dodecylphosphonic acid

Modify Date: 2024-01-08 18:30:35

dodecylphosphonic acid Structure
dodecylphosphonic acid structure
Common Name dodecylphosphonic acid
CAS Number 5137-70-2 Molecular Weight 250.31500
Density 1.018 g/cm3 Boiling Point 383.8ºC at 760 mmHg
Molecular Formula C12H27O3P Melting Point 68-70ºC
MSDS Chinese USA Flash Point 185.9ºC

 Names

Name N-Dodecylphosphonic Acid
Synonym More Synonyms

 Chemical & Physical Properties

Density 1.018 g/cm3
Boiling Point 383.8ºC at 760 mmHg
Melting Point 68-70ºC
Molecular Formula C12H27O3P
Molecular Weight 250.31500
Flash Point 185.9ºC
Exact Mass 250.17000
PSA 67.34000
LogP 4.08500
Index of Refraction 1.462

 MSDS


Section 1: Product Identification
Chemical Name:n-Dodecylphosphonic acid, min. 97%
CAS Registry Number:5137-70-2
Formula:CH3(CH2)11P(O)(OH)2
EINECS Number:225-897-8
Chemical Family:organic phosphonic acid
Synonym:1-Dodecanephosphonic acid

Section 2: Composition and Information on Ingredients
IngredientCAS NumberPercentACGIH (TWA)OSHA (PEL)
Title compound5137-70-2100%no datano data

Section 3: Hazards Identification
Emergency Overview:Irritating to skin, eyes and respiratory tract.
Primary Routes of Exposure:Inhalation, skin, eyes
Eye Contact:Dust causes moderate to severe irritation of the eyes.
Skin Contact:Causes irritation to the skin
Inhalation:Causes irritation to the nose, mucous membranes and respiratory tract
Ingestion:No information on the physiological effects of ingestion. May be harmful if swallowed.
Acute Health Affects:Irritating to skin, eyes and respiratory tract.
Chronic Health Affects:No information available on long-term chronic effects
NTP:No
IARC:No
OSHA:No

SECTION 4: First Aid Measures
Immediately flush the eyes with copious amounts of water for at least 10-15 minutes. A victim may need
Eye Exposure:
assistance in keeping their eye lids open. Get immediate medical attention.
Wash the affected area with water. Remove contaminated clothes if necessary. Seek medical assistance if
Skin Exposure:
irritation persists.
Remove the victim to fresh air. Closely monitor the victim for signs of respiratory problems, such as difficulty
Inhalation:
in breathing, coughing, wheezing, or pain. In such cases seek immediate medical assistance.
Seek medical attention immediately. Keep the victim calm. Give the victim water (only if conscious). Induce
Ingestion:
vomiting only if directed by medical personnel.

SECTION 5: Fire Fighting Measures
Flash Point:no data
Autoignition Temperature:no data
Explosion Limits:no data
Extinguishing Medium:carbon dioxide, dry chemical or foam
If this product is involved in a fire, fire fighters should be equipped with a NIOSH approved positive pressure
Special Fire Fighting Procedures:
self-contained breathing apparatus and full protective clothing.
Hazardous Combustion andIf involved in a fire, this material may emit irritating organic fumes
Decomposion Products:
Unusual Fire or Explosion Hazards: No unusual fire or explosion hazards

SECTION 6: Accidental Release Measures
Small spills can be mixed with vermiculite, sodium carbonate or other suitable non-combustible adsorbent and
Spill and Leak Procedures:
swept up.

SECTION 7: Handling and Storage
Handling and Storage:Store in a tightly sealed container in a cool, dry place.

SECTION 8: Exposure Controls and Personal Protection
Eye Protection:Always wear approved safety glasses when handling a chemical substance in the laboratory.
Skin Protection:Wear protective clothing and gloves. Consult with glove manufacturer to determine the proper type of glove.
Ventilation:It is imperative that this material be handled in an efficient fume hood.
If ventilation is not available a respirator should be worn. The use of respirators requires a Respirator
Respirator:
Protection Program to be in compliance with 29 CFR 1910.134.
Ventilation:It is imperative that this material be handled in an efficient fume hood.
Additional Protection:No additional protection required.

