1-methyl-1h-benzimidazole-2-sulfonic acid

Modify Date: 2024-01-11 18:05:46

1-methyl-1h-benzimidazole-2-sulfonic acid Structure
1-methyl-1h-benzimidazole-2-sulfonic acid structure
Common Name 1-methyl-1h-benzimidazole-2-sulfonic acid
CAS Number 5533-38-0 Molecular Weight 212.22600
Density 1.55g/cm3 Boiling Point N/A
Molecular Formula C8H8N2O3S Melting Point 341ºC
MSDS N/A Flash Point N/A

 Names

Name 1-methyl-1h-benzimidazole-2-sulfonic acid
Synonym More Synonyms

 Chemical & Physical Properties

Density 1.55g/cm3
Melting Point 341ºC
Molecular Formula C8H8N2O3S
Molecular Weight 212.22600
Exact Mass 212.02600
PSA 80.57000
LogP 1.90080
Index of Refraction 1.682

 MSDS

Name: 1-Methylbenzimidazole-2-sulfonic acid 99% Material Safety Data Sheet
Synonym: None listed
CAS: 5533-38-0
Section 1 - Chemical Product MSDS Name:1-Methylbenzimidazole-2-sulfonic acid 99% Material Safety Data Sheet
Synonym:None listed

Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
CAS# Chemical Name content EINECS#
5533-38-0 1-Methylbenzimidazole-2-sulfonic acid 99 unlisted
Hazard Symbols: None Listed.
Risk Phrases: None Listed.

Section 3 - HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW
The toxicological properties of this material have not been fully investigated.
Potential Health Effects
Eye:
May cause eye irritation.
Skin:
May cause skin irritation.
Ingestion:
May cause irritation of the digestive tract. The toxicological properties of this substance have not been fully investigated.
Inhalation:
May cause respiratory tract irritation. The toxicological properties of this substance have not been fully investigated.
Chronic:
No information found.

Section 4 - FIRST AID MEASURES
Eyes: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid.
Skin:
Get medical aid. Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse.
Ingestion:
Never give anything by mouth to an unconscious person. Get medical aid. Do NOT induce vomiting. If conscious and alert, rinse mouth and drink 2-4 cupfuls of milk or water.
Inhalation:
Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid.
Notes to Physician:

Section 5 - FIRE FIGHTING MEASURES
General Information:
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion.
Extinguishing Media:
Use water spray, dry chemical, carbon dioxide, or appropriate foam.

Section 6 - ACCIDENTAL RELEASE MEASURES
General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks:
Sweep up or absorb material, then place into a suitable clean, dry, closed container for disposal. Avoid generating dusty conditions.
Provide ventilation.

Section 7 - HANDLING and STORAGE
Handling:
Wash thoroughly after handling. Remove contaminated clothing and wash before reuse. Use with adequate ventilation. Minimize dust generation and accumulation. Avoid contact with eyes, skin, and clothing. Avoid ingestion and inhalation.
Storage:
Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances.

Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION
Engineering Controls:
Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate ventilation to keep airborne concentrations low.
Exposure Limits CAS# 5533-38-0: Personal Protective Equipment Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin exposure.
Respirators:
A respiratory protection program that meets OSHA's 29 CFR 1910.134 and ANSI Z88.2 requirements or European Standard EN 149 must be followed whenever workplace conditions warrant respirator use.

Section 9 - PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Powder
Color: off-white
Odor: none reported
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point: 329 - 331 deg C
Autoignition Temperature: Not applicable.
Flash Point: Not applicable.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature: Not available.
Solubility in water: Not available.
Specific Gravity/Density: Not available.
Molecular Formula: C8H8N2O3S
Molecular Weight: 212.23

Section 10 - STABILITY AND REACTIVITY
Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Incompatible materials, dust generation.
Incompatibilities with Other Materials:
Oxidizing agents.
Hazardous Decomposition Products:
Carbon monoxide, oxides of nitrogen, oxides of sulfur, irritating and toxic fumes and gases, carbon dioxide.
Hazardous Polymerization: Has not been reported.

Section 11 - TOXICOLOGICAL INFORMATION
RTECS#:
CAS# 5533-38-0 unlisted.
LD50/LC50:
Not available.
Carcinogenicity:
1-Methylbenzimidazole-2-sulfonic acid - Not listed by ACGIH, IARC, or NTP.

Section 12 - ECOLOGICAL INFORMATION


Section 13 - DISPOSAL CONSIDERATIONS
Dispose of in a manner consistent with federal, state, and local regulations.

Section 14 - TRANSPORT INFORMATION

IATA
Not regulated as a hazardous material.
IMO
Not regulated as a hazardous material.
RID/ADR
Not regulated as a hazardous material.

Section 15 - REGULATORY INFORMATION

European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: Not available.
Risk Phrases:
Safety Phrases:
S 24/25 Avoid contact with skin and eyes.
WGK (Water Danger/Protection)
CAS# 5533-38-0: No information available.
Canada
None of the chemicals in this product are listed on the DSL/NDSL list.
CAS# 5533-38-0 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 5533-38-0 is not listed on the TSCA inventory.
It is for research and development use only.


SECTION 16 - ADDITIONAL INFORMATION
N/A

 Safety Information

Safety Phrases 24/25
HS Code 2933990090

 Synthetic Route

~99%

1-methyl-1h-benzimidazole-2-sulfonic acid Structure

1-methyl-1h-ben...

CAS#:5533-38-0

Literature: Divaeva; Kuzmenko; Morkovnik; Komissarov Chemistry of Heterocyclic Compounds, 2006 , vol. 42, # 4 p. 463 - 468

~%

1-methyl-1h-benzimidazole-2-sulfonic acid Structure

1-methyl-1h-ben...

CAS#:5533-38-0

Literature: Chemistry of Heterocyclic Compounds (New York, NY, United States), , vol. 23, # 12 p. 1348 - 1352 Khimiya Geterotsiklicheskikh Soedinenii, , # 12 p. 1673 - 1677

~%

1-methyl-1h-benzimidazole-2-sulfonic acid Structure

1-methyl-1h-ben...

CAS#:5533-38-0

Literature: Chemistry of Heterocyclic Compounds (New York, NY, United States), , vol. 23, # 12 p. 1348 - 1352 Khimiya Geterotsiklicheskikh Soedinenii, , # 12 p. 1673 - 1677

~%

1-methyl-1h-benzimidazole-2-sulfonic acid Structure

1-methyl-1h-ben...

CAS#:5533-38-0

Literature: Chemistry of Heterocyclic Compounds (New York, NY, United States), , vol. 23, # 12 p. 1348 - 1352 Khimiya Geterotsiklicheskikh Soedinenii, , # 12 p. 1673 - 1677

~%

1-methyl-1h-benzimidazole-2-sulfonic acid Structure

1-methyl-1h-ben...

CAS#:5533-38-0

Literature: Chemistry of Heterocyclic Compounds (New York, NY, United States), , vol. 23, # 12 p. 1348 - 1352 Khimiya Geterotsiklicheskikh Soedinenii, , # 12 p. 1673 - 1677

 Customs

HS Code 2933990090
Summary 2933990090. heterocyclic compounds with nitrogen hetero-atom(s) only. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:20.0%

 Synonyms

1-methylbenzimidazole-2-sulfonic acid
MFCD00142670