potassium t-butoxide

Modify Date: 2024-01-01 23:16:40

potassium t-butoxide Structure
potassium t-butoxide structure
Common Name potassium t-butoxide
CAS Number 865-47-4 Molecular Weight 112.21
Density 0.910 g/mL at 20 °C Boiling Point 275°C
Molecular Formula C4H9KO Melting Point 256-258 °C (dec.)(lit.)
MSDS Chinese USA Flash Point 54 °F
Symbol GHS02 GHS05
GHS02, GHS05
Signal Word Danger

 Use of potassium t-butoxide


Potassium tert-butoxide (Potassiumtbutoxide) is a biochemical reagent that can be used as a biological material or organic compound for life science related research.

 Names

Name Potassium tert-butanolate
Synonym More Synonyms

 potassium t-butoxide Biological Activity

Description Potassium tert-butoxide (Potassiumtbutoxide) is a biochemical reagent that can be used as a biological material or organic compound for life science related research.
Related Catalog

 Chemical & Physical Properties

Density 0.910 g/mL at 20 °C
Boiling Point 275°C
Melting Point 256-258 °C (dec.)(lit.)
Molecular Formula C4H9KO
Molecular Weight 112.21
Flash Point 54 °F
Exact Mass 112.029045
PSA 23.06000
LogP 1.21540
Vapour Pressure 1 mm Hg ( 220 °C)
Storage condition Flammables area
Stability Stable, but reacts violently with water and acids, possibly leading to fire. Incompatible with water, acids, halogenated hydrocarbons, alcohols, strong oxidizing agents, ketones, carbon dioxide.
Water Solubility REACTS

 Safety Information

Symbol GHS02 GHS05
GHS02, GHS05
Signal Word Danger
Hazard Statements H228-H260-H314
Supplemental HS Reacts violently with water.
Precautionary Statements P210-P231 + P232-P280-P305 + P351 + P338-P370 + P378-P402 + P404
Personal Protective Equipment Faceshields;full-face respirator (US);Gloves;Goggles;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter
Hazard Codes C:Corrosive
Risk Phrases R11;R14;R19;R35
Safety Phrases S16-S26-S36/37/39-S43-S45-S7/9-S8-S43A-S33-S27
RIDADR UN 3274 3/PG 2
WGK Germany 1
Packaging Group I
Hazard Class 8
HS Code 29051900

 Synthetic Route

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potassium t-butoxide Structure

potassium t-butoxide

CAS#:865-47-4

Literature: US2005/101806 A1, ; Page/Page column 4 ;

 Customs

HS Code 2915900090
Summary 2915900090 other saturated acyclic monocarboxylic acids and their anhydrides, halides, peroxides and peroxyacids; their halogenated, sulphonated, nitrated or nitrosated derivatives VAT:17.0% Tax rebate rate:9.0% Supervision conditions:AB(certificate of inspection for goods inward,certificate of inspection for goods outward) MFN tariff:5.5% General tariff:30.0%

 Articles32

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Silylation of C-H bonds in aromatic heterocycles by an Earth-abundant metal catalyst.

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Heteroaromatic compounds containing carbon-silicon (C-Si) bonds are of great interest in the fields of organic electronics and photonics, drug discovery, nuclear medicine and complex molecule synthesi...

Encapsulation of fish oil with N-stearoyl O-butylglyceryl chitosan using membrane and ultrasonic emulsification processes.

Carbohydr. Polym. 123 , 432-42, (2015)

Fish oil-loaded microcapsules were prepared from oil-in-water emulsions using N-stearoyl O-butylglyceryl chitosan as shell material. The emulsions were prepared by both membrane and ultrasonic emulsif...

Utilizing capillary gas chromatography mass spectrometry to determine 4-benzotrifluoride t-butyl ether as a reaction by-product in fluoxetine synthesized using potassium t-butoxide as base.

J. Pharm. Biomed. Anal. 31(1) , 63-74, (2003)

Fluoxetine hydrochloride has been prepared using two similar synthetic routes, both of which rely upon an ether formation reaction mediated by a base. The base used can affect the impurity profile of ...

 Synonyms

potassium,2-methylpropan-2-olate
tBuOK
Kalium-2-methylpropan-2-olat
KOtBu
MFCD00012162
potassium t-butoxide
Potassium tert-butoxide
tert-Butoxide, potassium
potassium 2-methylpropan-2-olate
EINECS 212-740-3
Potassium 2-methyl-2-propanolate
2-Propanol, 2-methyl-, potassium salt (1:1)
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