Chemistry Letters

Aminated Polystyrene-Bound Rhodium Carbonyl Clusters as a Catalyst for Deoxygenation of Various N–O Bonds

K Kaneda, T Takemoto, T Imanaka

Index: Kaneda, Kiyotomi; Takemoto, Tetsuya; Imanaka, Toshinobu Chemistry Letters, 1988 , p. 1759 - 1762

Full Text: HTML

Citation Number: 1

Abstract

Aminated polystyrene-bound rhodium carbonyl cluster complexes are prepared by treatment of Rh 6 (CO) 16 with various aminated polystyrenes. The polymeric rhodium complexes show a catalytic activity for deoxygenation of nitro compounds, oximes, hydroxylamines, and N-oxides under the conditions using CO and H 2 O. The recovered rhodium complexes maintain the deoxygenation ability with a small loss of the selectivity.

Related Articles:

Kepner-Tregoe Decision Analysis as a Tool To Aid Route Selection. Part 2. Application to AZD7545, a PDK Inhibitor

[Kajigaeshi, Shoji; Asano, Kohichi; Fujisaki, Shizuo; Kakinami, Takaaki; Okamoto, Tsuyoshi Chemistry Letters, 1989 , p. 463 - 464]

Comparison of the activity and lifetime of Raney nickel and nickel boride in the hydrogenation of various functional groups

[Journal of Organic Chemistry, , vol. 46, # 7 p. 1263 - 1269]

Pd/C (en)-Catalyzed chemoselective hydrogenation with retention of the N-Cbz protective group and its scope and limitations

[Hattori, Kazuyuki; Sajiki, Hironao; Hirota, Kosaku Tetrahedron, 2000 , vol. 56, # 43 p. 8433 - 8441]

Iodide reduction of sulfilimines. Evidence for the partitioning of sulfurane intermediates

[Journal of the American Chemical Society, , vol. 107, # 25 p. 7572 - 7577]

Reaction of Allenyl Selenoketene, Generated by [3, 3] Sigmatropic Rearrangement, with Amines

[Koketsu; Kanoh; Itoh; Ishihara Journal of Organic Chemistry, 2001 , vol. 66, # 11 p. 4099 - 4101]

More Articles...