(S)-1,1,1-TRIFLUORO-N-(PYRROLIDIN-2-YLMETHYL)METHANESULFONAMIDE

Modify Date: 2024-01-04 11:52:52

(S)-1,1,1-TRIFLUORO-N-(PYRROLIDIN-2-YLMETHYL)METHANESULFONAMIDE structure	Common Name	(S)-1,1,1-TRIFLUORO-N-(PYRROLIDIN-2-YLMETHYL)METHANESULFONAMIDE
	CAS Number	782495-18-5	Molecular Weight	232.22400
	Density	N/A	Boiling Point	N/A
	Molecular Formula	C₆H₁₁F₃N₂O₂S	Melting Point	205-215°C
	MSDS	Chinese USA	Flash Point	N/A
	Symbol	GHS05	Signal Word	Danger

Name	1,1,1-trifluoro-N-[[(2S)-pyrrolidin-2-yl]methyl]methanesulfonamide
Synonym	More Synonyms

Melting Point	205-215°C
Molecular Formula	C₆H₁₁F₃N₂O₂S
Molecular Weight	232.22400
Exact Mass	232.04900
PSA	66.58000
LogP	1.97810
Storage condition	2-8°C

MSDS(Chinese)

Symbol	GHS05
Signal Word	Danger
Hazard Statements	H314
Precautionary Statements	P280-P305 + P351 + P338-P310
Personal Protective Equipment	Eyeshields;Faceshields;full-face particle respirator type N100 (US);Gloves;respirator cartridge type N100 (US);type P1 (EN143) respirator filter;type P3 (EN 143) respirator cartridges
Hazard Codes	C: Corrosive;
Risk Phrases	34
Safety Phrases	26-36/37/39-45
RIDADR	UN 3263 8/PG 3
Hazard Class	8.0
HS Code	2935009090

HS Code	2935009090
Summary	2935009090 other sulphonamides VAT:17.0% Tax rebate rate:9.0% Supervision conditions:none MFN tariff:6.5% General tariff:35.0%

A recyclable fluorous (S)-pyrrolidine sulfonamide promoted direct, highly enantioselective Michael addition of ketones and aldehydes to nitroolefins in water.

Org. Lett. 8 , 3077-3079, (2006)

[reaction: see text] A recycle and reusable fluorous (S)-pyrrolidine sulfonamide organocatalyst has been developed for promoting highly enantio- and diastereoselective Michael addition reactions of ke...

Highly enantioselective aldol reactions catalyzed by a recyclable fluorous (S) pyrrolidine sulfonamide on water.

Org. Lett. 10 , 1211-1214, (2008)

Fluorous (S) pyrrolidine sulfonamide serves as an efficient promoter for highly enantioselective aldol reactions of ketones and aldehydes with aromatic aldehydes on water. A notable feature of the org...

Direct, highly enantioselective pyrrolidine sulfonamide catalyzed Michael addition of aldehydes to nitrostyrenes.

Angew. Chem. Int. Ed. Engl. 44 , 1369-1371, (2005)