2-Crotonoyl chloride

Modify Date: 2024-01-02 19:38:28

2-Crotonoyl chloride Structure
2-Crotonoyl chloride structure
Common Name 2-Crotonoyl chloride
CAS Number 625-35-4 Molecular Weight 104.535
Density 1.1±0.1 g/cm3 Boiling Point 124.5±0.0 °C at 760 mmHg
Molecular Formula C4H5ClO Melting Point N/A
MSDS Chinese USA Flash Point 35.0±0.0 °C
Symbol GHS02 GHS05 GHS07
GHS02, GHS05, GHS07
Signal Word Danger

 Names

Name trans-Crotonyl chloride
Synonym More Synonyms

 Chemical & Physical Properties

Density 1.1±0.1 g/cm3
Boiling Point 124.5±0.0 °C at 760 mmHg
Molecular Formula C4H5ClO
Molecular Weight 104.535
Flash Point 35.0±0.0 °C
Exact Mass 104.002892
PSA 17.07000
LogP 1.58
Vapour Pressure 12.7±0.2 mmHg at 25°C
Index of Refraction 1.441
Storage condition 2-8°C

 Safety Information

Symbol GHS02 GHS05 GHS07
GHS02, GHS05, GHS07
Signal Word Danger
Hazard Statements H226-H314-H335
Precautionary Statements P261-P280-P305 + P351 + P338-P310
Personal Protective Equipment Faceshields;full-face respirator (US);Gloves;Goggles;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter
Hazard Codes C:Corrosive
Risk Phrases R10;R34
Safety Phrases S16-S24/25-S28
RIDADR UN 2920
WGK Germany 3
Packaging Group II

 Synthetic Route

~82%

2-Crotonoyl chloride Structure

2-Crotonoyl chloride

CAS#:625-35-4

Literature: Ongoka, Pascal; Mauze, Bernard; Miginiac, Leone Journal of Organometallic Chemistry, 1987 , vol. 322, p. 131 - 140

~91%

2-Crotonoyl chloride Structure

2-Crotonoyl chloride

CAS#:625-35-4

Literature: Ramachandran, P. Veeraraghavan; Nicponski, Daniel; Kim, Bomi Organic Letters, 2013 , vol. 15, # 6 p. 1398 - 1401

~0%

2-Crotonoyl chloride Structure

2-Crotonoyl chloride

CAS#:625-35-4

Literature: Boudjouk, Philip; Ohrbom, Walter H.; Woell, James B. Synthetic Communications, 1986 , vol. 16, # 4 p. 401 - 410

~%

2-Crotonoyl chloride Structure

2-Crotonoyl chloride

CAS#:625-35-4

Literature: Journal of Organic Chemistry, , vol. 65, # 20 p. 6688 - 6696

~%

2-Crotonoyl chloride Structure

2-Crotonoyl chloride

CAS#:625-35-4

Literature: Journal of the American Chemical Society, , vol. 70, p. 500 Journal of the American Chemical Society, , vol. 60, p. 1326

~%

2-Crotonoyl chloride Structure

2-Crotonoyl chloride

CAS#:625-35-4

Literature: Recueil des Travaux Chimiques des Pays-Bas, , vol. 76, p. 969,972

 Articles1

More Articles
Double asymmetric induction as a mechanistic probe: the doubly diastereoselective conjugate addition of enantiopure lithium amides to enantiopure α,β-unsaturated esters and enantiopure α,β-unsaturated hydroxamates. Davies SG, et al.

Tetrahedron 67(34) , 6382-6403, (2011)

 Synonyms

2-Butenoyl chloride, (2E)-
(2E)-2-Butenoyl chloride
(E)-2-Butenoyl chloride
MFCD00000734
(2E)-But-2-enoylchlorid
2-Crotonoyl chloride
EINECS 234-010-3
(2E)-But-2-enoyl chloride