Tris[triphenylphosphinegold(I)]oxonium tetrafluoroborate

Modify Date: 2024-01-07 18:01:44

Tris[triphenylphosphinegold(I)]oxonium tetrafluoroborate Structure
Tris[triphenylphosphinegold(I)]oxonium tetrafluoroborate structure
Common Name Tris[triphenylphosphinegold(I)]oxonium tetrafluoroborate
CAS Number 53317-87-6 Molecular Weight 1480.56000
Density N/A Boiling Point N/A
Molecular Formula C54H45Au3BF4OP3 Melting Point 207ºC (dec.)
MSDS Chinese USA Flash Point N/A
Symbol GHS07
GHS07
Signal Word Warning

 Names

Name oxidanium,gold,triphenylphosphane,tetrafluoroborate
Synonym More Synonyms

 Chemical & Physical Properties

Melting Point 207ºC (dec.)
Molecular Formula C54H45Au3BF4OP3
Molecular Weight 1480.56000
Exact Mass 1480.17000
PSA 50.00000
LogP 11.55850
Storage condition 2-8°C

 Safety Information

Symbol GHS07
GHS07
Signal Word Warning
Hazard Statements H315-H319-H335
Precautionary Statements P280-P304 + P340 + P312-P305 + P351 + P338-P337 + P313
Personal Protective Equipment dust mask type N95 (US);Eyeshields;Gloves
Hazard Codes Xi
Risk Phrases 36/37/38
Safety Phrases 26-36/37/39
RIDADR NONH for all modes of transport

 Synthetic Route

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Tris[triphenylphosphinegold(I)]oxonium tetrafluoroborate Structure

Tris[triphenylp...

CAS#:53317-87-6

Literature: Grohmann, Andreas; Riede, Juergen; Schmidbaur, Hubert Journal of the Chemical Society, Dalton Transactions: Inorganic Chemistry (1972-1999), 1991 , p. 783 - 788

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Tris[triphenylphosphinegold(I)]oxonium tetrafluoroborate Structure

Tris[triphenylp...

CAS#:53317-87-6

Detail
Literature: Grohmann, Andreas; Riede, Juergen; Schmidbaur, Hubert Zeitschrift fuer Naturforschung, B: Chemical Sciences, 1992 , vol. 47, # 9 p. 1255 - 1260

~14%

Tris[triphenylphosphinegold(I)]oxonium tetrafluoroborate Structure

Tris[triphenylp...

CAS#:53317-87-6

Literature: Banditelli, Guido; Bandini, Anna Laura; Bonati, Flavio; Goel, Ram G.; Minghetti, Giovanni Gazzetta Chimica Italiana, 1982 , vol. 112, p. 539 - 542

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Tris[triphenylphosphinegold(I)]oxonium tetrafluoroborate Structure

Tris[triphenylp...

CAS#:53317-87-6

Literature: Cinellu, Maria Agostina; Stoccoru, Sergio; Minghetti, Giovanni; Bandini, Anna Laura; Demartin, Francesco Inorganica Chimica Acta, 1990 , vol. 168, p. 33 - 42

 Articles1

More Articles
Gold(I)-catalyzed propargyl Claisen rearrangement.

J. Am. Chem. Soc. 126 , 15978, (2004)

Homoallenic alcohols are prepared from propargyl vinyl ethers using a trinuclear gold(I)-oxo complex, [(Ph3PAu)3O]BF4, as a catalyst for propargyl Claisen rearrangement at room temperature. The gold(I...

 Synonyms

tris[(triphenylphosphane)gold(I)]oxonium tetrafluoroborate
tris[(triphenylphosphino)aurio(I)]oxonium tetrafluoroborate
MFCD06658141
[(PPh3Au)3O]BF4
[(Ph3PAu)3O]BF4
TRIS[TRIPHENYLPHOSPHINEGOLD(I)]OXONIUM TETRAFLUOROBORATE
Oxotris(triphenylphosphine)trigold tetrafluoroborate
Oxotris((triphenylphosphine)gold) tetrafluoroborate
[Au(PPh3)O]BF4
{[(triphenylphosphino)Au]3O}BF4
Tris(triphenylphosphinegold)oxonium tetrafluoroborate
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