Template-driven self-assembly of a porphyrin-containing supramolecular complex

JS Manka, DS Lawrence

Index: Manka; Lawrence Journal of the American Chemical Society, 1990 , vol. 112, # 6 p. 2440 - 2442

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Citation Number: 142

Abstract

3 sequestered by addition of an aqueous solution of sodium tetraphenylboron to produce the supramolecular entity 3, which instantaneously precipitated out of solution. This complex was purified on a cellulose gravity column (40% acetone/60% benzene) and obtained in an isolated yield of 85.3%. Several features of 3 are noteworthy:(I) Porphyrin encapsulation occurs via the secondary alcohol face of the Me-CD, as demonstrated by one-dimensional ...