N-(3-Aminopropyl)diethanolamine

Modify Date: 2024-01-02 23:32:46

N-(3-Aminopropyl)diethanolamine Structure
N-(3-Aminopropyl)diethanolamine structure
Common Name N-(3-Aminopropyl)diethanolamine
CAS Number 4985-85-7 Molecular Weight 162.230
Density 1.1±0.1 g/cm3 Boiling Point 316.5±22.0 °C at 760 mmHg
Molecular Formula C7H18N2O2 Melting Point N/A
MSDS N/A Flash Point 145.2±22.3 °C

 Names

Name N-(3-Aminopropyl)diethanolamine
Synonym More Synonyms

 Chemical & Physical Properties

Density 1.1±0.1 g/cm3
Boiling Point 316.5±22.0 °C at 760 mmHg
Molecular Formula C7H18N2O2
Molecular Weight 162.230
Flash Point 145.2±22.3 °C
Exact Mass 162.136826
PSA 69.72000
LogP -1.07
Vapour Pressure 0.0±1.5 mmHg at 25°C
Index of Refraction 1.509

 MSDS

N-(3-Aminopropyl)diethanolamine Revision number: 1
SAFETY DATA SHEET

Section1. BASE INFORMATION
Product name:N-(3-Aminopropyl)diethanolamine

Revision number:1

Section2. HAZARDS IDENTIFICATION
Classification of the GHS
PHYSICAL HAZARDSNot classified
HEALTH HAZARDS
Category 1C
Skin corrosion/irritation
Serious eye damage/eye irritationCategory 1
Not classified
ENVIRONMENTAL HAZARDS
GHS label elements
Pictograms or hazard symbols
Signal wordDanger
Hazard statementCauses severe skin burns and eye damage
Precautionary statements
[Prevention]Do not breathe.
Wash hands thoroughly after handling.
Wear protective gloves/eye protection/face protection.
[Response]IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for
breathing.
IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.
IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses,
if present and easy to do. Continue rinsing.
IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse
skin with water/shower.
Wash contaminated clothing before reuse.
Immediately call a POISON CENTER or doctor/physician.
Store locked up.
[Storage]
[Disposal]Dispose of contents/container through a waste management company authorized by
the local government

Section3. COMPOSITION/INFORMATION ON INGREDIENTS
Substance/mixture:Substance
Component(s):N-(3-Aminopropyl)diethanolamine
>90.0%(GC)
Percent:
CAS Number:4985-85-7
N,N-Bis(2-hydroxyethyl)-1,3-diaminopropane
Synonyms:
Chemical Formula:C7H18N2O2
N-(3-Aminopropyl)diethanolamine

Section4. FIRST AID MEASURES
Inhalation:Remove victim to fresh air and keep at rest in a position comfortable for breathing.
Immediately call a POISON CENTER or doctor/physician.
Skin contact:Remove/Take off immediately all contaminated clothing. Gently wash with plenty of
soap and water. Immediately call a POISON CENTER or doctor/physician.
Eye contact:Rinse cautiously with water for several minutes. Remove contact lenses, if present
and easy to do. Continue rinsing.Immediately call a POISON CENTER or
doctor/physician.
Ingestion:Immediately call a POISON CENTER or doctor/physician. Rinse mouth. Do NOT
induce vomiting.
burning sensation, difficulty in breathing, thirst, asthma, nausea, vomiting, bronchitis ,
Symptoms/effects:
diarrhoea, weakness, collapse, headache, redness, pain, burn
A rescuer should wear personal protective equipment, such as rubber gloves and air-
Protection of first-aiders:
tight goggles.

Section5. FIRE-FIGHTING MEASURES
Suitable extinguishingDry chemical, foam, water spray, carbon dioxide.
media:
Extinguishing media not to Solid streams of water
be used:
Specific hazards:Take care as it may decompose upon combustion or in high temperatures to
generate poisonous fume.
Specific methods:Fire-extinguishing work is done from the windward and the suitable fire-extinguishing
method according to the surrounding situation is used. Uninvolved persons should
evacuate to a safe place. In case of fire in the surroundings: Remove movable
containers if safe to do so.
Special protectiveWhen extinguishing fire, be sure to wear personal protective equipment.
equipment for firefighters:

Section6. ACCIDENTAL RELEASE MEASURES
Personal precautions,Use extra personal protective equipment (self-contained breathing apparatus). Keep
protective equipment and people away from and upwind of spill/leak. Ensure adequate ventilation. Entry to non-
emergency procedures: involved personnel should be controlled around the leakage area by roping off, etc.
Environmental precautions: Prevent product from entering drains.
Methods and materials for Absorb spilled material in a suitable absorbent (e.g. rag, dry sand, earth, saw-dust).
containment and cleaning In case of large amount of spillage, contain a spill by bunding. Adhered or collected
up: material should be promptly disposed of, in accordance with appropriate laws and
regulations.

