Copper cyanide structure
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Common Name | Copper cyanide | ||
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CAS Number | 544-92-3 | Molecular Weight | 89.56340 | |
Density | 2.92 g/mL at 25 °C(lit.) | Boiling Point | N/A | |
Molecular Formula | CCuN | Melting Point | 474 °C(lit.) | |
MSDS | Chinese USA | Flash Point | 140°C(lit.) | |
Symbol |
GHS06, GHS09 |
Signal Word | Danger |
Name | Copper(I) cyanide |
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Synonym | More Synonyms |
Density | 2.92 g/mL at 25 °C(lit.) |
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Melting Point | 474 °C(lit.) |
Molecular Formula | CCuN |
Molecular Weight | 89.56340 |
Flash Point | 140°C(lit.) |
Exact Mass | 88.93270 |
PSA | 23.79000 |
LogP | 0.01428 |
Stability | Stable. Incompatible with acids, bases, magnesium. Reacts violently with oxidizing agents, nitrates. Reaction with acid releases highly toxic gas (HCN). |
CHEMICAL IDENTIFICATION
HEALTH HAZARD DATAACUTE TOXICITY DATA
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Symbol |
GHS06, GHS09 |
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Signal Word | Danger |
Hazard Statements | H300 + H310 + H330-H410 |
Supplemental HS | Contact with acids liberates very toxic gas. |
Precautionary Statements | P260-P264-P273-P280-P284-P301 + P310 |
Hazard Codes | T+:Verytoxic;N:Dangerous for the environment; |
Risk Phrases | R26/27/28;R32 |
Safety Phrases | S7-S28-S29-S45-S60-S61 |
RIDADR | UN 1587 6.1/PG 2 |
WGK Germany | 2 |
RTECS | GL7150000 |
Packaging Group | II |
Hazard Class | 6.1 |
HS Code | 2837199011 |
~% Copper cyanide CAS#:544-92-3 |
Literature: WO2004/14357 A2, ; Page/Page column 35-36 ; |
~% Copper cyanide CAS#:544-92-3 |
Literature: Chim. et Ind. Sonderband 18. Congr. Chim. ind. Nancy, , p. 420 Chem. Zentralbl., , vol. 110, # II p. 2902 |
~% Copper cyanide CAS#:544-92-3 |
Literature: Varet, R. Comptes Rendus Hebdomadaires des Seances de l'Academie des Sciences, 1895 , vol. 121, p. 598 - 599 Full Text Show Details Gmelin Handbook: Cu: MVol.B1, 183, page 404 - 406 |
~% Copper cyanide CAS#:544-92-3 |
Literature: Journal of the Chemical Society, vol. 125, p. 1667 |
~% Copper cyanide CAS#:544-92-3 |
Literature: Ann. Chim. Phys., , vol. 8, p. 240 - 288 Comptes Rendus Hebdomadaires des Seances de l'Academie des Sciences, , vol. 110, p. 147 - 149 |
~0% Copper cyanide CAS#:544-92-3 |
Literature: Varet, R. Ann. Chim. Phys., 1896 , vol. 8, p. 240 - 288 |
Precursor 6 | |
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DownStream 9 | |
HS Code | 2926909090 |
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Summary | HS:2926909090 other nitrile-function compounds VAT:17.0% Tax rebate rate:9.0% Supervision conditions:none MFN tariff:6.5% General tariff:30.0% |
Iron(VI) and iron(V) oxidation of copper(I) cyanide.
Environ. Sci. Technol. 39(10) , 3849-54, (2005) Copper(Il) cyanide (Cu(CN)4(3-)) in the gold mine industry presentsthe biggest concern in cyanide management because it is much more stable than free cyanide. Cu(CN)4(3-) is highlytoxic to aquatic lif... |
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The first precise molecular structure of a monomeric transition metal cyanide, copper(I) cyanide.
J. Am. Chem. Soc. 124(20) , 5895-901, (2002) Copper(I) cyanide is an important reagent in organic, organometallic, and supramolecular chemistry because of both the copper center and the versatile cyanide ligand. Solid-phase CuCN and many of its ... |
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Crystal Structures of a Series of Complexes Produced by Reaction of Copper(I) Cyanide with Diamines.
Inorg. Chem. 38 , 984, (1999) A new synthetic procedure developed recently in our laboratories has made possible the synthesis of variety of new complexes of CuCN with diamines. Synthesis was effected by adding the ligand to a sol... |
EINECS 208-883-6 |
MFCD00010975 |
copper(i) cyanide |