(5S)-5,6-DIHYDRO-5,6-DIHYDROXY-6-METHYLHEPTAN-2-ONE ACETONIDE

Modify Date: 2024-01-22 12:42:34

(5S)-5,6-DIHYDRO-5,6-DIHYDROXY-6-METHYLHEPTAN-2-ONE ACETONIDE Structure
(5S)-5,6-DIHYDRO-5,6-DIHYDROXY-6-METHYLHEPTAN-2-ONE ACETONIDE structure
Common Name (5S)-5,6-DIHYDRO-5,6-DIHYDROXY-6-METHYLHEPTAN-2-ONE ACETONIDE
CAS Number 61262-94-0 Molecular Weight 200.27500
Density 0.93g/cm3 Boiling Point 93ºC (0.1 mmHg)
Molecular Formula C11H20O3 Melting Point N/A
MSDS N/A Flash Point 92.8ºC

 Names

Name 4-[(4S)-2,2,5,5-tetramethyl-1,3-dioxolan-4-yl]butan-2-one
Synonym More Synonyms

 Chemical & Physical Properties

Density 0.93g/cm3
Boiling Point 93ºC (0.1 mmHg)
Molecular Formula C11H20O3
Molecular Weight 200.27500
Flash Point 92.8ºC
Exact Mass 200.14100
PSA 35.53000
LogP 2.28570
Index of Refraction 1.4325-1.4345

 MSDS

Name: (5S)-5 6-Isopropylidenedioxy-6-Methyl-Heptan-2-One 99% Material Safety Data Sheet
Synonym: (5S)-5,6-Dihydro-5,6-Dihydroxy-6-Methylheptan-2-One Acetonide
CAS: 61262-94-0
Section 1 - Chemical Product MSDS Name:(5S)-5 6-Isopropylidenedioxy-6-Methyl-Heptan-2-One 99% Material Safety Data Sheet
Synonym:(5S)-5,6-Dihydro-5,6-Dihydroxy-6-Methylheptan-2-One Acetonide

Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
CAS# Chemical Name content EINECS#
61262-94-0 (5S)-5,6-Isopropylidenedioxy-6-Methyl- 99% unlisted
Hazard Symbols: None Listed.
Risk Phrases: None Listed.

Section 3 - HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW
The toxicological properties of this material have not been fully investigated.
Potential Health Effects
Eye:
Non-irritating to the eyes. May cause eye irritation.
Skin:
Non-irritating to the skin. May cause skin irritation.
Ingestion:
May cause irritation of the digestive tract. No information found.
The toxicological properties of this substance have not been fully investigated.
Inhalation:
May cause respiratory tract irritation. No information available.
The toxicological properties of this substance have not been fully investigated.
Chronic:
No information found.

Section 4 - FIRST AID MEASURES
Eyes: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid.
Skin:
Get medical aid. Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse.
Ingestion:
Never give anything by mouth to an unconscious person. Get medical aid. Do NOT induce vomiting. If conscious and alert, rinse mouth and drink 2-4 cupfuls of milk or water.
Inhalation:
Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid.
Notes to Physician:

Section 5 - FIRE FIGHTING MEASURES
General Information:
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. Vapors may be heavier than air. They can spread along the ground and collect in low or confined areas. Runoff from fire control or dilution water may cause pollution.
Extinguishing Media:
Use agent most appropriate to extinguish fire. Use water spray, dry chemical, carbon dioxide, or appropriate foam.

Section 6 - ACCIDENTAL RELEASE MEASURES
General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth), then place in suitable container. Avoid runoff into storm sewers and ditches which lead to waterways. Clean up spills immediately, observing precautions in the Protective Equipment section. Provide ventilation.

Section 7 - HANDLING and STORAGE
Handling:
Wash thoroughly after handling. Use with adequate ventilation. Avoid breathing dust, vapor, mist, or gas. Avoid contact with eyes, skin, and clothing. Avoid contact with skin and eyes. Keep container tightly closed. Avoid ingestion and inhalation.
Storage:
Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances.

Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION
Engineering Controls:
Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate ventilation to keep airborne concentrations low.
Exposure Limits CAS# 61262-94-0: Personal Protective Equipment Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin exposure.
Clothing:
Wear a chemical apron. Wear appropriate protective clothing to prevent skin exposure.
Respirators:
Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced.

Section 9 - PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Clear liquid
Color: colorless
Odor: Not available.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: 93 deg C @10 mmHg
Freezing/Melting Point: Not available.
Autoignition Temperature: Not applicable.
Flash Point: Not applicable.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water:
Specific Gravity/Density:
Molecular Formula: C11H20O3
Molecular Weight: 200.27

Section 10 - STABILITY AND REACTIVITY
Chemical Stability:
Stable at room temperature in closed containers under normal storage and handling conditions.
Conditions to Avoid:
Incompatible materials, excess heat, strong oxidants.
Incompatibilities with Other Materials:
Oxidizing agents.
Hazardous Decomposition Products:
Carbon monoxide, irritating and toxic fumes and gases, carbon dioxide.
Hazardous Polymerization: Has not been reported

Section 11 - TOXICOLOGICAL INFORMATION
RTECS#:
CAS# 61262-94-0 unlisted.
LD50/LC50:
Not available.
Carcinogenicity:
(5S)-5,6-Isopropylidenedioxy-6-Methyl-Heptan-2-One - Not listed by ACGIH, IARC, or NTP.

