1-Bromo-3-(chloromethyl)benzene

Modify Date: 2025-08-25 15:56:35

1-Bromo-3-(chloromethyl)benzene structure	Common Name	1-Bromo-3-(chloromethyl)benzene
	CAS Number	932-77-4	Molecular Weight	205.480
	Density	1.5±0.1 g/cm3	Boiling Point	245.5±15.0 °C at 760 mmHg
	Molecular Formula	C₇H₆BrCl	Melting Point	32.5ºC
	MSDS	Chinese USA	Flash Point	111.7±10.5 °C
	Symbol	GHS05	Signal Word	Danger

Name	3-Bromobenzyl chloride
Synonym	More Synonyms

Density	1.5±0.1 g/cm3
Boiling Point	245.5±15.0 °C at 760 mmHg
Melting Point	32.5ºC
Molecular Formula	C₇H₆BrCl
Molecular Weight	205.480
Flash Point	111.7±10.5 °C
Exact Mass	203.934128
LogP	3.26
Vapour Pressure	0.0±0.5 mmHg at 25°C
Index of Refraction	1.570

1-Bromo-3-(chloromethyl)benzene MSDS(Chinese)

Symbol	GHS05
Signal Word	Danger
Hazard Statements	H314
Precautionary Statements	P280-P305 + P351 + P338-P310
Personal Protective Equipment	Faceshields;full-face respirator (US);Gloves;Goggles;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter
Hazard Codes	C:Corrosive;
Risk Phrases	R34
Safety Phrases	S26-S27-S28-S36/37/39-S45
RIDADR	UN 3265 8/PG 2
WGK Germany	3
Packaging Group	III
Hazard Class	8
HS Code	2903999090

3-Bromobenzyl a...

CAS#:15852-73-0

~80%

1-Bromo-3-(chlo...

CAS#:932-77-4

Literature: Kim, Hyung Woo; Lee, Yun-Sang; Shetty, Dinesh; Lee, Hak Jeong; Lee, Dong Soo; Chung, June-Key; Lee, Myung Chul; Chung, Kyoo-Hyun; Jeong, Jae Min Bulletin of the Korean Chemical Society, 2010 , vol. 31, # 11 p. 3434 - 3436

3-Bromotoluene

CAS#:591-17-3

1-Bromo-3-(chlo...

CAS#:932-77-4

Literature: Monatshefte fuer Chemie, , vol. 64, p. 153,157 Journal fuer Praktische Chemie (Leipzig), , vol. <2> 133, p. 331,346

3-Bromobenzyl a...

CAS#:15852-73-0

3-Bromobenzyl b...

CAS#:823-78-9

1-Bromo-3-(chlo...

CAS#:932-77-4

Literature: Synthesis, , # 24 art. no. P08208SS, p. 3937 - 3940

2-Bromo-p-toluidine

CAS#:583-68-6

1-Bromo-3-(chlo...

CAS#:932-77-4

Literature: Monatshefte fuer Chemie, , vol. 64, p. 153,157

Sulfuryl chloride

CAS#:7791-25-5

3-Bromotoluene

CAS#:591-17-3

Benzoyl peroxide

CAS#:94-36-0

3-Bromobenzyl b...

CAS#:823-78-9

Detail

Literature: Journal of the American Chemical Society, , vol. 73, p. 2940

1,4-Dioxane

CAS#:123-91-1

Hydrochloric acid

CAS#:7647-01-0

3-(fluoromethyl...

CAS#:456-43-9

1-Bromo-3-(chlo...

CAS#:932-77-4

Literature: Journal of the American Chemical Society, , vol. 70, p. 2310,2313

Precursor 8
CAS#:15852-73-0 3-Bromobenzyl a... CAS#:591-17-3 3-Bromotoluene CAS#:583-68-6 2-Bromo-p-toluidine CAS#:7791-25-5 Sulfuryl chloride
CAS#:94-36-0 Benzoyl peroxide CAS#:123-91-1 1,4-Dioxane CAS#:7647-01-0 Hydrochloric acid CAS#:456-43-9 3-(fluoromethyl...
DownStream 10
CAS#:107558-73-6 diethyl 2-(3-br... CAS#:42287-90-1 3-(3-Bromopheny... CAS#:90433-27-5 4-(3-Bromopheny... CAS#:39959-54-1 3-Bromobenzylam...
CAS#:90433-28-6 4-(3-CYANOPHENY... CAS#:20600-29-7 1-bromo-3-(phen... CAS#:876473-54-0 2-(3-bromo-benz... CAS#:18257-89-1 1-ALLYL-3-BROMO...
CAS#:34598-49-7 5-Bromoindanone CAS#:1878-67-7 3-Bromophenylac...

HS Code	2903999090
Summary	2903999090 halogenated derivatives of aromatic hydrocarbons VAT:17.0% Tax rebate rate:9.0% Supervision conditions:none MFN tariff:5.5% General tariff:30.0%

Biologically stable [(18)F]-labeled benzylfluoride derivatives.

Nucl. Med. Biol. 27(2) , 163-8, (2000)

Use of the [(18)F]-fluoromethyl phenyl group is an attractive alternative to direct fluorination of phenyl groups because the fluorination of the methyl group takes place under milder reaction conditi...

Bromo Derivatives of Benzylphenols. I. Some Monobromo, Dibromo and Tribromo Derivatives of Ortho and Para Benzylphenols. Huston RC, et al.

J. Am. Chem. Soc. 55(5) , 2146-2149, (1933)

Facile Chlorination of Benzyl Alcohols Using 1, 8-Diazabicyclo [5.4. 0] undec-7-ene (DBU) and Sulfonyl Chlorides. Kim HW, et al.

ChemInform 42(14) , (2011)

1-Bromo-3-(chloromethyl)benzene

1-bromo-3-chloromethylbenzene

m-Bromobenzylchloride

3-Bromobenzylchloride

Benzene, 1-bromo-3-(chloromethyl)-

MFCD00040865