Reactivity of the Indole Ring in Palladium (II) Complexes of 2N1O-Donor Ligands: Cyclopalladation and π-Cation Radical Formation

…, Y Shimazaki, T Yajima, Y Nakabayashi…

Index: Motoyama, Takeshi; Shimazaki, Yuichi; Yajima, Tatsuo; Nakabayashi, Yasuo; Naruta, Yoshinori; Yamauchi, Osamu Journal of the American Chemical Society, 2004 , vol. 126, # 23 p. 7378 - 7385

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Citation Number: 32

Abstract

The Pd (II) complexes of new 2N1O-donor ligands containing a pendent indole, 3-[N-2- pyridylmethyl-N-2-hydroxy-3, 5-di (tert-butyl) benzylamino] ethylindole (Htbu-iepp), 1-methyl- 3-[N-2-pyridylmethyl-N-2-hydroxy-3, 5-di (tert-butyl) benzylamino] ethylindole (Htbu-miepp), 3-[N-2-pyridylmethyl-N-2-hydroxy-3, 5-di (tert-butyl) benzylamino] methylindole (Htbu-impp), and 3-(N-2-pyridylmethyl-N-4-hydroxybenzylamino) ethylindole (Hp-iepp)(H denotes a ...