3-Butenoic acid

Modify Date: 2024-01-05 16:15:02

3-Butenoic acid Structure
3-Butenoic acid structure
 Common Name 3-Butenoic acid
CAS Number 625-38-7 Molecular Weight 86.089
Density 1.0±0.1 g/cm3 Boiling Point 170.6±9.0 °C at 760 mmHg
Molecular Formula C4H6O2 Melting Point −39 °C(lit.)
MSDS Chinese USA Flash Point 65.6±0.0 °C
Symbol GHS05 GHS07
GHS05, GHS07		 Signal Word Danger

 Use of 3-Butenoic acid


3-Butenoic acid (Vinylacetic acid) can be used to synthesize bicyclic 3,6-dihydro-1,2-oxazine. Strained bicyclic 3,6-dihydro-1,2-oxazine is a reactive substrate in domino metathesis with an external alkene[1][2].

 Names

Name Vinylacetic Acid
Synonym More Synonyms

 3-Butenoic acid Biological Activity

Description 3-Butenoic acid (Vinylacetic acid) can be used to synthesize bicyclic 3,6-dihydro-1,2-oxazine. Strained bicyclic 3,6-dihydro-1,2-oxazine is a reactive substrate in domino metathesis with an external alkene[1][2].
Related Catalog
References

[1]. Géraldine Calvet, et al. Domino metathesis of 3,6-dihydro-1,2-oxazine: access to isoxazolo[2,3-a]pyridin-7-ones. Org Lett. 2007 Apr 12;9(8):1485-8.

[2]. M A Casado-Rodriguez, et al. Synthesis of vinyl-terminated Au nanoprisms and nanooctahedra mediated by 3-butenoic acid: direct Au@pNIPAM fabrication with improved SERS capabilities. Nanoscale. 2016 Feb 28;8(8):4557-64.

 Chemical & Physical Properties

Density 1.0±0.1 g/cm3
Boiling Point 170.6±9.0 °C at 760 mmHg
Melting Point −39 °C(lit.)
Molecular Formula C4H6O2
Molecular Weight 86.089
Flash Point 65.6±0.0 °C
Exact Mass 86.036781
PSA 37.30000
LogP 0.54
Vapour Pressure 0.7±0.7 mmHg at 25°C
Index of Refraction 1.432
Storage condition 2-8°C

 Safety Information

Symbol GHS05 GHS07
GHS05, GHS07
Signal Word Danger
Hazard Statements H302-H314
Precautionary Statements P280-P305 + P351 + P338-P310
Personal Protective Equipment Faceshields;full-face respirator (US);Gloves;Goggles;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter
Hazard Codes C:Corrosive;
Risk Phrases R34
Safety Phrases S26-S36/37/39-S45
RIDADR UN 2922 8/PG 2
WGK Germany 2
Packaging Group II
Hazard Class 8
HS Code 2916190090

 Customs

HS Code 2916190090
Summary 2916190090 unsaturated acyclic monocarboxylic acids, their anhydrides, halides, peroxides, peroxyacids and their derivatives。supervision conditions:AB(certificate of inspection for goods inward,certificate of inspection for goods outward)。VAT:17.0%。tax rebate rate:9.0%。MFN tariff:6.5%。general tariff:30.0%

 Articles12

More Articles
On the Question of Site-Selective Ligand Exchange in Carboxylate-Substituted Metal Oxo Clusters.

Eur. J. Inorg. Chem. 2015 , 2889-2894, (2015)

Reaction of [Ti4Zr4O6(OBu)4(OMc)16] (OMc = methacrylate) with acetylacetone (acacH) resulted in dissection of the cluster and formation of [Ti(OBu)2(acac)2] and the smaller cluster [Ti2Zr4O4(OMc)16]. ...

Synthesis of base substituted 2-hydroxy-3-(purin-9-yl)-propanoic acids and 4-(purin-9-yl)-3-butenoic acids.

Nucleosides Nucleotides Nucleic Acids 22(12) , 2145-60, (2003)

Alkylation of 6-chloropurine and 2-amino-6-chloropurine with bromoacetaldehyde diethyl acetal afforded 6-chloro-9-(2,2-diethoxyethyl)purine (3a) and its 2-amino congener (3b). Treatment of compounds 3...

Increases in microbial nitrogen production and efficiency in vitro with three inhibitors of ruminal methanogenesis.

Can. J. Microbiol. 53(4) , 496-503, (2007)

It was hypothesized that the addition of crotonic acid or 3-butenoic acid would relieve constraints in digestibility observed when methane formation is inhibited by lumazine, propynoic acid, or ethyl ...

 Synonyms

Vinyl acetic acid
But-3-enoic acid
vinylacetic acid
3-Butenoic acid
EINECS 210-892-5
MFCD00002782
Iodoquinol Impurity 4
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Chemsrc provides 3-Butenoic acid(CAS#:625-38-7) MSDS, density, melting point, boiling point, structure, formula, molecular weight etc. Articles of 3-Butenoic acid are included as well.>> amp version: 3-Butenoic acid

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