Study on 1, 3, 5??Triazine Chemistry in Dehydrocondensation: Gauche Effect on the Generation of Active Triazinylammonium Species

M Kunishima, T Ujigawa, Y Nagaoka…

Index: Kunishima, Munetaka; Ujigawa, Takae; Nagaoka, Yoshie; Kawachi, Chiho; Hioki, Kazuhito; Shiro, Motoo Chemistry - A European Journal, 2012 , vol. 18, # 49 p. 15856 - 15867

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Citation Number: 21

Abstract

Abstract The reaction of 2-chloro-4, 6-dimethoxy-1, 3, 5-triazine (CDMT) with various nitrogen-containing compounds, particularly tertiary amines (tert-amines), has been studied for the preparation of 2-(4, 6-dimethoxy-1, 3, 5-triazinyl) trialkylammonium salts [DMT-Am (s)]. DMT-Ams derived from aliphatic tert-amines exhibited activity for the dehydrocondensation between a carboxylic acid and an amine to form an amide in a ...