The Journal of Organic Chemistry

Mechanistic investigation of the oxidation of aromatic alkenes by monooxoruthenium (IV). Asymmetric alkene epoxidation by chiral monooxoruthenium (IV) complexes

WH Fung, WY Yu, CM Che

Index: Fung, Wai-Hong; Yu, Wing-Yiu; Che, Chi-Ming Journal of Organic Chemistry, 1998 , vol. 63, # 22 p. 7715 - 7726

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Citation Number: 84

Abstract

The oxoruthenium (IV) complexes [RuIV (terpy)(6, 6'-Cl2-bpy) O](ClO4) 2 (1a; terpy= 2, 2': 6', 2''-terpyridine; 6, 6'-Cl2-bpy= 6, 6'-dichloro-2, 2'-bipyridine),[RuIV (terpy)(tmeda) O](ClO4) 2 (1b; tmeda= N, N, N', N'-tetramethylethylenediamine),[RuIV (Cn)(bpy) O](ClO4) 2 (1c; Cn= 1, 4, 7-trimethyl-1, 4, 7-triazacyclononane), and [RuIV (PPz*)(bpy) O](ClO4) 2 (1d; PPz*= 2, 6- bis [(4 S, 7 R)-7, 8, 8-trimethyl-4, 5, 6, 7-tetrahydro-4, 7-methanoindazol-2-yl] pyridine) are ...

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