Synthesis and chemistry of aryloxygermylene-amine complexes

E Bonnefille, S Mazières, N El Hawi, H Gornitzka…

Index: Bonnefille, Eric; Mazieres, Stephane; Hawi, Nancy El; Gornitzka, Heinz; Couret, Claude Journal of Organometallic Chemistry, 2006 , vol. 691, p. 5619 - 5625

Full Text: HTML

Citation Number: 11

Abstract

The synthesis of stable monomeric dimesityloxygermylene-amine (MesO) 2Ge-NR3 [NR3= Et2NH,(C6H11) 2NH, Et3N, dabco, tmeda] and chloromesityloxygermylene-amine MesO (Cl) Ge–tmeda complexes is presented. All compounds have been fully characterized by spectroscopic methods. The insertion reaction of (MesO) 2Ge–tmeda 1a with dimethyl disulfide, bis (trimethylsilyl) peroxide and iodomethane is reported. Cycloaddition ...