a-D-Xylofuranose,1,2-O-(1-methylethylidene)-, 5-acetate

Modify Date: 2024-01-13 19:01:19

a-D-Xylofuranose,1,2-O-(1-methylethylidene)-, 5-acetate Structure
a-D-Xylofuranose,1,2-O-(1-methylethylidene)-, 5-acetate structure
Common Name a-D-Xylofuranose,1,2-O-(1-methylethylidene)-, 5-acetate
CAS Number 80244-96-8 Molecular Weight 232.23000
Density 1.228g/cm3 Boiling Point 340.5ºC at 760mmHg
Molecular Formula C10H16O6 Melting Point N/A
MSDS N/A Flash Point 130.4ºC

 Names

Name (6-hydroxy-2,2-dimethyl-3a,5,6,6a-tetrahydrofuro[2,3-d][1,3]dioxol-5-yl)methyl acetate
Synonym More Synonyms

 Chemical & Physical Properties

Density 1.228g/cm3
Boiling Point 340.5ºC at 760mmHg
Molecular Formula C10H16O6
Molecular Weight 232.23000
Flash Point 130.4ºC
Exact Mass 232.09500
PSA 74.22000
Index of Refraction 1.468

 Synthetic Route

~91%

a-D-Xylofuranose,1,2-O-(1-methylethylidene)-, 5-acetate Structure

a-D-Xylofuranos...

CAS#:80244-96-8

Literature: Ishihara, Kazuaki; Kurihara, Hideki; Yamamoto, Hisashi Journal of Organic Chemistry, 1993 , vol. 58, # 15 p. 3791 - 3793

~%

a-D-Xylofuranose,1,2-O-(1-methylethylidene)-, 5-acetate Structure

a-D-Xylofuranos...

CAS#:80244-96-8

Literature: ANADYS PHARMACEUTICALS, INC.; HALEY, Gregory, J. Patent: WO2010/57103 A1, 2010 ; Location in patent: Page/Page column 13; 14 ;

~28%

a-D-Xylofuranose,1,2-O-(1-methylethylidene)-, 5-acetate Structure

a-D-Xylofuranos...

CAS#:80244-96-8

Literature: Ishihara, Kazuaki; Kurihara, Hideki; Yamamoto, Hisashi Journal of Organic Chemistry, 1993 , vol. 58, # 15 p. 3791 - 3793

~70%

a-D-Xylofuranose,1,2-O-(1-methylethylidene)-, 5-acetate Structure

a-D-Xylofuranos...

CAS#:80244-96-8

Literature: Ishido, Yoshiharu; Sakairi, Nobuo; Sekiya, Masao; Nakazaki, Nobuo Carbohydrate Research, 1981 , vol. 97, p. 51 - 80

~66%

a-D-Xylofuranose,1,2-O-(1-methylethylidene)-, 5-acetate Structure

a-D-Xylofuranos...

CAS#:80244-96-8

Literature: Nishida, Atsushi; Oishi, Satoshi; Yonemitsu, Osamu Chemical & Pharmaceutical Bulletin, 1989 , vol. 37, # 8 p. 2266 - 2268

~77%

a-D-Xylofuranose,1,2-O-(1-methylethylidene)-, 5-acetate Structure

a-D-Xylofuranos...

CAS#:80244-96-8

Literature: Mota, Antonio J.; Robles, Rafael; De Cienfuegos, Luis Alvarez; Lamenca, Alberto Tetrahedron Letters, 2004 , vol. 45, # 17 p. 3349 - 3353

~22%

a-D-Xylofuranose,1,2-O-(1-methylethylidene)-, 5-acetate Structure

a-D-Xylofuranos...

CAS#:80244-96-8

Literature: Rana, Surjit S.; Barlow, Joseph J.; Matta, Khushi L. Tetrahedron Letters, 1981 , vol. 22, # 50 p. 5007 - 5010

~%

a-D-Xylofuranose,1,2-O-(1-methylethylidene)-, 5-acetate Structure

a-D-Xylofuranos...

CAS#:80244-96-8

Literature: Levene; Raymond Journal of Biological Chemistry, 1933 , vol. 102, p. 317,323 Journal of Biological Chemistry, 1934 , vol. 107, p. 75,78

 Synonyms

5-Acetyl-1,2-isopropylidene-alfa-D-xylofuranose
[(3aR,5R,6S,6aR)-6-hydroxy-2,2-dimethyl-3a,5,6,6a-tetrahydrofuro[2,3-d][1,3]dioxol-5-yl]methyl acetate