(3AR,6R,6aR)-6-(((tert-butyldimethylsilyl)oxy)methyl)-2,2-dimethyldihydrofuro[3,4-d][1,3]dioxol-4(3aH)-one

Modify Date: 2024-02-01 15:09:42

(3AR,6R,6aR)-6-(((tert-butyldimethylsilyl)oxy)methyl)-2,2-dimethyldihydrofuro[3,4-d][1,3]dioxol-4(3aH)-one Structure
(3AR,6R,6aR)-6-(((tert-butyldimethylsilyl)oxy)methyl)-2,2-dimethyldihydrofuro[3,4-d][1,3]dioxol-4(3aH)-one structure
 Common Name (3AR,6R,6aR)-6-(((tert-butyldimethylsilyl)oxy)methyl)-2,2-dimethyldihydrofuro[3,4-d][1,3]dioxol-4(3aH)-one
CAS Number 75467-36-6 Molecular Weight 302.43900
Density 1.031 g/cm3 Boiling Point 371.046ºC at 760 mmHg
Molecular Formula C14H26O5Si Melting Point 72-74ºC(lit.)
MSDS N/A Flash Point 148.088ºC

 Names

Name (3aR,6R,6aR)-6-[[tert-butyl(dimethyl)silyl]oxymethyl]-2,2-dimethyl-6,6a-dihydro-3aH-furo[3,4-d][1,3]dioxol-4-one
Synonym More Synonyms

 Chemical & Physical Properties

Density 1.031 g/cm3
Boiling Point 371.046ºC at 760 mmHg
Melting Point 72-74ºC(lit.)
Molecular Formula C14H26O5Si
Molecular Weight 302.43900
Flash Point 148.088ºC
Exact Mass 302.15500
PSA 53.99000
LogP 2.45370
Index of Refraction 1.447

 Safety Information

Hazard Codes Xi: Irritant;
Risk Phrases R36/37/38
Safety Phrases 26-36

 Synthetic Route

2,3-O-Isopropylidene-D-ribonic g-lactone structure

2,3-O-Isopropyl...

CAS#:30725-00-9

tert-Butyldimethylsilyl chloride structure

tert-Butyldimet...

CAS#:18162-48-6

~97%

(3AR,6R,6aR)-6-(((tert-butyldimethylsilyl)oxy)methyl)-2,2-dimethyldihydrofuro[3,4-d][1,3]dioxol-4(3aH)-one Structure

(3AR,6R,6aR)-6-...

CAS#:75467-36-6

Literature: Jones, Nigel A.; Jenkinson, Sarah F.; Soengas, Raquel; Fanefjord, Mette; Wormald, Mark R.; Dwek, Raymond A.; Kiran, Gullapalli P.; Devendar, Rao; Takata, Goro; Morimoto, Kenji; Izumori, Ken; Fleet, George W.J. Tetrahedron Asymmetry, 2007 , vol. 18, # 6 p. 774 - 786
(3aR,6R,6aR)-6-(((tert-Butyldimethylsilyl)oxy)methyl)-2,2-dimethyltetrahydrofuro[3,4-d][1,3]dioxol-4-ol structure

(3aR,6R,6aR)-6-...

CAS#:217309-46-1

~95%

(3AR,6R,6aR)-6-(((tert-butyldimethylsilyl)oxy)methyl)-2,2-dimethyldihydrofuro[3,4-d][1,3]dioxol-4(3aH)-one Structure

(3AR,6R,6aR)-6-...

CAS#:75467-36-6

Literature: Alessandrini, Laura; Casati, Silvana; Ciuffreda, Pierangela; Ottria, Roberta; Santaniello, Enzo Journal of Carbohydrate Chemistry, 2008 , vol. 27, # 5 p. 332 - 344
2,3-O-isopropylidine-D-ribose structure

2,3-O-isopropyl...

CAS#:67814-68-0

~%

(3AR,6R,6aR)-6-(((tert-butyldimethylsilyl)oxy)methyl)-2,2-dimethyldihydrofuro[3,4-d][1,3]dioxol-4(3aH)-one Structure

(3AR,6R,6aR)-6-...

