2,2,6,6-tetramethyl-3,5-heptanedionato silver (i)

Modify Date: 2024-01-11 11:42:29

2,2,6,6-tetramethyl-3,5-heptanedionato silver (i) Structure
2,2,6,6-tetramethyl-3,5-heptanedionato silver (i) structure
Common Name 2,2,6,6-tetramethyl-3,5-heptanedionato silver (i)
CAS Number 79827-25-1 Molecular Weight 291.13600
Density N/A Boiling Point N/A
Molecular Formula C11H19AgO2 Melting Point 178ºC (dec.)
MSDS N/A Flash Point N/A

 Names

Name 2,2,6,6-tetramethyl-3,5-heptanedionato silver (i)
Synonym More Synonyms

 Chemical & Physical Properties

Melting Point 178ºC (dec.)
Molecular Formula C11H19AgO2
Molecular Weight 291.13600
Exact Mass 290.04400
PSA 26.30000
LogP 3.01250

 MSDS


Section 1: Product Identification
Chemical Name:2,2,6,6-Tetramethyl-3,5-heptanedionato silver (I) (99.9%-Ag) [Ag(TMHD)]
CAS Registry Number:79827-25-1
Formula:AgC11H19O2
EINECS Number:none
Chemical Family:metal beta-diketonate complexes
Synonym:Dipivaloylmethane, silver complex

Section 2: Composition and Information on Ingredients
IngredientCAS NumberPercentACGIH (TWA)OSHA (PEL)
Title Compound79827-25-1100%no datano data

Section 3: Hazards Identification
No reports could be found indicating specific hazards are associated with this material. Toxicity is probably
Emergency Overview:
minimal.
Primary Routes of Exposure:Ingestion, Inhalation of dust.
Eye Contact:May cause slight to mild irritation of the eyes.
May cause slight to mild irritation of the skin. Contact with the skin can lead to formation of dark blotches
Skin Contact:
(silver staining)
Inhalation:Dust may be irritating to the nose, mucous membranes and respiratory tract.
Ingestion:No information on the physiological effects of ingestion.
Acute Health Affects:May be irritating to skin, eyes and respiratory tract.
Chronic Health Affects:No information available on long-term chronic effects.
NTP:No
IARC:No
OSHA:No

SECTION 4: First Aid Measures
Immediately flush the eyes with copious amounts of water for at least 10-15 minutes. A victim may need
Eye Exposure:
assistance in keeping their eye lids open. Get immediate medical attention.
Wash the affected area with soap and water. Remove contaminated clothes if necessary. Seek medical
Skin Exposure:
assistance if irritation persists.
Remove the victim to fresh air. Closely monitor the victim for signs of respiratory problems, such as difficulty
Inhalation:
in breathing, coughing, wheezing, or pain. In such cases seek immediate medical assistance.
Ingestion:Seek medical attention immediately. Keep the victim calm. Give the victim water (only if conscious).

SECTION 5: Fire Fighting Measures
Flash Point:not applicable
Autoignition Temperature:none
Explosion Limits:none
Extinguishing Medium:carbon dioxide, dry powder or foam
If involved in a fire, fire fighters should be equipped with a NIOSH approved positive pressure self-contained
Special Fire Fighting Procedures:
breathing apparatus and full protective clothing.
Hazardous Combustion andIf involved in a fire this material may emit toxic organic fumes.
Decomposion Products:
Unusual Fire or Explosion Hazards: No unusual fire or explosion hazards.

SECTION 6: Accidental Release Measures
Spill and Leak Procedures:Small spills can be mixed with vermiculite or sodium carbonate and swept up.

SECTION 7: Handling and Storage
Handling and Storage:Store in a sealed container. Keep away from heat and moisture.

SECTION 8: Exposure Controls and Personal Protection
Eye Protection:Always wear approved safety glasses when handling a chemical substance in the laboratory.
Skin Protection:Wear appropriate chemical resistant gloves and protective clothing.
Ventilation:Material may form a fine dust. If possible, handle the material in an efficient fume hood.
If in form of fine dust and ventilation is not available a respirator should be worn. The use of respirators
Respirator:
requires a Respirator Protection Program to be in compliance with 29 CFR 1910.134.
Ventilation:Material may form a fine dust. If possible, handle the material in an efficient fume hood.
Additional Protection:No additional protection required.

SECTION 9: Physical and Chemical Properties
Color and Form:gray pwdr.
Molecular Weight:291.14
Melting Point:178° dec.
Boiling Point:no data
Vapor Pressure:not applicable
Specific Gravity:no data
Odor:none
Solubility in Water:insoluble

SECTION 10: Stability and Reactivity
Stability:air and moisture stable solid
Hazardous Polymerization:no hazardous polymerization
Conditions to Avoid:none
Incompatibility:oxidizing agents
Decomposition Products:Carbon dioxide, carbon monoxide, organic vapors, and metal oxides and carbonates.

SECTION 11: Toxicological Information
RTECS Data:No information available in the RTECS files.
Carcinogenic Effects:No data available
Mutagenic Effects:No data available
Tetratogenic Effects:No data available

SECTION 12: Ecological Information
Ecological Information:No information available

SECTION 13: Disposal Considerations
Disposal:Dispose of according to local, state and federal regulations.

SECTION 14: Transportation
Shipping Name (CFR):Non-hazardous
Hazard Class (CFR):NA
Additional Hazard Class (CFR):NA
Packaging Group (CFR):NA
UN ID Number (CFR):NA
Shipping Name (IATA):Non-hazardous
Hazard Class (IATA):NA
Additional Hazard Class (IATA):NA
Packaging Group (IATA):NA
UN ID Number (IATA):NA

SECTION 15: Regulatory Information
TSCA:Not listed in the TSCA inventory.
SARA (Title 313):Title compound: See Category Code N740 for reporting.
Second Ingredient:none


SECTION 16 - ADDITIONAL INFORMATION
N/A

 Safety Information

Risk Phrases 36/37/38
Safety Phrases 26-36/37/39

 Synonyms

TetramethylheptanedionatosilverI
silver 2,2,6,6-tetramethyl-3,5-heptanedionate
2,2,5-TRIMETHYL-1,3-DIOXANE-5-CARBOXYLIC ACID VINYL ESTER-D3