Tributyltin hydride

Modify Date: 2024-01-02 10:41:33

Tributyltin hydride Structure
Tributyltin hydride structure
Common Name Tributyltin hydride
CAS Number 688-73-3 Molecular Weight 291.061
Density 1.082 g/mL at 25 °C(lit.) Boiling Point 281.5±9.0 °C at 760 mmHg
Molecular Formula C12H27Sn Melting Point <0ºC
MSDS Chinese USA Flash Point 124.0±18.7 °C

 Names

Name tributylstannane
Synonym More Synonyms

 Chemical & Physical Properties

Density 1.082 g/mL at 25 °C(lit.)
Boiling Point 281.5±9.0 °C at 760 mmHg
Melting Point <0ºC
Molecular Formula C12H27Sn
Molecular Weight 291.061
Flash Point 124.0±18.7 °C
Exact Mass 292.121307
LogP 4.88150
Vapour Pressure 0.0±0.6 mmHg at 25°C
Index of Refraction n20/D 1.473(lit.)
Storage condition 2-8°C
Water Solubility REACTS

 Toxicological Information

CHEMICAL IDENTIFICATION

RTECS NUMBER :
WH8675000
CHEMICAL NAME :
Stannane, tri-n-butyl-, hydride
CAS REGISTRY NUMBER :
688-73-3
BEILSTEIN REFERENCE NO. :
3587329
LAST UPDATED :
199712
DATA ITEMS CITED :
25
MOLECULAR FORMULA :
C12-H28-Sn
MOLECULAR WEIGHT :
291.09
WISWESSER LINE NOTATION :
4-SN-H4&4

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :
LCLo - Lowest published lethal concentration
ROUTE OF EXPOSURE :
Inhalation
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
1460 mg/m3/10M
REFERENCE :
NDRC** National Defense Research Committee, Office of Scientific Research and Development, Progress Report. Volume(issue)/page/year: NDCrc-132,FEB1942 *** REVIEWS *** ACGIH TLV-TWA 0.1 mg(Sn)/m3;STEL 0.2 mg/m3 (skin) DTLVS* The Threshold Limit Values (TLVs) and Biological Exposure Indices (BEIs) booklet issues by American Conference of Governmental Industrial Hygienists (ACGIH), Cincinnati, OH, 1996 Volume(issue)/page/year: TLV/BEI,1997 ACGIH TLV-Not classifiable as a human carcinogen DTLVS* The Threshold Limit Values (TLVs) and Biological Exposure Indices (BEIs) booklet issues by American Conference of Governmental Industrial Hygienists (ACGIH), Cincinnati, OH, 1996 Volume(issue)/page/year: TLV/BEI,1997 *** U.S. STANDARDS AND REGULATIONS *** MSHA STANDARD-air:TWA 0.1 mg(Sn)/m3 DTLVS* The Threshold Limit Values (TLVs) and Biological Exposure Indices (BEIs) booklet issues by American Conference of Governmental Industrial Hygienists (ACGIH), Cincinnati, OH, 1996 Volume(issue)/page/year: 3,258,1971 OSHA PEL (Gen Indu):8H TWA 0.1 mg(Sn)/m3 CFRGBR Code of Federal Regulations. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) Volume(issue)/page/year: 29,1910.1000,1994 OSHA PEL (Construc):8H TWA 0.1 mg(Sn)/m3 CFRGBR Code of Federal Regulations. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) Volume(issue)/page/year: 29,1926.55,1994 OSHA PEL (Shipyard):8H TWA 0.1 mg(Sn)/m3 CFRGBR Code of Federal Regulations. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) Volume(issue)/page/year: 29,1915.1000,1993 OSHA PEL (Fed Cont):8H TWA 0.1 mg(Sn)/m3 CFRGBR Code of Federal Regulations. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) Volume(issue)/page/year: 41,50-204.50,1994 *** OCCUPATIONAL EXPOSURE LIMITS *** OEL-AUSTRALIA:TWA 0.1 mg(Sn)/m3;Skin JAN 1993 OEL-BELGIUM:TWA 0.1 mg(Sn)/m3;Skin JAN 1993 OEL-DENMARK:TWA 0.1 mg(Sn)/m3;Skin JAN 1993 OEL-FINLAND:TWA 0.1 mg(Sn)/m3;STEL 0.3 mg(Sn)/m3;Skin JAN 1993 OEL-FRANCE:TWA 0.1 mg(Sn)/m3;STEL 0.2 mg(Sn)/m3 JAN 1993 OEL-GERMANY:TWA 0.1 mg(Sn)/m3;Skin JAN 1993 OEL-HUNGARY:STEL 0.1 mg(Sn)/m3;Skin JAN 1993 OEL-THE NETHERLANDS:TWA 0.1 mg(Sn)/m3;Skin JAN 1993 OEL-THE PHILIPPINES:TWA 0.1 mg(Sn)/m3 JAN 1993 OEL-SWEDEN:TWA 0.1 mg(Sn)/m3;STEL 0.2 mg(Sn)/m3;Skin JAN 1993 OEL-SWITZERLAND:TWA 0.1 mg(Sn)/m3;STEL 0.2 mg(Sn)/m3;Skin JAN 1993 OEL-THAILAND:TWA 0.1 mg(Sn)/m3 JAN 1993 OEL-UNITED KINGDOM:TWA 0.1 mg(Sn)/m3;STEL 0.2 mg(Sn)/m3;Skin JAN 1993 OEL IN BULGARIA, COLOMBIA, JORDAN, KOREA check ACGIH TLV OEL IN NEW ZEALAND, SINGAPORE, VIETNAM check ACGIH TLV *** NIOSH STANDARDS DEVELOPMENT AND SURVEILLANCE DATA *** NIOSH RECOMMENDED EXPOSURE LEVEL (REL) : NIOSH REL TO ORGANOTIN COMPOUND-air:10H TWA 0.1 mg(Sn)/m3 REFERENCE : NIOSH* National Institute for Occupational Safety and Health, U.S. Dept. of Health, Education, and Welfare, Reports and Memoranda. Volume(issue)/page/year: DHHS #92-100,1992

 Safety Information

Hazard Codes T:Toxic;N:Dangerousfortheenvironment;
Risk Phrases R10;R15;R21;R25;R36/38;R48/23/25;R50/53
Safety Phrases S35-S36/37/39-S45-S60-S61-S62-S36/37-S33-S26-S16
RIDADR UN 1993 3/PG 3
WGK Germany 3
RTECS WH8675000
Packaging Group II
Hazard Class 6.1
HS Code 29310095

 Synthetic Route

 Customs

HS Code 2931900090
Summary 2931900090. other organo-inorganic compounds. VAT:17.0%. Tax rebate rate:13.0%. Supervision conditions:AB(certificate of inspection for goods inward,certificate of inspection for goods outward). MFN tariff:6.5%. General tariff:30.0%

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 Synonyms

MFCD00009416
SnBu3H
Tri-n-butyltin hydride
Stannane, tributyl-
Tributyltin hydride
TBTH
Tin, tri-n-butyl-, hydride
Tri-n-butylstannane
Tributylstannic hydride
Tributyltin
Tributylstannane
EINECS 211-704-4
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