Vanadium(IV) chloride

Modify Date: 2024-01-02 18:34:17

Vanadium(IV) chloride Structure
Vanadium(IV) chloride structure
Common Name Vanadium(IV) chloride
CAS Number 7632-51-1 Molecular Weight 192.75400
Density 1.816 g/mL at 25ºC(lit.) Boiling Point 148 - 153ºC
Molecular Formula Cl4V Melting Point -28ºC
MSDS Chinese USA Flash Point 148.5°C/755mm
Symbol GHS05 GHS06
GHS05, GHS06
Signal Word Danger

 Names

Name Vanadium(IV) chloride
Synonym More Synonyms

 Chemical & Physical Properties

Density 1.816 g/mL at 25ºC(lit.)
Boiling Point 148 - 153ºC
Melting Point -28ºC
Molecular Formula Cl4V
Molecular Weight 192.75400
Flash Point 148.5°C/755mm
Exact Mass 190.81900
LogP 2.75800
Water Solubility diethyl ether: slightly soluble(lit.) | soluble alcohol, ether [HAW93]

 Toxicological Information

CHEMICAL IDENTIFICATION

RTECS NUMBER :
YW2625000
CHEMICAL NAME :
Vanadium tetrachloride
CAS REGISTRY NUMBER :
7632-51-1
LAST UPDATED :
199701
DATA ITEMS CITED :
21
MOLECULAR FORMULA :
Cl4-V
MOLECULAR WEIGHT :
192.74
WISWESSER LINE NOTATION :
VA G4

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
160 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value

MUTATION DATA

TYPE OF TEST :
Morphological transformation
TEST SYSTEM :
Rodent - hamster Embryo
REFERENCE :
AETODY Advances in Modern Environmental Toxicology. (Senate Press, Inc., P.O. Box 252, Princeton Junction, NJ 08550) V.1- 1980- Volume(issue)/page/year: 1,241,1980 *** OCCUPATIONAL EXPOSURE LIMITS *** OEL-AUSTRALIA:TWA 0.05 mg(V2O5)/m3 JAN 1993 OEL-BELGIUM:TWA 0.05 mg(V2O5)/m3 JAN 1993 OEL-DENMARK:TWA 0.03 mg(V2O5)/m3 JAN 1993 OEL-FINLAND:TWA 0.5 mg(V2O5)/m3 JAN 1993 OEL-FRANCE:TWA 0.05 mg(V2O5)/m3 JAN 1993 OEL-GERMANY:TWA 0.05 mg(V2O5)/m3 JAN 1993 OEL-HUNGARY:TWA 0.05 mg(V2O5)/m3;STEL 0.1 mg(V205)/m3 JAN 1993 OEL-JAPAN:TWA 0.5 mg(V2O5)/m3 JAN 1993 OEL-THE NETHERLANDS:TWA 0.5 mg(V2O5)/m3 JAN 1993 OEL-THE PHILIPPINES:TWA 0.25 mg(V205)/m3 JAN 1993 OEL-POLAND:TWA 0.5 mg(V2O5)/m3 JAN 1993 OEL-SWEDEN:STEL 0.05 mg(V2O5)/m3 JAN 1993 OEL-SWEDEN:TWA 0.2 mg(V2O5)/m3 (dust) JAN 1993 OEL-SWITZERLAND:TWA 0.05 mg(V2O5)/m3;STEL 0.25 mg(V2O5)/m3 JAN 1993 OEL-TURKEY:TWA 0.5 mg(V2O5)/m3 JAN 1993 OEL-UNITED KINGDOM:TWA 0.05 mg(V2O5)/m3 (dust) JAN 1993 OEL-UNITED KINGDOM:TWA 0.5 mg(V2O5)/m3 JAN 1993 *** NIOSH STANDARDS DEVELOPMENT AND SURVEILLANCE DATA *** NIOSH RECOMMENDED EXPOSURE LEVEL (REL) : NIOSH REL TO VANADIUM (as V2O5), resp dust/fume-air:CL 0.05 mg/m3/15M REFERENCE : NIOSH* National Institute for Occupational Safety and Health, U.S. Dept. of Health, Education, and Welfare, Reports and Memoranda. Volume(issue)/page/year: DHHS #92-100,1992

 Safety Information

Symbol GHS05 GHS06
GHS05, GHS06
Signal Word Danger
Hazard Statements H301 + H311 + H331-H314
Supplemental HS Reacts violently with water.
Precautionary Statements P261-P280-P301 + P310-P305 + P351 + P338-P310
Personal Protective Equipment Faceshields;full-face respirator (US);Gloves;Goggles;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter
Hazard Codes T
Risk Phrases R14;R23/24/25;R34
Safety Phrases S26-S27-S36/37/39-S45
RIDADR UN 2444 8/PG 1
WGK Germany 3
RTECS YW2625000
Packaging Group I

 Synthetic Route

 Synonyms

vanadium (iv) chloride
EINECS 231-561-1
MFCD00061343