4,4′-Diamino-2,2′-stilbenedisulfonic acid

Modify Date: 2024-01-07 01:26:00

4,4′-Diamino-2,2′-stilbenedisulfonic acid Structure
4,4′-Diamino-2,2′-stilbenedisulfonic acid structure
Common Name 4,4′-Diamino-2,2′-stilbenedisulfonic acid
CAS Number 81-11-8 Molecular Weight 370.401
Density 1.7±0.1 g/cm3 Boiling Point N/A
Molecular Formula C14H14N2O6S2 Melting Point 300 °C
MSDS Chinese USA Flash Point N/A
Symbol GHS07
GHS07
Signal Word Warning

 Names

Name 4,4'-Diamino-2,2'-stilbenedisulfonic acid
Synonym More Synonyms

 Chemical & Physical Properties

Density 1.7±0.1 g/cm3
Melting Point 300 °C
Molecular Formula C14H14N2O6S2
Molecular Weight 370.401
Exact Mass 370.029327
PSA 177.54000
LogP -1.72
Index of Refraction 1.726
Storage condition -20°C Freezer
Stability Stable. Combustible. Incompatible with iron, strong oxidizing agents.
Water Solubility <0.1 g/100 mL at 23 ºC

 Toxicological Information

CHEMICAL IDENTIFICATION

RTECS NUMBER :
WJ6603000
CHEMICAL NAME :
2,2'-Stilbenedisulfonic acid, 4,4'-diamino-
CAS REGISTRY NUMBER :
81-11-8
BEILSTEIN REFERENCE NO. :
0629516
LAST UPDATED :
199701
DATA ITEMS CITED :
4
MOLECULAR FORMULA :
C14-H14-N2-O6-S2
MOLECULAR WEIGHT :
370.42
WISWESSER LINE NOTATION :
WSQR CZ F1U1R DZ BSWQ

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - guinea pig
DOSE/DURATION :
47 gm/kg
TOXIC EFFECTS :
Liver - liver function tests impaired Kidney, Ureter, Bladder - renal function tests depressed
REFERENCE :
GISAAA Gigiena i Sanitariya. For English translation, see HYSAAV. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR) V.1- 1936- Volume(issue)/page/year: 45(3),73,1980 ** REPRODUCTIVE DATA **
TYPE OF TEST :
TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE :
Intraperitoneal
DOSE :
300 mg/kg
SEX/DURATION :
female 1 day(s) pre-mating
TOXIC EFFECTS :
Reproductive - Maternal Effects - uterus, cervix, vagina
REFERENCE :
JTEHD6 Journal of Toxicology and Environmental Health. (Hemisphere Pub., 1025 Vermont Ave., NW, Washington, DC 20005) V.1- 1975/76- Volume(issue)/page/year: 36,13,1992 *** NIOSH STANDARDS DEVELOPMENT AND SURVEILLANCE DATA *** NIOSH OCCUPATIONAL EXPOSURE SURVEY DATA : NOES - National Occupational Exposure Survey (1983) NOES Hazard Code - T1888 No. of Facilities: 38 (estimated) No. of Industries: 2 No. of Occupations: 5 No. of Employees: 948 (estimated)

 Safety Information

Symbol GHS07
GHS07
Signal Word Warning
Hazard Statements H302
Personal Protective Equipment dust mask type N95 (US);Eyeshields;Gloves
Hazard Codes C:Corrosive
Risk Phrases R34
Safety Phrases S24/25-S45-S36/37/39-S26-S22
RIDADR UN 2583
RTECS WJ6603000
HS Code 2921420090

 Synthetic Route

~%

4,4′-Diamino-2,2′-stilbenedisulfonic acid Structure

4,4′-Diamino-2,...

CAS#:81-11-8

Literature: Chemische Berichte, , vol. 30, p. 3100 Journal of the Chemical Society, , vol. 89, p. 1605 Chemische Berichte, , vol. 36, p. 1554

~%

4,4′-Diamino-2,2′-stilbenedisulfonic acid Structure

4,4′-Diamino-2,...

CAS#:81-11-8

Literature: DE38735 ; Fortschr. Teerfarbenfabr. Verw. Industriezweige, vol. 1, p. 510

~%

4,4′-Diamino-2,2′-stilbenedisulfonic acid Structure

4,4′-Diamino-2,...

CAS#:81-11-8

Literature: Chemische Berichte, , vol. 19, p. 3235 DE40575 ; Fortschr. Teerfarbenfabr. Verw. Industriezweige, vol. 1, p. 512

~%

4,4′-Diamino-2,2′-stilbenedisulfonic acid Structure

4,4′-Diamino-2,...

CAS#:81-11-8

Literature: Bulletin de la Societe Chimique de France, , vol. <3> 29, p. 349

~%

4,4′-Diamino-2,2′-stilbenedisulfonic acid Structure

4,4′-Diamino-2,...

CAS#:81-11-8

Literature: Journal of the American Chemical Society, , vol. 70, p. 2802,2804

~%

4,4′-Diamino-2,2′-stilbenedisulfonic acid Structure

4,4′-Diamino-2,...

CAS#:81-11-8

Literature: Journal of the American Chemical Society, , vol. 70, p. 2802,2804

~%

4,4′-Diamino-2,2′-stilbenedisulfonic acid Structure

4,4′-Diamino-2,...

CAS#:81-11-8

Literature: Journal of the American Chemical Society, , vol. 70, p. 2802,2804

~%

4,4′-Diamino-2,2′-stilbenedisulfonic acid Structure

4,4′-Diamino-2,...

CAS#:81-11-8

Literature: Journal of the Chemical Society, , vol. 89, p. 1605

~%

Detail
Literature: Journal of the Chemical Society, , vol. 89, p. 1605 Chemische Berichte, , vol. 36, p. 1554

 Customs

HS Code 2921420090
Summary HS:2921420090 aniline derivatives and their salts VAT:17.0% Tax rebate rate:9.0% Supervision conditions:none MFN tariff:6.5% General tariff:30.0%

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 Synonyms

MFCD00024946
4,4'-diaminostilbene-2,2'-disulphonic acid
4,4′-Diamino-2,2′-stilbenedisulfonic acid
2,2'-(1,2-ethenediyl)bis(5-amino)benzenesulfonic acid
2,2'-(1,2-Ethenediyl)bis(5-aminobenzenesulfonic acid)
DSD ACID
Amsonic acid
AMSOMICACID
2,2'-Ethene-1,2-diylbis(5-aminobenzenesulfonic acid)
DASDA
flavonicacid
Benzenesulfonic acid, 2,2'-(1,2-ethenediyl)bis[5-amino-
4,4'-diamino-stilbene-2,2'-disulfonic acid
DASD
DAS
4,4'-Diamino-2,2'-stilbenedisulfonic acid
EINECS 201-325-2
tinopalbhs
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