Malachite green

Modify Date: 2024-01-02 06:28:26

Malachite green Structure
Malachite green structure
Common Name Malachite green
CAS Number 569-64-2 Molecular Weight 364.911
Density 1.0448 (rough estimate) Boiling Point 520.91°C (rough estimate)
Molecular Formula C23H25ClN2 Melting Point 158-160ºC
MSDS Chinese USA Flash Point N/A
Symbol GHS05 GHS07 GHS08 GHS09
GHS05, GHS07, GHS08, GHS09
Signal Word Danger

 Use of Malachite green


Basic green 4 (Malachite green) is a cationic dye. Basic green 4 also is an N-methylated diaminotriphenylmethane dye to be used for coloring purpose[1].

 Names

Name malachite green
Synonym More Synonyms

 Malachite green Biological Activity

Description Basic green 4 (Malachite green) is a cationic dye. Basic green 4 also is an N-methylated diaminotriphenylmethane dye to be used for coloring purpose[1].
Related Catalog
References

[1]. Chowdhury. S, et al. Sea shell powder as a new adsorbent to remove Basic Green 4 (Malachite Green) from aqueous solutions: Equilibrium, kinetic and thermodynamic studies. Chemical Engineering Journal, 164(1), 168–177.

 Chemical & Physical Properties

Density 1.0448 (rough estimate)
Boiling Point 520.91°C (rough estimate)
Melting Point 158-160ºC
Molecular Formula C23H25ClN2
Molecular Weight 364.911
Exact Mass 364.170624
PSA 6.25000
LogP 1.39760
Index of Refraction 1.5940 (estimate)
Storage condition Refrigerator
Water Solubility Solubility Very soluble in water; soluble in ethanol, methanol, amyl alcohol

 Toxicological Information

CHEMICAL IDENTIFICATION

RTECS NUMBER :
BQ1180000
CHEMICAL NAME :
Ammonium, (4-(p-(dimethylamino)-alpha-phenylbenzylidene)-2,5-cy clohexadien-1-ylidene )- dimethyl-, chloride
CAS REGISTRY NUMBER :
569-64-2
LAST UPDATED :
199712
DATA ITEMS CITED :
10
MOLECULAR FORMULA :
C23-H25-N2.Cl
MOLECULAR WEIGHT :
364.95
WISWESSER LINE NOTATION :
L6Y DYJ AUYR&R DN1&1& DUK1&1 &Q &G

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
80 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Intraperitoneal
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
4200 ug/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value

MUTATION DATA

TYPE OF TEST :
DNA adduct
TEST SYSTEM :
Mammal - species unspecified Lymphocyte
DOSE/DURATION :
10 pph
REFERENCE :
BIPMAA Biopolymers. (John Wiley & Sons, Inc., 605 Third Ave., New York, NY 10158) V.1- 1963- Volume(issue)/page/year: 11,2537,1972 *** U.S. STANDARDS AND REGULATIONS *** EPA FIFRA 1988 PESTICIDE SUBJECT TO REGISTRATION OR RE-REGISTRATION FEREAC Federal Register. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) V.1- 1936- Volume(issue)/page/year: 54,7740,1989 *** NIOSH STANDARDS DEVELOPMENT AND SURVEILLANCE DATA *** NIOSH OCCUPATIONAL EXPOSURE SURVEY DATA : NOHS - National Occupational Hazard Survey (1974) NOHS Hazard Code - 84620 No. of Facilities: 2852 (estimated) No. of Industries: 25 No. of Occupations: 47 No. of Employees: 28485 (estimated) NOES - National Occupational Exposure Survey (1983) NOES Hazard Code - 84620 No. of Facilities: 5859 (estimated) No. of Industries: 84 No. of Occupations: 65 No. of Employees: 181763 (estimated) No. of Female Employees: 18135 (estimated)

 Safety Information

Symbol GHS05 GHS07 GHS08 GHS09
GHS05, GHS07, GHS08, GHS09
Signal Word Danger
Hazard Statements H302-H318-H361d-H410
Precautionary Statements P273-P280-P305 + P351 + P338-P501
Personal Protective Equipment dust mask type N95 (US);Eyeshields;Faceshields;Gloves
Hazard Codes Xn;N
Risk Phrases R22
Safety Phrases S24/25
RIDADR UN 2811 6.1/PG 3
WGK Germany 3
RTECS BQ1190000
Packaging Group III
HS Code 29215900

 Synthetic Route

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 Synonyms

N-(4-{[4-(Dimethylamino)phenyl](phenyl)methylene}cyclohexa-2,5-dien-1-ylidene)-N-methylmethanaminium chloride
China Green
N-(4-{[4-(Dimethylamino)phenyl](phenyl)methylene}-2,5-cyclohexadien-1-ylidene)-N-methylmethanaminium chloride
Benzal Green
N-{4-[[4-(dimethylamino)phenyl](phenyl)methylene]cyclohexa-2,5-dien-1-ylidene}-N-methylmethanaminium chloride
Malachite green chloride
Chlorure de N-(4-{[4-(diméthylamino)phényl](phényl)méthylène}-2,5-cyclohexadién-1-ylidène)-N-méthylméthanaminium
4-{[4-(Dimethylamino)phenyl](phenyl)methylene}-N,N-dimethyl-2,5-cyclohexadien-1-iminium chloride
Malachite Green ; Basic Green 4
Grenoble Green
Methanaminium, N-[4-[[4-(dimethylamino)phenyl]phenylmethylene]-2,5-cyclohexadien-1-ylidene]-N-methyl-, chloride (1:1)
Aniline Green
N-(4-{[4-(dimethylamino)phenyl](phenyl)methylidene}cyclohexa-2,5-dien-1-ylidene)-N-methylmethanaminium chloride
Victoria Green B
Basic Green 4
Victoria Green
methanaminium, N-[4-[[4-(dimethylamino)phenyl]phenylmethylene]-2,5-cyclohexadien-1-ylidene]-N-methyl-, chloride
[4-[[4-(dimethylamino)phenyl]-phenylmethylidene]cyclohexa-2,5-dien-1-ylidene]-dimethylazanium,chloride
Diamond Green B
n-(4-{[4-(dimethylamino)phenyl](phenyl)methylen}-2,5-cyclohexadien-1-yliden)-n-methylmethanaminiumchlorid
Malachite green
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