SECTION 9: Physical and Chemical Properties
Color and Form:white to off-white powder
Molecular Weight:250.31
Melting Point:96-98°
Boiling Point:no data
Vapor Pressure:no data
Specific Gravity:no data
Odor:not determined
Solubility in Water:insoluble

SECTION 10: Stability and Reactivity
Stability:air and moisture stable
Hazardous Polymerization:no hazardous polymerization
Conditions to Avoid:none
Incompatibility:oxidizing agents
Decomposition Products:carbon dioxide, carbon monoxide and organic fumes

SECTION 11: Toxicological Information
RTECS Data:Intraperitoneal(mouse); LDLo: 500mg/kg.
Carcinogenic Effects:no data
Mutagenic Effects:no data
Tetratogenic Effects:no data

SECTION 12: Ecological Information
Ecological Information:No information available

SECTION 13: Disposal Considerations
Disposal:Dispose of according to local, state and federal regulations

SECTION 14: Transportation
Shipping Name (CFR):Non-hazardous
Hazard Class (CFR):NA
Additional Hazard Class (CFR):NA
Packaging Group (CFR):NA
UN ID Number (CFR):NA
Shipping Name (IATA):Non-hazardous
Hazard Class (IATA):NA
Additional Hazard Class (IATA):NA
Packaging Group (IATA):NA
UN ID Number (IATA):NA

SECTION 15: Regulatory Information
TSCA:Listed in the TSCA inventory
SARA (Title 313):Title compound not listed
Second Ingredient:none


SECTION 16 - ADDITIONAL INFORMATION
N/A

 Toxicological Information

CHEMICAL IDENTIFICATION

RTECS NUMBER :
SZ7875000
CHEMICAL NAME :
Phosphonic acid, dodecyl-
CAS REGISTRY NUMBER :
5137-70-2
BEILSTEIN REFERENCE NO. :
1778341
LAST UPDATED :
199712
DATA ITEMS CITED :
4
MOLECULAR FORMULA :
C12-H27-O3-P
MOLECULAR WEIGHT :
250.36
WISWESSER LINE NOTATION :
QPQO&12

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :
LDLo - Lowest published lethal dose
ROUTE OF EXPOSURE :
Intraperitoneal
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
500 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
CBCCT* "Summary Tables of Biological Tests," National Research Council Chemical-Biological Coordination Center. (National Academy of Science Library, 2101 Constitution Ave., NW, Washington, DC 20418) Volume(issue)/page/year: 9,132,1957

 Safety Information

Hazard Codes C
RIDADR UN3261
Packaging Group III
Hazard Class 8.0
HS Code 2931900090

 Synthetic Route

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dodecylphosphonic acid Structure

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CAS#:5137-70-2

Literature: Macromolecules, , vol. 38, # 6 p. 2230 - 2236

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CAS#:5137-70-2

Literature: Journal of the American Chemical Society, , vol. 67, p. 1182 US2397422 , ;

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CAS#:5137-70-2

Literature: Macromolecules, , vol. 38, # 6 p. 2230 - 2236

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CAS#:5137-70-2

Literature: Synthetic Communications, , vol. 33, # 12 p. 2151 - 2159

 Customs

HS Code 2931900090
Summary 2931900090. other organo-inorganic compounds. VAT:17.0%. Tax rebate rate:13.0%. Supervision conditions:AB(certificate of inspection for goods inward,certificate of inspection for goods outward). MFN tariff:6.5%. General tariff:30.0%

 Articles2

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Acc. Chem. Res. 45 , 337, (2012)

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Heteroatom Chem. 20 , 369-377, (2009)

 Synonyms

EINECS 225-897-8
1-Dodecylphosphonic acid
dodecylphosphonic acid
MFCD00015832
N-DODECYLPHOSPHONIC ACID