Structures of N, N-Dialkoxyamides: Pyramidal Anomeric Amides with Low Amidicity

SA Glover, JM White, AA Rosser…

Index: Bonin, Antonio M.; Glover, Stephen A.; Hammond, Gerard P. Journal of the Chemical Society, Perkin Transactions 2: Physical Organic Chemistry (1972-1999), 1994 , # 6 p. 1173 - 1180

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Citation Number: 18

Abstract

The first X-ray structures of two anomeric N, N-dialkoxyamides (2 and 3) have been obtained, which confirm that they are highly pyramidalized at nitrogen and have long N–CO bonds, a characteristic of other anomeric amides and a consequence of drastically reduced

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