Spectroscopic and dielcometric study of the kinetics of alcoholysis of trichloroacetyl chloride with butanol

VV Varfolomeeva, VA Terent'ev…

Index: Varfolomeeva; Terent'ev; Bulanova Russian Journal of General Chemistry, 2003 , vol. 73, # 11 p. 1799 - 1802

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Abstract

Abstract The kinetics of alcoholysis of trichloroacetyl chloride with butanol in carbon tetrachloride were studied by dielcometry and IR spectroscopy. The reaction is reversible, and it involves intermediate formation of 1-butoxy-1, 2, 2, 2-tetrachloroethanol and 1, 1, 2, 2, 2-pentachloroethanol.

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