tebbe reagent
Modify Date: 2024-01-08 17:41:25
tebbe reagent structure
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Common Name | tebbe reagent | ||
|---|---|---|---|---|
| CAS Number | 67719-69-1 | Molecular Weight | 284.58400 | |
| Density | 0.927 | Boiling Point | N/A | |
| Molecular Formula | C13H18AlClTi | Melting Point | N/A | |
| MSDS | N/A | Flash Point | 4ºC | |
| Symbol |
GHS02, GHS05, GHS07, GHS08 |
Signal Word | Danger | |
| Name | mu-Chloro-mu-Methylene[Bis(Cyclopentadienyl)Titanium]Dimethylaluminum |
|---|---|
| Synonym | More Synonyms |
| Density | 0.927 |
|---|---|
| Molecular Formula | C13H18AlClTi |
| Molecular Weight | 284.58400 |
| Flash Point | 4ºC |
| Exact Mass | 284.03900 |
| LogP | 4.36090 |
| Appearance of Characters | Solution | Dark red to purple |
| Storage condition | Refrigerator |
| Water Solubility | Soluble in toluene, benzene, dichloromethane. Insoluble in water. |
| Symbol |
GHS02, GHS05, GHS07, GHS08 |
|---|---|
| Signal Word | Danger |
| Hazard Statements | H225-H304-H314-H336-H361d-H373 |
| Precautionary Statements | P210-P261-P280-P301 + P310-P305 + P351 + P338-P310 |
| Personal Protective Equipment | Faceshields;full-face respirator (US);Gloves;Goggles;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter |
| Hazard Codes | F:Highlyflammable;T:Toxic; |
| Risk Phrases | R11;R23/24/25;R34 |
| Safety Phrases | S16-S25-S29-S33-S36/37/39 |
| RIDADR | UN 2924 3/PG 2 |
| WGK Germany | 2 |
| Packaging Group | II |
| Hazard Class | 4.3 |
| HS Code | 29310099 |
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Synthesis and in vitro trypanocide activity of several polycyclic drimane-quinone derivatives.
Bioorg. Med. Chem. 11 , 2489-2497, (2003) The Diels-Alder reaction between two polygodial-derived dienes and simple quinones to yield substituted naphtho- and anthraquinones, is described. The in vitro trypanocide activity for the series was ... |
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Synthesis of a novel ceramide analogue via Tebbe methylenation and evaluation of its antiproliferative activity.
Org. Lett. 7 , 1645, (2005) [reaction: see text] A new analogue of (2S,3R)-ceramide (2) with a methylene group at C4 has been synthesized from d-tartaric acid (3) by using Tebbe methylenation as the key step. Compound 2 exhibite... |
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Synthesis , 165, (1991)
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| MFCD00151575 |
| tebbe reagent |