Titanium(IV) iodide

Modify Date: 2025-08-25 19:05:31

Titanium(IV) iodide Structure
Titanium(IV) iodide structure
Common Name Titanium(IV) iodide
CAS Number 7720-83-4 Molecular Weight 555.485
Density 4.3 g/cm3 Boiling Point 377,1ºC
Molecular Formula I4Ti Melting Point 150-151ºC
MSDS Chinese USA Flash Point N/A
Symbol GHS05
GHS05
Signal Word Danger

 Names

Name titanium (iv) iodide
Synonym More Synonyms

 Chemical & Physical Properties

Density 4.3 g/cm3
Boiling Point 377,1ºC
Melting Point 150-151ºC
Molecular Formula I4Ti
Molecular Weight 555.485
Exact Mass 555.565796
LogP 3.54280

 MSDS


Section 1: Product Identification
Chemical Name:Titanium (IV) iodide (99.99%-Ti) PURATREM
CAS Registry Number:7720-83-4
Formula:TiI4
EINECS Number:231-754-0
Chemical Family:metal halide
Synonym:Titanium tetraiodide

Section 2: Composition and Information on Ingredients
IngredientCAS NumberPercentACGIH (TWA)OSHA (PEL)
Title Compound7720-83-4100%no datano data

Section 3: Hazards Identification
Corrosive to skin, eyes, and mucous membranes. May cause coughing, wheezing, shortness of breath,
Emergency Overview:
headache, nausea and vomiting. Ingestion may cause damage to the mouth, throat and esophagus.
Primary Routes of Exposure:Ingestion, inhalation, skin, eyes.
Eye Contact:Corrosive to eyes.
Skin Contact:Corrosive to skin.
Inhalation:Inhalation may cause inflammation of the respiratory tract, edema and chemical pneumonitis.
Ingestion:Ingestion may cause damage to the mouth, throat and esophagus.
Corrosive to skin, eyes and mucous membranes. Inhalation causes coughing, wheezing, shortness of breath,
Acute Health Affects:
headache, nausea, and vomiting. Ingestion may cause damage to the mouth throat and esophagus.
Chronic ingestion of iodides may produce iodism. Symptoms include skin rash, running nose, headache and
Chronic Health Affects:
irritation of mucous membranes.
NTP:No
IARC:No
OSHA:No

SECTION 4: First Aid Measures
Immediately flush the eyes with copious amounts of water for at least 10-15 minutes. A victim may need
Eye Exposure:
assistance in keeping their eye lids open. Get immediate medical attention.
Wash the affected area with water. Remove contaminated clothes if necessary. Seek medical assistance if
Skin Exposure:
irritation persists.
Remove the victim to fresh air. Closely monitor the victim for signs of respiratory problems, such as difficulty
Inhalation:
in breathing, coughing, wheezing, or pain. In such cases seek immediate medical assistance.
Seek medical attention immediately. Keep the victim calm. Give the victim water (only if conscious). Induce
Ingestion:
vomiting only if directed by medical personnel.

SECTION 5: Fire Fighting Measures
Flash Point:not applicable
Autoignition Temperature:none
Explosion Limits:none
Extinguishing Medium:none required
If involved in a fire, fire fighters should be equipped with a NIOSH approved positive pressure self-contained
Special Fire Fighting Procedures:
breathing apparatus and full protective clothing.
Hazardous Combustion andIf involved in a fire this material may emit corrosive hydrogen iodide fumes.
Decomposion Products:
Unusual Fire or Explosion Hazards: No unusual fire or explosion hazards.

SECTION 6: Accidental Release Measures
Small spills can be mixed with powdered sodium bicarbonate, lime, or calcium carbonate and swept up.
Spill and Leak Procedures:Spillage in areas not adequately ventilated may require an evacuation of area. Emergency response teams
will require self-contained breathing apparatus.

SECTION 7: Handling and Storage
Store material in a tightly sealed bottle away from moisture. If possible, handle material in an efficient fume
Handling and Storage:
hood. Prolonged exposure to the atmosphere may lead to degradation of the product.

SECTION 8: Exposure Controls and Personal Protection
Eye Protection:Always wear approved safety glasses when handling a chemical substance in the laboratory.
Skin Protection:Wear protective clothing and gloves. Consult with glove manufacturer to determine the proper type of glove.
Ventilation:If possible, handle the material in an efficient fume hood.
In the absence of adequate ventilation a respirator should be worn. The use of a respiratory requires a
Respirator:
Respirator Protection Program to be in compliance with 29 CFR 1910.134.
Ventilation:If possible, handle the material in an efficient fume hood.
Additional Protection:No additional protection required.

