Journal of fluorine chemistry

Synthesis of new nitrogen-containing perfluoroalkyl iodides

H Fukaya, E Hayashi, Y Hayakawa, T Abe

Index: Fukaya, Haruhiko; Hayashi, Eiji; Hayakawa, Yoshio; Abe, Takashi Journal of Fluorine Chemistry, 1997 , vol. 83, # 2 p. 117 - 123

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Citation Number: 10

Abstract

Perfluoro (dimethylamino)-, perfluoro (diethylamino)-, perfluoro (1-pyrrolidinyl)-, perfluoromorpholino-, perfluoropiperidino-and perfluoropropoxy-subs perfluoroalkyl iodides were synthesized directly by the reaction of the corresponding perfluoroacyl fluorides with lithium iodide in high yield. Under controlled reaction conditions, it was possible to synthesize either iodo-perfluoroacyl fluorides or perfluoroalkylidene diiodides by the ...

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