4-(difluoromethoxy)benzyl alcohol

Modify Date: 2024-01-02 19:48:00

4-(difluoromethoxy)benzyl alcohol Structure
4-(difluoromethoxy)benzyl alcohol structure
Common Name 4-(difluoromethoxy)benzyl alcohol
CAS Number 659-33-6 Molecular Weight 174.14500
Density 1.259 g/mL at 25 °C(lit.) Boiling Point 129-130 °C(lit.)
Molecular Formula C8H8F2O2 Melting Point -39 °C
MSDS N/A Flash Point 84 °F

 Names

Name 4-(difluoromethoxy)benzyl alcohol
Synonym More Synonyms

 Chemical & Physical Properties

Density 1.259 g/mL at 25 °C(lit.)
Boiling Point 129-130 °C(lit.)
Melting Point -39 °C
Molecular Formula C8H8F2O2
Molecular Weight 174.14500
Flash Point 84 °F
Exact Mass 174.04900
PSA 29.46000
LogP 1.78030
Index of Refraction n20/D 1.375(lit.)
Water Solubility 10 g/L (20 ºC)

 Safety Information

Risk Phrases R36/37/38
Safety Phrases S26-S36
HS Code 2909309090

 Synthetic Route

~77%

4-(difluoromethoxy)benzyl alcohol Structure

4-(difluorometh...

CAS#:659-33-6

Literature: Journal of Fluorine Chemistry, , vol. 132, # 8 p. 521 - 528

~%

4-(difluoromethoxy)benzyl alcohol Structure

4-(difluorometh...

CAS#:659-33-6

Literature: Journal of Fluorine Chemistry, , vol. 160, p. 72 - 76

~83%

4-(difluoromethoxy)benzyl alcohol Structure

4-(difluorometh...

CAS#:659-33-6

Literature: Angewandte Chemie - International Edition, , vol. 52, # 47 p. 12390 - 12394 Angew. Chem., , vol. 125, # 47 p. 12616 - 12620,5

~64%

4-(difluoromethoxy)benzyl alcohol Structure

4-(difluorometh...

CAS#:659-33-6

Literature: Tetrahedron, , vol. 65, # 27 p. 5278 - 5283

~66%

4-(difluoromethoxy)benzyl alcohol Structure

4-(difluorometh...

CAS#:659-33-6

Literature: Organic Letters, , vol. 13, # 20 p. 5568 - 5571

~%

4-(difluoromethoxy)benzyl alcohol Structure

4-(difluorometh...

CAS#:659-33-6

Literature: Journal of Fluorine Chemistry, , vol. 41, p. 247 - 262

~%

4-(difluoromethoxy)benzyl alcohol Structure

4-(difluorometh...

CAS#:659-33-6

Literature: Journal of Fluorine Chemistry, , vol. 160, p. 72 - 76

~81%

4-(difluoromethoxy)benzyl alcohol Structure

4-(difluorometh...

CAS#:659-33-6

Literature: Beilstein Journal of Organic Chemistry, , vol. 10, p. 344 - 351

~83%

4-(difluoromethoxy)benzyl alcohol Structure

4-(difluorometh...

CAS#:659-33-6

Literature: Journal of Organic Chemistry, , vol. 78, # 17 p. 8904 - 8908

 Customs

HS Code 2909309090
Summary 2909309090 other aromatic ethers and their halogenated, sulphonated, nitrated or nitrosated derivatives VAT:17.0% Tax rebate rate:9.0% Supervision conditions:none MFN tariff:5.5% General tariff:30.0%

 Synonyms

1-Difluormethoxy-4-methoxy-benzol
4-Methoxy-phenyl-difluormethyl-aether
difluoromethyl 4-methoxyphenyl ether
MFCD00236228
RARECHEM AL BD 0279