SECTION 9: Physical and Chemical Properties
Color and Form:black xtl.
Molecular Weight:555.52
Melting Point:150°
Boiling Point:377.1°C
Vapor Pressure:no data
Specific Gravity:4.3
Odor:Pungent odor.
Solubility in Water:reacts with water

SECTION 10: Stability and Reactivity
Stability:moisture sensitive
Hazardous Polymerization:no hazardous polymerization
Conditions to Avoid:contact with moisture
Incompatibility:Oxidizing agents, water, alcohols, active metals and halogens
Decomposition Products:with moisture: hydrogen iodide

SECTION 11: Toxicological Information
RTECS Data:No information available in the RTECS files.
Carcinogenic Effects:no data
Mutagenic Effects:no data
Tetratogenic Effects:no data

SECTION 12: Ecological Information
Ecological Information:No information available

SECTION 13: Disposal Considerations
Disposal:Dispose of according to local, state and federal regulations.

SECTION 14: Transportation
Shipping Name (CFR):Corrosive Solid, Acidic, Inorganic, N.O.S.
Hazard Class (CFR):8
Additional Hazard Class (CFR):NA
Packaging Group (CFR):II
UN ID Number (CFR):UN# 3260
Shipping Name (IATA):Corrosive Solid, Acidic, Inorganic, N.O.S.
Hazard Class (IATA):8
Additional Hazard Class (IATA):NA
Packaging Group (IATA):II
UN ID Number (IATA):UN# 3260

SECTION 15: Regulatory Information
TSCA:Listed in the TSCA inventory.
SARA (Title 313):Title compound not listed.
Second Ingredient:none


SECTION 16 - ADDITIONAL INFORMATION
N/A

 Safety Information

Symbol GHS05
GHS05
Signal Word Danger
Hazard Statements H314
Precautionary Statements P280-P305 + P351 + P338-P310
Personal Protective Equipment Eyeshields;Faceshields;full-face particle respirator type N100 (US);Gloves;respirator cartridge type N100 (US);type P1 (EN143) respirator filter;type P3 (EN 143) respirator cartridges
Hazard Codes C
Risk Phrases R34
Safety Phrases 26-36/37/39-45
RIDADR UN3260
Packaging Group II

 Synthetic Route

~%

Titanium(IV) iodide Structure

Titanium(IV) iodide

CAS#:7720-83-4

Literature: Ann. Chim. Phys., , vol. 9, p. 229 - 237 Comptes Rendus Hebdomadaires des Seances de l'Academie des Sciences, , vol. 120, p. 290 - 296 Ti: MVol., 3.5, page 189 - 199

~%

Titanium(IV) iodide Structure

Titanium(IV) iodide

CAS#:7720-83-4

Literature: Bulletin de la Societe Chimique de France, , p. 201 - 203 Jahresbericht ueber die Fortschritte der Chemie und Verwandter Theile Anderer Wissenschaften, , p. 207

~%

Titanium(IV) iodide Structure

Titanium(IV) iodide

CAS#:7720-83-4

Literature: Bulletin de la Societe Chimique de France, , p. 201 - 203 Jahresbericht ueber die Fortschritte der Chemie und Verwandter Theile Anderer Wissenschaften, , p. 207

~0%

Titanium(IV) iodide Structure

Titanium(IV) iodide

CAS#:7720-83-4

Literature: Denes Georges Journal of Solid State Chemistry, 1988 , vol. 77, p. 54 - 59

~%

Titanium(IV) iodide Structure

Titanium(IV) iodide

CAS#:7720-83-4

Literature: Bulletin de la Societe Chimique de France, , vol. 7, p. 198 Bulletin de la Societe Chimique de France, , vol. 7, p. 201 - 201 I: MVol.2, 21, page 291 - 293

~99%

Titanium(IV) iodide Structure

Titanium(IV) iodide

CAS#:7720-83-4

Literature: Troyanov, S. I.; Mazo, G. N. Russian Journal of Inorganic Chemistry (Translation of Zhurnal Neorganicheskoi Khimii), 1988 , vol. 33, p. 499 - 501 Zhurnal Neorganicheskoi Khimii, 1988 , vol. 33, p. 889 - 892

~%

Titanium(IV) iodide Structure

Titanium(IV) iodide

CAS#:7720-83-4

Literature: Journal of Physical Chemistry, , vol. 8, p. 500 - 504

 Synonyms

iodine titanium
Titanium(4+) tetraiodide
MFCD00043077
Titanium (IV) iodide
Titanium(IV) iodide
EINECS 231-754-0
titanium iodide
TITANIUM TETRAIODIDE
iodide titanium
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