di-t-butylmethylphosphine

Modify Date: 2024-01-10 19:15:05

di-t-butylmethylphosphine Structure
di-t-butylmethylphosphine structure
Common Name di-t-butylmethylphosphine
CAS Number 6002-40-0 Molecular Weight 160.23700
Density 0.824 g/mL at 25ºC(lit.) Boiling Point 58ºC12 mm Hg(lit.)
Molecular Formula C9H21P Melting Point N/A
MSDS USA Flash Point 60ºC
Symbol GHS02 GHS05
GHS02, GHS05
Signal Word Danger

 Names

Name Di-tert-butylmethylphosphine
Synonym More Synonyms

 Chemical & Physical Properties

Density 0.824 g/mL at 25ºC(lit.)
Boiling Point 58ºC12 mm Hg(lit.)
Molecular Formula C9H21P
Molecular Weight 160.23700
Flash Point 60ºC
Exact Mass 160.13800
PSA 13.59000
LogP 3.69510
Appearance of Characters liquid | colorless
Storage condition Flammables area

 Safety Information

Symbol GHS02 GHS05
GHS02, GHS05
Signal Word Danger
Hazard Statements H250-H314
Precautionary Statements P222-P231-P280-P305 + P351 + P338-P310-P422
Personal Protective Equipment Faceshields;full-face respirator (US);Gloves;Goggles;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter
Hazard Codes F,C
Risk Phrases 17-34
Safety Phrases S16-S26-S45-S36-S37-S39
RIDADR UN 2845 4.2/PG 1
WGK Germany 3
HS Code 2901100000

 Synthetic Route

~93%

di-t-butylmethylphosphine Structure

di-t-butylmethy...

CAS#:6002-40-0

Literature: HOKKO CHEMICAL INDUSTRY CO. LTD. Patent: EP1473297 A1, 2004 ; Location in patent: Page 20-21 ;

~96%

di-t-butylmethylphosphine Structure

di-t-butylmethy...

CAS#:6002-40-0

Literature: Eisentraeger, Frank; Goethlich, Alexander; Gruber, Irene; Heiss, Helmut; Kiener, Christoph A.; Krueger, Carl; Notheis, J. Ulrich; Rominger, Frank; Scherhag, Gunter; Schultz, Madeleine; Straub, Bernd F.; Volland, Martin A. O.; Hofmann, Peter New Journal of Chemistry, 2003 , vol. 27, # 3 p. 540 - 550

~63%

di-t-butylmethylphosphine Structure

di-t-butylmethy...

CAS#:6002-40-0

Literature: Wang, Kun; Goldman, Martin E.; Emge, Thomas J.; Goldman, Alan S. Journal of Organometallic Chemistry, 1996 , vol. 518, # 1-2 p. 55 - 68

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di-t-butylmethylphosphine Structure

di-t-butylmethy...

CAS#:6002-40-0

Literature: Chemische Berichte, , vol. 99, p. 1134 - 1142

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di-t-butylmethylphosphine Structure

di-t-butylmethy...

CAS#:6002-40-0

Literature: Journal of the Chemical Society [Section] C: Organic, , p. 332 - 336

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di-t-butylmethylphosphine Structure

di-t-butylmethy...

CAS#:6002-40-0

Literature: Phosphorus and Sulfur and the Related Elements, , vol. 30, p. 433 - 436

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di-t-butylmethylphosphine Structure

di-t-butylmethy...

CAS#:6002-40-0

Literature: Phosphorus and Sulfur and the Related Elements, , vol. 30, p. 433 - 436

 Customs

HS Code 2901100000
Summary 2901100000 saturated acyclic hydrocarbons。Supervision conditions:None。VAT:17.0%。Tax rebate rate:9.0%。MFN tariff:2.0%。General tariff:30.0%

 Articles1

More Articles
Room-temperature Hiyama cross-couplings of arylsilanes with alkyl bromides and iodides.

J. Am. Chem. Soc. 125 , 5616, (2003)

The first method for achieving Hiyama couplings of unactivated alkyl bromides and iodides is reported. The desired carbon-carbon bond formation proceeds under mild conditions (room temperature) with g...

 Synonyms

ditert-butyl(methyl)phosphane
MFCD01634711
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