Journal of Organometallic Chemistry

A simple and efficient protocol for Suzuki coupling reactions of aryl chlorides and aryl bromides in aqueous DMF

L Liu, W Wang, C Xiao

Index: Liu, Leifang; Wang, Wendi; Xiao, Chuanyong Journal of Organometallic Chemistry, 2014 , vol. 749, p. 83 - 87

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Abstract

Abstract A simple, efficient and ligand-free palladium acetate catalyzed protocol was developed in aqueous N, N-dimethylformamide (DMF) under mild reaction conditions in the presence of Na 2 CO 3 in air. This procedure showed good catalytic efficiency towards the Suzuki coupling of aryl bromide and arylboronic acid. Furthermore, under enhanced reaction conditions, various aryl chlorides could smoothly be coupled with arylboronic ...

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