Journal of organometallic chemistry

Aminosilylation of heterocumulenes and the intramolecular decomposition of their silyl-functionalized adducts

RJP Corriu, GF Lanneau, VD Mehta

Index: Corriu, R. J. P.; Lanneau, Gerard F.; Mehta, V. D. Journal of Organometallic Chemistry, 1991 , vol. 419, # 1 p. 9 - 26

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Citation Number: 19

Abstract

Abstract Heteroorganic amidosilanes are readily obtained by interaction of CO 2, CS 2 and other heterocumulenes with pentacoordinated diaminosilanes. A comparison is made with the corresponding reactions of tetracoordinated species. Decomposition of these bifunctional organosilanes gives 2-substituted ureido derivatives and base-stabilized low coordinated silicon species, seemingly by a unimolecular thermal β-elimination.

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