The Journal of Organic Chemistry

Some reactions of p-toluenesulfonyl isocyanate

C King

Index: King,C. Journal of Organic Chemistry, 1960 , vol. 25, p. 352 - 356

Full Text: HTML

Citation Number: 66

Abstract

Several new reactions of p-toluenesulfonyl isocyanate (I) are reported. Reaction with N, N- dialkylamides gives N, N-dialkyl-N'-p-toluenesulfonylamidines (11), with elimination of carbon dioxide. Monoalkylamides give rise to N-alkyl-N-acyl-N'-p-toluenesulfonylureas (111) by simple addition, or to N-alkyl-N'-p-toluenesulfonylamidines (IV), with elimination of carbon dioxide. Isobutyraldehyde reacts to give VI. Dimethyl sulfoxide yields Np- ...

Related Articles:

Chemistry of benzenesulfinyl azides. Reactions with sulfoxides

[Maricich,T.J.; Hoffman,V.L. Journal of the American Chemical Society, 1974 , vol. 96, p. 7770 - 7781]

Activation of dimethyl sulfoxide by electrophiles and use of the reactive intermediates in the preparation of iminosulfuranes

[Varkey,T.E. et al. Journal of Organic Chemistry, 1974 , vol. 39, p. 3365 - 3372]

Zur Kenntnis nichtmetallischer Iminverbindungen, XI. Aliphatische Sulfimine

[Appel,R.; Buechner,W. Chemische Berichte, 1962 , vol. 95, p. 855 - 866]

Tin for organic synthesis. 10. Unconventional regiospecific syntheses of aromatic carbonamides and thiocarbonamides by means of tin-mediated Friedel-Crafts …

[Arnswald, Martin; Neumann, Wilhelm P. Journal of Organic Chemistry, 1993 , vol. 58, # 25 p. 7022 - 7028]

Tin for organic synthesis. 10. Unconventional regiospecific syntheses of aromatic carbonamides and thiocarbonamides by means of tin-mediated Friedel-Crafts …

[Arnswald, Martin; Neumann, Wilhelm P. Journal of Organic Chemistry, 1993 , vol. 58, # 25 p. 7022 - 7028]

More Articles...