CAS#:75467-36-6

Literature: Tetrahedron, , vol. 60, # 31 p. 6609 - 6617
tert-Butyldimethylsilyl chloride structure

tert-Butyldimet...

CAS#:18162-48-6

~%

(3AR,6R,6aR)-6-(((tert-butyldimethylsilyl)oxy)methyl)-2,2-dimethyldihydrofuro[3,4-d][1,3]dioxol-4(3aH)-one Structure

(3AR,6R,6aR)-6-...

CAS#:75467-36-6

Literature: Journal of Organic Chemistry, , vol. 59, # 10 p. 2715 - 2723
(2R,3S,4S)-1-O-((1,1-Dimethylethyl)dimethylsilyl)-2-hydroxy-6-methyl-3,4-O-(1-methylethylidene)hept-5-ene structure

(2R,3S,4S)-1-O-...

CAS#:154976-38-2

~%

(3AR,6R,6aR)-6-(((tert-butyldimethylsilyl)oxy)methyl)-2,2-dimethyldihydrofuro[3,4-d][1,3]dioxol-4(3aH)-one Structure

(3AR,6R,6aR)-6-...

CAS#:75467-36-6

Literature: Journal of Organic Chemistry, , vol. 59, # 10 p. 2715 - 2723
D-Lyxofuranose (9CI) structure

D-Lyxofuranose (9CI)

CAS#:532-20-7

~%

(3AR,6R,6aR)-6-(((tert-butyldimethylsilyl)oxy)methyl)-2,2-dimethyldihydrofuro[3,4-d][1,3]dioxol-4(3aH)-one Structure

(3AR,6R,6aR)-6-...

CAS#:75467-36-6

Literature: Tetrahedron, , vol. 60, # 31 p. 6609 - 6617
N/A structure

N/A

CAS#:154976-39-3

~%

(3AR,6R,6aR)-6-(((tert-butyldimethylsilyl)oxy)methyl)-2,2-dimethyldihydrofuro[3,4-d][1,3]dioxol-4(3aH)-one Structure

(3AR,6R,6aR)-6-...

CAS#:75467-36-6

Literature: Journal of Organic Chemistry, , vol. 59, # 10 p. 2715 - 2723
2,2-Dimethoxypropane structure

2,2-Dimethoxypropane

CAS#:77-76-9

~%

(3AR,6R,6aR)-6-(((tert-butyldimethylsilyl)oxy)methyl)-2,2-dimethyldihydrofuro[3,4-d][1,3]dioxol-4(3aH)-one Structure

(3AR,6R,6aR)-6-...

CAS#:75467-36-6

Literature: European Journal of Organic Chemistry, , # 12 p. 2293 - 2297
D-Ribonolactone structure

D-Ribonolactone

CAS#:5336-08-3

~%

(3AR,6R,6aR)-6-(((tert-butyldimethylsilyl)oxy)methyl)-2,2-dimethyldihydrofuro[3,4-d][1,3]dioxol-4(3aH)-one Structure

(3AR,6R,6aR)-6-...

CAS#:75467-36-6

Literature: Tetrahedron, , vol. 60, # 31 p. 6609 - 6617

 Synonyms

MFCD00216623
5-o-tert-butyldimethylsilyl-2,3-o-isopropylidene-d-lyxono-1,4-lactone
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(3AR,6R,6aR)-6-(((tert-butyldimethylsilyl)oxy)methyl)-2,2-dimethyldihydrofuro[3,4-d][1,3]dioxol-4(3aH)-one suppliers

(3AR,6R,6aR)-6-(((tert-butyldimethylsilyl)oxy)methyl)-2,2-dimethyldihydrofuro[3,4-d][1,3]dioxol-4(3aH)-one price

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Chemsrc provides CAS#:75467-36-6 MSDS, density, melting point, boiling point, structure, etc. Its name is (3AR,6R,6aR)-6-(((tert-butyldimethylsilyl)oxy)methyl)-2,2-dimethyldihydrofuro[3,4-d][1,3]dioxol-4(3aH)-one>> amp version: (3AR,6R,6aR)-6-(((tert-butyldimethylsilyl)oxy)methyl)-2,2-dimethyldihydrofuro[3,4-d][1,3]dioxol-4(3aH)-one

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