Chemistry of benzenesulfinyl azides. Reactions with sulfoxides

TJ Maricich, VL Hoffman

Index: Maricich,T.J.; Hoffman,V.L. Journal of the American Chemical Society, 1974 , vol. 96, p. 7770 - 7781

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Citation Number: 27

Abstract

Abstract: The preparation and decomposition of some benzenesulfinyl azides are reported. They undergo ready first-order decomposition with loss of nitrogen to give products which generally are consistent with a dipolar sulfinylnitrene intermediate. Unlike carbonyl and sulfonyl azides, the benzenesulfinyl azides do not undergo the Curtius rearrangement or react with CH bonds. In unreactive solvents like 1, 2-dimethoxyethane and acetonitrile, the ...

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