dichloro-[1,3-bis(diisopropylphenyl)imidazolylidene]-(3-chloropyridyl)palladium(ii)

Modify Date: 2025-08-27 10:10:10

dichloro-[1,3-bis(diisopropylphenyl)imidazolylidene]-(3-chloropyridyl)palladium(ii) Structure
dichloro-[1,3-bis(diisopropylphenyl)imidazolylidene]-(3-chloropyridyl)palladium(ii) structure
Common Name dichloro-[1,3-bis(diisopropylphenyl)imidazolylidene]-(3-chloropyridyl)palladium(ii)
CAS Number 905459-27-0 Molecular Weight 681.475
Density N/A Boiling Point N/A
Molecular Formula C32H42Cl3N3Pd Melting Point 240℃ (DEC.)
MSDS Chinese USA Flash Point N/A
Symbol GHS07
GHS07
Signal Word Warning

 Names

Name [1,3-Bis(2,6-Diisopropylphenyl)imidazol-2-ylidene](3-chloropyridyl)palladium(II) dichloride
Synonym More Synonyms

 Chemical & Physical Properties

Melting Point 240℃ (DEC.)
Molecular Formula C32H42Cl3N3Pd
Molecular Weight 681.475
Exact Mass 679.147888
PSA 19.37000
LogP 3.80850

 Safety Information

Symbol GHS07
GHS07
Signal Word Warning
Hazard Statements H302-H312-H332
Precautionary Statements P280
Personal Protective Equipment dust mask type N95 (US);Eyeshields;Gloves
Hazard Codes Xn
Risk Phrases 20/21/22
RIDADR NONH for all modes of transport
HS Code 28439000

 Articles6

More Articles
A user-friendly, all-purpose Pd-NHC (NHC=N-heterocyclic carbene) precatalyst for the negishi reaction: a step towards a universal cross-coupling catalyst.

Chemistry 12 , 4749, (2006)

We have developed the first user-friendly Negishi protocol capable of routinely cross-coupling all combinations of alkyl and aryl centers. The use of an easily synthesized, air stable, highly active, ...

Palladium complexes of N-heterocyclic carbenes as catalysts for cross-coupling reactions--a synthetic chemist's perspective.

Angew. Chem. Int. Ed. Engl. 46 , 2768, (2007)

Palladium-catalyzed C-C and C-N bond-forming reactions are among the most versatile and powerful synthetic methods. For the last 15 years, N-heterocyclic carbenes (NHCs) have enjoyed increasing popula...

Pd-catalyzed aryl amination mediated by well defined, N-heterocyclic carbene (NHC)-Pd precatalysts, PEPPSI.

Chemistry 14 , 2443, (2008)

Pd-N-heterocyclic carbene (NHC)-catalyzed Buchwald-Hartwig amination protocols mediated by Pd-PEPPSI precatalysts is described. These protocols provide access to a range of hindered and functionalized...

 Synonyms

1,3-bis[2,6-di(propan-2-yl)phenyl]-2H-imidazole,3-chloropyridine,dichloropalladium
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