Methyl bromoacetate

Modify Date: 2025-08-21 19:26:55

Methyl bromoacetate Structure
Methyl bromoacetate structure
 Common Name Methyl bromoacetate
CAS Number 96-32-2 Molecular Weight 152.975
Density 1.6±0.1 g/cm3 Boiling Point 154.0±0.0 °C at 760 mmHg
Molecular Formula C3H5BrO2 Melting Point -50°C
MSDS Chinese USA Flash Point 62.8±0.0 °C
Symbol GHS05 GHS06
GHS05, GHS06		 Signal Word Danger

 Names

Name Methyl bromoacetate
Synonym More Synonyms

 Chemical & Physical Properties

Density 1.6±0.1 g/cm3
Boiling Point 154.0±0.0 °C at 760 mmHg
Melting Point -50°C
Molecular Formula C3H5BrO2
Molecular Weight 152.975
Flash Point 62.8±0.0 °C
Exact Mass 151.947281
PSA 26.30000
LogP 0.84
Vapour Pressure 3.2±0.2 mmHg at 25°C
Index of Refraction 1.450
Freezing Point <-50℃

 Toxicological Information

CHEMICAL IDENTIFICATION

RTECS NUMBER :
AF6300000
CHEMICAL NAME :
Acetic acid, bromo-, methyl ester
CAS REGISTRY NUMBER :
96-32-2
LAST UPDATED :
199701
DATA ITEMS CITED :
3
MOLECULAR FORMULA :
C3-H5-Br-O2
MOLECULAR WEIGHT :
152.99
WISWESSER LINE NOTATION :
E1VO1

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :
LDLo - Lowest published lethal dose
ROUTE OF EXPOSURE :
Intravenous
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
15800 ug/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
CBCCT* "Summary Tables of Biological Tests," National Research Council Chemical-Biological Coordination Center. (National Academy of Science Library, 2101 Constitution Ave., NW, Washington, DC 20418) Volume(issue)/page/year: 6,138,1954 *** NIOSH STANDARDS DEVELOPMENT AND SURVEILLANCE DATA *** NIOSH OCCUPATIONAL EXPOSURE SURVEY DATA : NOES - National Occupational Exposure Survey (1983) NOES Hazard Code - X7133 No. of Facilities: 7 (estimated) No. of Industries: 1 No. of Occupations: 1 No. of Employees: 1822 (estimated) No. of Female Employees: 272 (estimated)

 Safety Information

Symbol GHS05 GHS06
GHS05, GHS06
Signal Word Danger
Hazard Statements H301-H314-H335
Precautionary Statements P261-P280-P301 + P310-P305 + P351 + P338-P310
Personal Protective Equipment Faceshields;full-face respirator (US);Gloves;Goggles;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter
Hazard Codes T:Toxic
Risk Phrases R23/24/25
Safety Phrases S26-S36/37/39-S45-S28A-S36-S16
RIDADR UN 2643 6.1/PG 2
WGK Germany 3
RTECS AF6300000
Packaging Group II
Hazard Class 6.1
HS Code 29159080

 Synthetic Route

 Customs

HS Code 2915900090
Summary 2915900090 other saturated acyclic monocarboxylic acids and their anhydrides, halides, peroxides and peroxyacids; their halogenated, sulphonated, nitrated or nitrosated derivatives VAT:17.0% Tax rebate rate:9.0% Supervision conditions:AB(certificate of inspection for goods inward,certificate of inspection for goods outward) MFN tariff:5.5% General tariff:30.0%

 Articles4

More Articles
Studies on the collision-induced dissociation of adipoR agonists after electrospray ionization and their implementation in sports drug testing.

J. Mass Spectrom. 50(2) , 407-17, (2015)

AdipoR agonists are small, orally active molecules capable of mimicking the protein adiponectin, which represents an adipokine with antidiabetic and antiatherogenic effects. Two adiponectin receptors ...

Synthesis and characterization of some new 4-hydroxy-coumarin derivatives.

Molecules 19(8) , 11791-9, (2014)

Some novel coumarins were synthesized starting from 4-hydroxycoumarin and methyl bromoacetate. The structures of the newly obtained compounds were confirmed by elemental analysis, mass, IR and NMR spe...

One-pot method for stereoselective cyclopropanation of electron-deficient olefins with methyl bromoacetate and phenacyl bromide in the presence of triphenylarsine. Ren Z, et al.

Synthesis 2005(16) , 2718-22, (2005)

 Synonyms

BROMO METHYLACETATE
METHYL 2-BROMOACETATE
Methyl α-bromoacetate
2-Bromoacetic acid methyl ester
Methyl monobromoacetate
bromoacetic acid methyl ester
EINECS 202-499-2
BAM
Bromoacetic acid methyl
Methyl bromoacetate
MFCD00000189
Acetic acid, 2-bromo-, methyl ester
2-BROMOMETHYL ACETATE
Methyl bomoacetate
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