5-(di-tert-Butylphosphino)-1',3',5'-triphenyl-1'h-[1,4']bipyrazole

Modify Date: 2024-01-08 15:07:35

5-(di-tert-Butylphosphino)-1',3',5'-triphenyl-1'h-[1,4']bipyrazole Structure
5-(di-tert-Butylphosphino)-1',3',5'-triphenyl-1'h-[1,4']bipyrazole structure
Common Name 5-(di-tert-Butylphosphino)-1',3',5'-triphenyl-1'h-[1,4']bipyrazole
CAS Number 894086-00-1 Molecular Weight 506.621
Density N/A Boiling Point 652.7±55.0 °C at 760 mmHg
Molecular Formula C32H35N4P Melting Point 169-173ºC
MSDS Chinese USA Flash Point 348.5±31.5 °C

 Names

Name ditert-butyl-[2-(1,3,5-triphenylpyrazol-4-yl)pyrazol-3-yl]phosphane
Synonym More Synonyms

 Chemical & Physical Properties

Boiling Point 652.7±55.0 °C at 760 mmHg
Melting Point 169-173ºC
Molecular Formula C32H35N4P
Molecular Weight 506.621
Flash Point 348.5±31.5 °C
Exact Mass 506.259918
PSA 49.23000
LogP 9.82
Vapour Pressure 0.0±1.9 mmHg at 25°C

 MSDS


Section 1: Product Identification
Chemical Name:5-(Di-t-butylphosphino)-1',3',5'-triphenyl-1,4'-bi-1H-pyrazole, min. 95% t-Bu-BippyPhos
CAS Registry Number:894086-00-1
Formula:C32H35N4P
EINECS Number:none
Chemical Family:organophosphine salt
Synonym:y-Bu-BippyPhos; 5-(Di-tert-butyl-phosphanyl)-1',3',5'-triphenyl-1'H-[1,4']bipyrazolyl

Section 2: Composition and Information on Ingredients
IngredientCAS NumberPercentACGIH (TWA)OSHA (PEL)
Title compound894086-00-1100%no datano data

Section 3: Hazards Identification
Emergency Overview:Irritating to skin, eyes and respiratory tract.
Primary Routes of Exposure:Ingestion, inhalation
Eye Contact:Causes slight to mild irritation of the eyes.
Skin Contact:Causes slight to mild irritation of the skin.
Inhalation:Irritating to the nose, mucous membranes and respiratory tract.
Ingestion:No information available on the physiological effects of ingestion. May be harmful if swallowed.
Acute Health Affects:Irritating to skin, eyes and respiratory tract.
Chronic Health Affects:No information on long-term chronic effects.
NTP:No
IARC:No
OSHA:No

SECTION 4: First Aid Measures
Immediately flush the eyes with copious amounts of water for at least 10-15 minutes. A victim may need
Eye Exposure:
assistance in keeping their eye lids open. Get immediate medical attention.
Wash the affected area with water. Remove contaminated clothes if necessary. Seek medical assistance if
Skin Exposure:
irritation persists.
Remove the victim to fresh air. Closely monitor the victim for signs of respiratory problems, such as difficulty
Inhalation:
in breathing, coughing, wheezing, or pain. In such cases seek immediate medical assistance.
Seek medical attention immediately. Keep the victim calm. Give the victim water (only if conscious). Induce
Ingestion:
vomiting only if directed by medical personnel.

SECTION 5: Fire Fighting Measures
Flash Point:no data
Autoignition Temperature:no data
Explosion Limits:no data
Extinguishing Medium:carbon dioxide, dry powder or foam
If this product is involved in a fire, fire fighters should be equipped with a NIOSH approved positive pressure
Special Fire Fighting Procedures:
self-contained breathing apparatus and full protective clothing.
Hazardous Combustion andIf involved in a fire this material may emit irritating fumes.
Decomposion Products:
Unusual Fire or Explosion Hazards: No unusual fire or explosion hazards.

SECTION 6: Accidental Release Measures
Spill and Leak Procedures:Small spills can be mixed with vermiculite or sodium carbonate and swept up.

SECTION 7: Handling and Storage
The material will degrade on prolonged exposure to air. Store in a tightly sealed container under an inert
Handling and Storage:
atmosphere of nitrogen or argon.

SECTION 8: Exposure Controls and Personal Protection
Eye Protection:Always wear approved safety glasses when handling a chemical substance in the laboratory.
Skin Protection:Wear protective clothing and gloves.
Ventilation:Handle the material in an efficient fume hood.
If ventilation is not available a respirator should be worn. The use of respirators requires a Respirator
Respirator:
Protection Program to be in compliance with 29 CFR 1910.134.
Ventilation:Handle the material in an efficient fume hood.
Additional Protection:No additional protection required.

SECTION 9: Physical and Chemical Properties
Color and Form:white powder
Molecular Weight:506.62
Melting Point:169-173°
Boiling Point:no data
Vapor Pressure:no data
Specific Gravity:no data
Odor:none
Solubility in Water:insoluble

SECTION 10: Stability and Reactivity
Stability:air sensitive
Hazardous Polymerization:no hazardous polymerization
Conditions to Avoid:prolonged exposure to air
Incompatibility:strong oxidizing agents
Decomposition Products:carbon monoxide, carbon dioxide, phosphorus oxides and organic fumes

SECTION 11: Toxicological Information
RTECS Data:No information available in the RTECS files.
Carcinogenic Effects:no data
Mutagenic Effects:no data
Tetratogenic Effects:no data

SECTION 12: Ecological Information
Ecological Information:No information available

SECTION 13: Disposal Considerations
Disposal:Dispose of according to local, state and federal regulations.

SECTION 14: Transportation
Shipping Name (CFR):Non-hazardous
Hazard Class (CFR):NA
Additional Hazard Class (CFR):NA
Packaging Group (CFR):NA
UN ID Number (CFR):NA
Shipping Name (IATA):Non-hazardous
Hazard Class (IATA):NA
Additional Hazard Class (IATA):NA
Packaging Group (IATA):NA
UN ID Number (IATA):NA

SECTION 15: Regulatory Information
TSCA:Not listed in the TSCA inventory
SARA (Title 313):Title compound not listed
Second Ingredient:none


SECTION 16 - ADDITIONAL INFORMATION
N/A

 Safety Information

Hazard Codes Xi
RIDADR NONH for all modes of transport

 Articles4

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The bis-pyrazole phosphine ligand BippyPhos is effective for the palladium-catalyzed cross-coupling of hydroxylamines with aryl bromides, chlorides, and iodides. Reactions proceed smoothly at 80 degre...

 Synonyms

T-BU-BIPPYPHOS
5-[Bis(2-methyl-2-propanyl)phosphino]-1',3',5'-triphenyl-1'H-1,4'-bipyrazole
1,4'-Bi-1H-pyrazole, 5-[bis(1,1-dimethylethyl)phosphino]-1',3',5'-triphenyl-
BippyPhos
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