97% Material Safety Data Sheet
Synonym: None
CAS: 4955-82-2
Section 1 - Chemical Product MSDS Name:1-Cyanothioformanilide 97% Material Safety Data Sheet
Synonym:None

Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
CAS# Chemical Name content EINECS#
4955-82-2 1-Cyanothioformanilide 97% unlisted
Hazard Symbols: XI
Risk Phrases: 36/37/38

Section 3 - HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW
Irritating to eyes, respiratory system and skin.The toxicological properties of this material have not been fully investigated.
Potential Health Effects
Eye:
Causes eye irritation.
Skin:
Causes skin irritation.
Ingestion:
Causes gastrointestinal irritation with nausea, vomiting and diarrhea. The toxicological properties of this substance have not been fully investigated.
Inhalation:
Causes respiratory tract irritation. The toxicological properties of this substance have not been fully investigated.
Chronic:
No information found.

Section 4 - FIRST AID MEASURES
Eyes: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid.
Skin:
Get medical aid. Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse.
Ingestion:
Never give anything by mouth to an unconscious person. Get medical aid. Do NOT induce vomiting. If conscious and alert, rinse mouth and drink 2-4 cupfuls of milk or water.
Inhalation:
Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid.
Notes to Physician:
Treat symptomatically and supportively.

Section 5 - FIRE FIGHTING MEASURES
General Information:
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion.
Extinguishing Media:
Use agent most appropriate to extinguish fire. Use water spray, dry chemical, carbon dioxide, or appropriate foam.

Section 6 - ACCIDENTAL RELEASE MEASURES
General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks:
Vacuum or sweep up material and place into a suitable disposal container. Clean up spills immediately, observing precautions in the Protective Equipment section. Avoid generating dusty conditions.
Provide ventilation.

Section 7 - HANDLING and STORAGE
Handling:
Wash thoroughly after handling. Use with adequate ventilation.
Minimize dust generation and accumulation. Avoid contact with eyes, skin, and clothing. Keep container tightly closed. Avoid ingestion and inhalation. Wash clothing before reuse.
Storage:
Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances.

Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION
Engineering Controls:
Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate ventilation to keep airborne concentrations low.
Exposure Limits CAS# 4955-82-2: Personal Protective Equipment Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin exposure.
Respirators:
A respiratory protection program that meets OSHA's 29 CFR 1910.134 and ANSI Z88.2 requirements or European Standard EN 149 must be followed whenever workplace conditions warrant respirator use.

Section 9 - PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Solid
Color: brown
Odor: Not available.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point: 77-80C
Autoignition Temperature: Not applicable.
Flash Point: Not applicable.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water:
Specific Gravity/Density:
Molecular Formula: C8H6N2S
Molecular Weight: 162.1154

Section 10 - STABILITY AND REACTIVITY
Chemical Stability:
Stable at room temperature in closed containers under normal storage and handling conditions.
Conditions to Avoid:
Incompatible materials, dust generation, excess heat.
Incompatibilities with Other Materials:
Oxidizing agents.
Hazardous Decomposition Products:
Carbon monoxide, oxides of nitrogen, oxides of sulfur, irritating and toxic fumes and gases, carbon dioxide.
Hazardous Polymerization: Has not been reported

Section 11 - TOXICOLOGICAL INFORMATION
RTECS#:
CAS# 4955-82-2 unlisted.
LD50/LC50:
Not available.
Carcinogenicity:
1-Cyanothioformanilide - Not listed by ACGIH, IARC, or NTP.

Section 12 - ECOLOGICAL INFORMATION


Section 13 - DISPOSAL CONSIDERATIONS
Dispose of in a manner consistent with federal, state, and local regulations.

Section 14 - TRANSPORT INFORMATION

IATA
Shipping Name: NITRILES, SOLID, TOXIC, N.O.S.*
Hazard Class: 6.1
UN Number: 3276
Packing Group: III
IMO
Shipping Name: NITRILES, TOXIC, N.O.S.
Hazard Class: 6.1
UN Number: 3276
Packing Group: III
RID/ADR
Shipping Name: NITRILES, TOXIC, N.O.S.
Hazard Class: 6.1
UN Number: 3276
Packing group: III

Section 15 - REGULATORY INFORMATION

European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XI
Risk Phrases:
R 36/37/38 Irritating to eyes, respiratory system
and skin.
Safety Phrases:
S 28A After contact with skin, wash immediately with
plenty of water.
S 37 Wear suitable gloves.
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
WGK (Water Danger/Protection)
CAS# 4955-82-2: No information available.
Canada
None of the chemicals in this product are listed on the DSL/NDSL list.
CAS# 4955-82-2 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 4955-82-2 is not listed on the TSCA inventory.
It is for research and development use only.


SECTION 16 - ADDITIONAL INFORMATION
N/A

 Safety Information

Hazard Codes Xn
Risk Phrases 20/21/22-36/37/38
Safety Phrases 26-37/39
HS Code 2930909090

 Synthetic Route

~%

1-cyano-N-phenylmethanethioamide Structure

1-cyano-N-pheny...

CAS#:4955-82-2

Literature: Reissert Chemische Berichte, 1904 , vol. 37, p. 3730

~%

1-cyano-N-phenylmethanethioamide Structure

1-cyano-N-pheny...

CAS#:4955-82-2

Literature: Reissert Chemische Berichte, 1904 , vol. 37, p. 3730

~%

1-cyano-N-phenylmethanethioamide Structure

1-cyano-N-pheny...

CAS#:4955-82-2

Literature: Kalle and Co. Patent: DE410471 ; Fortschr. Teerfarbenfabr. Verw. Industriezweige, vol. 15, p. 230 Full Text Show Details Reissert; Brueggemann Chemische Berichte, 1924 , vol. 57, p. 987

~%

1-cyano-N-phenylmethanethioamide Structure

1-cyano-N-pheny...

CAS#:4955-82-2

Literature: Reissert Chemische Berichte, 1904 , vol. 37, p. 3730

~%

1-cyano-N-phenylmethanethioamide Structure

1-cyano-N-pheny...

CAS#:4955-82-2

Literature: Kalle and Co. Patent: DE410471 ; Fortschr. Teerfarbenfabr. Verw. Industriezweige, vol. 15, p. 230 Full Text Show Details Reissert; Brueggemann Chemische Berichte, 1924 , vol. 57, p. 987

~%

1-cyano-N-phenylmethanethioamide Structure

1-cyano-N-pheny...

CAS#:4955-82-2

Literature: Reissert Chemische Berichte, 1904 , vol. 37, p. 3730

~%

1-cyano-N-phenylmethanethioamide Structure

1-cyano-N-pheny...

CAS#:4955-82-2

Literature: Kalle and Co. Patent: DE410471 ; Fortschr. Teerfarbenfabr. Verw. Industriezweige, vol. 15, p. 230 Full Text Show Details Reissert; Brueggemann Chemische Berichte, 1924 , vol. 57, p. 987

 Customs

HS Code 2930909090
Summary 2930909090. other organo-sulphur compounds. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:30.0%

 Synonyms

N-Phenylcyanothioformamide
2-nitrilo-N-phenyl-thioacetamide
N-phenylcyanothioformanilide
Cyanothioformanilide
1-CYANOTHIOFORMANILIDE
MFCD00012312