Section7. HANDLING AND STORAGE
Handling
Technical measures:Handling is performed in a well ventilated place. Wear suitable protective equipment.
Prevent generation of vapor or mist. Wash hands and face thoroughly after handling.
Use a closed system if possible. Use a ventilation, local exhaust if vapor or aerosol
will be generated.
Advice on safe handling:Avoid contact with skin, eyes and clothing.
Storage
Storage conditions:Keep container tightly closed. Store in a cool and dark place.
Store under inert gas.
Protect from moisture.
Store locked up.
Store away from incompatible materials such as oxidizing agents.
Law is followed.
Packaging material:

Section8. EXPOSURE CONTROLS / PERSONAL PROTECTION
Engineering controls:Install a closed system or local exhaust. Also install safety shower and eye bath.
N-(3-Aminopropyl)diethanolamine

Section8. EXPOSURE CONTROLS / PERSONAL PROTECTION
Personal protective equipment
Respiratory protection: Half or full facepiece respirator, self-contained breathing apparatus(SCBA), supplied
air respirator, etc. Use respirators approved under appropriate government standards
and follow local and national regulations.
Hand protection:Impervious gloves.
Safety goggles. A face-shield, if the situation requires.
Eye protection:
Skin and body protection: Impervious protective clothing. Protective boots, if the situation requires.

Section9. PHYSICAL AND CHEMICAL PROPERTIES
Physical state (20°C):Liquid
clear
Form:
Color:Colorless - Slightly pale yellow
Ammoniacal
Odor:
pH: 12
Melting point/freezing point:No data available
Boiling Point/Range:207 °C
Flash Point:138°C
Explosive limits
No data available
Lower:
Upper:No data available
5.6
Vapor Density:
Density:1.07
Soluble in : Water
Solubility:

Section10. STABILITY AND REACTIVITY
Stability:Stable under proper conditions.
Reactivity:No special reactivity has been reported.
Conditions to avoid:Hygroscopic
Incompartible materials: oxidizing agents, acids
Hazardous Decomposition Carbon monoxide, Carbon dioxide, Nitrogen oxides (NOx)
Products:

Section11. TOXICOLOGICAL INFORMATION
No data available
Acute Toxicity:
Skin corrosion/irritation: No data available
No data available
Serious eye
damage/irritation:
Germ cell mutagenicity: No data available
Carcinogenicity:
No data available
IARC =
NTP =No data available
No data available
Reproductive toxicity:

Section12. ECOLOGICAL INFORMATION
Ecotoxicity:
Fish:No data available
Crustacea:No data available
Algae:No data available
Persistence / degradability: No data available
BioaccumulativeNo data available
potential(BCF):
Mobillity in soil
log Pow:No data available
Soil adsorption (Koc):No data available
Henry's LawNo data available
constant(PaM3/mol):
N-(3-Aminopropyl)diethanolamine

Section13. DISPOSAL CONSIDERATIONS
Recycle to process, if possible. Consult your local regional authorities. You may be able to burn in a chemical
incinerator equipped with an afterburner and scrubber system. Observe all federal, state and local regulations when
disposing of the substance.

Section14. TRANSPORT INFORMATION
Hazards Class:8: Corrosive.
UN-No:2735
Polyamines, liquid, corrosive, n.o.s.
Proper shipping name:
Packing group:III

Section15. REGULATORY INFORMATION
Safe management ordinance of dangerous chemical product (State Council announces on January 26,
2002): Safe use and production, the storage of a dangerous chemical, transport, loading and unloading were
prescribed.


SECTION 16 - ADDITIONAL INFORMATION
N/A

 Safety Information

Hazard Codes Xi: Irritant;
Risk Phrases R34
Safety Phrases S26-S36/37/39
RIDADR 2735
Packaging Group III
Hazard Class 8
HS Code 2922199090

 Synthetic Route

~32%

N-(3-Aminopropyl)diethanolamine Structure

N-(3-Aminopropy...

CAS#:4985-85-7

Literature: Jocher, Christoph; Pape, Tania; Hahn, F. Ekkehardt Zeitschrift fur Naturforschung - Section B Journal of Chemical Sciences, 2005 , vol. 60, # 6 p. 667 - 672

~79%

N-(3-Aminopropyl)diethanolamine Structure

N-(3-Aminopropy...

CAS#:4985-85-7

Literature: Asseline, Ulysse; Chassignol, Marcel; Draus, Jolanta; Durand, Maurice; Maurizot, Jean-Claude Bioorganic and Medicinal Chemistry, 2003 , vol. 11, # 16 p. 3499 - 3511

~%

N-(3-Aminopropyl)diethanolamine Structure

N-(3-Aminopropy...

CAS#:4985-85-7

Literature: Wingfoot Corp. Patent: US2368521 , 1942 ;

~%

N-(3-Aminopropyl)diethanolamine Structure

N-(3-Aminopropy...

CAS#:4985-85-7

Literature: Ledochowski,A. et al. Roczniki Chemii, 1969 , vol. 43, # 5 p. 1083 - 1087

 Customs

HS Code 2922199090
Summary 2922199090. other amino-alcohols, other than those containing more than one kind of oxygen function, their ethers and esters; salts thereof. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:30.0%

 Synonyms

ethanol, 2,2'-((3-aminopropyl)imino)bis-
N,N-Bis(2-hydroxyethyl)-1,3-propanediamine
N,N-Bis(2-hydroxyethyl)-1,3-diaminopropane
N,N-Di(2-hydroxyethyl)-1,3-propanediamine
2,2'-((3-Aminopropyl)imino)diethanol
2-[3-aminopropyl(2-hydroxyethyl)amino]ethanol
MFCD00047971
2,2'-[(3-Aminopropyl)imino]diethanol
EINECS 225-642-0
2,2'-((3-aminopropyl)imino)bisethanol
N-(3-Aminopropyl)diethanolamine
Ethanol, 2,2'-[(3-aminopropyl)imino]bis-