Section 12 - ECOLOGICAL INFORMATION


Section 13 - DISPOSAL CONSIDERATIONS
Dispose of in a manner consistent with federal, state, and local regulations.

Section 14 - TRANSPORT INFORMATION

IATA
Not regulated as a hazardous material.
IMO
Not regulated as a hazardous material.
RID/ADR
Not regulated as a hazardous material.

Section 15 - REGULATORY INFORMATION

European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: Not available.
Risk Phrases:
Safety Phrases:
S 24/25 Avoid contact with skin and eyes.
WGK (Water Danger/Protection)
CAS# 61262-94-0: No information available.
Canada
None of the chemicals in this product are listed on the DSL/NDSL list.
CAS# 61262-94-0 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 61262-94-0 is not listed on the TSCA inventory.
It is for research and development use only.


SECTION 16 - ADDITIONAL INFORMATION
N/A

 Safety Information

Safety Phrases S24/25
HS Code 2932999099

 Synthetic Route

~78%

(5S)-5,6-DIHYDRO-5,6-DIHYDROXY-6-METHYLHEPTAN-2-ONE ACETONIDE Structure

(5S)-5,6-DIHYDR...

CAS#:61262-94-0

Literature: Fourneron, J. D.; Archelas, A.; Furstoss, R. Journal of Organic Chemistry, 1989 , vol. 54, # 19 p. 4686 - 4689

~40%

(5S)-5,6-DIHYDRO-5,6-DIHYDROXY-6-METHYLHEPTAN-2-ONE ACETONIDE Structure

(5S)-5,6-DIHYDR...

CAS#:61262-94-0

Literature: Archelas; Delbecque; Furstoss Tetrahedron Asymmetry, 1993 , vol. 4, # 12 p. 2445 - 2446

~%

(5S)-5,6-DIHYDRO-5,6-DIHYDROXY-6-METHYLHEPTAN-2-ONE ACETONIDE Structure

(5S)-5,6-DIHYDR...

CAS#:61262-94-0

Literature: Fourneron, J. D.; Archelas, A.; Furstoss, R. Journal of Organic Chemistry, 1989 , vol. 54, # 19 p. 4686 - 4689

~%

(5S)-5,6-DIHYDRO-5,6-DIHYDROXY-6-METHYLHEPTAN-2-ONE ACETONIDE Structure

(5S)-5,6-DIHYDR...

CAS#:61262-94-0

Literature: Fourneron, J. D.; Archelas, A.; Furstoss, R. Journal of Organic Chemistry, 1989 , vol. 54, # 19 p. 4686 - 4689

~%

(5S)-5,6-DIHYDRO-5,6-DIHYDROXY-6-METHYLHEPTAN-2-ONE ACETONIDE Structure

(5S)-5,6-DIHYDR...

CAS#:61262-94-0

Literature: Archelas; Delbecque; Furstoss Tetrahedron Asymmetry, 1993 , vol. 4, # 12 p. 2445 - 2446

~%

(5S)-5,6-DIHYDRO-5,6-DIHYDROXY-6-METHYLHEPTAN-2-ONE ACETONIDE Structure

(5S)-5,6-DIHYDR...

CAS#:61262-94-0

Literature: Archelas; Delbecque; Furstoss Tetrahedron Asymmetry, 1993 , vol. 4, # 12 p. 2445 - 2446

~%

(5S)-5,6-DIHYDRO-5,6-DIHYDROXY-6-METHYLHEPTAN-2-ONE ACETONIDE Structure

(5S)-5,6-DIHYDR...

CAS#:61262-94-0

Literature: Archelas; Delbecque; Furstoss Tetrahedron Asymmetry, 1993 , vol. 4, # 12 p. 2445 - 2446

~%

(5S)-5,6-DIHYDRO-5,6-DIHYDROXY-6-METHYLHEPTAN-2-ONE ACETONIDE Structure

(5S)-5,6-DIHYDR...

CAS#:61262-94-0

Literature: Archelas; Delbecque; Furstoss Tetrahedron Asymmetry, 1993 , vol. 4, # 12 p. 2445 - 2446

~%

(5S)-5,6-DIHYDRO-5,6-DIHYDROXY-6-METHYLHEPTAN-2-ONE ACETONIDE Structure

(5S)-5,6-DIHYDR...

CAS#:61262-94-0

Literature: Archelas; Delbecque; Furstoss Tetrahedron Asymmetry, 1993 , vol. 4, # 12 p. 2445 - 2446

 Customs

HS Code 2932999099
Summary 2932999099. other heterocyclic compounds with oxygen hetero-atom(s) only. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:20.0%

 Synonyms

MFCD00067072